MSDS 820006

Material Safety Data Sheet:   Simple Green® All-Purpose Cleaner
                              Simple Green® Scrubbing Pad
Version No. 1300509A          Date of Issue: January 2009


Section 1: PRODUCT & COMPANY IDENTIFICATION

Product Name:            Simple Green® All-Purpose Cleaner               
                         Simple Green® Scrubbing Pad                     
Additional Name:         Simple Green® Concentrated                      
                         Cleaner/Degreaser/Deodorizer                    

Manufacturer's Product Code Numbers:    *Please refer to page 4         

Company:                 Sunshine Makers, Inc.                           
                         15922 Pacific Coast Highway                     
                         Huntington Harbour, CA 92649 USA                
Telephone:               800-228-0709 * 562-795-6000 Fax: 562-592-3830   
Emergency Phone:         Chem-Tel 24-Hour Emergency Service: 800-255-3924
Use of Product:          An all purpose cleaner and degreaser used       
                         diluted in water for direct, spray and dip tank 
                         procedures. Scrubbing pad is used with water for
                         manual scrubbing applications. Both are for     
                         cleaning water-safe surfaces.                   


Section 2: HAZARDS IDENTIFICATION

Emergency Overview:     CAUTION. Mild eye irritant            
Simple Green@ is a dark green liquid with a sassafras odor. Scrubbing Pad is a
green fibrous rectangle.                                                      

HMIS Rating:
Health = 1 = slight
Fire = 0
Reactivity, and Special = 0 = minimal

Eye Contact:         Mild Eye Irritant.                                       
Skin Contact:        No adverse effects expected under typical use conditions.
                     Prolonged exposure may cause dryness. Under this         
                     condition, use of gloves or skin moisturizer after       
                     washing may be indicated.                                
Ingestion:           May cause stomach or intestinal upset if swallowed (due  
                     to detersive properties.)                                
Inhalation:          No adverse effects expected under typical use conditions.
                     Adequate ventilation should be present when using Simple 
                     Green® over a prolonged period of time. Open windows or  
                     ventilate via fan or other air-moving equipment if       
                     necessary.                                               
Carcinogens:        No ingredients are listed by OSHA, IARC, or NTP as known  
                    or suspected carcinogens.                                 
Medical Conditions: No medical conditions are known to be aggravated by      
                    exposure to Simple Green®. Dermal-sensitive users may    
                    experience mild but reversible reactions.                

UN Number: Not Required      Dangerous Goods Class: Non-hazardous               
  

Section 3: COMPOSITION/INFORMATION ON INGREDIENTS

The only ingredient of Simple Green® with established exposure limits is
undiluted 2-butoxyethanol (<4%) (Butyl Cellosolve; CAS No. 111-76-2) [1% for
Scrubbing Pad]: the ACGIH TLV-TWA is 20 ppm (97 mg/m3). Based upon chemical
analysis, Simple Green® contains no known EPA priority pollutants, heavy metals
or chemicals listed under RCRA, CERCLA, or CWA. Analysis by TCLP (Toxicity
Characteristic Leaching Procedure) according to RCRA revealed no toxic organic
or inorganic constituents.

All components of Simple Green® are listed on the TSCA Chemical Substance
Inventory.
This product does not contain any ingredients covered by the provisions of 29
CFR 1910.1200.


Section 4: FIRST AID MEASURES

Eye Contact:    Reddening may develop. Immediately rinse the eye with large 
                quantities of cool water; continue 10-15 minutes or until   
                the material has been removed; be sure to remove contact    
                lenses, if present, and to lift upper and lower lids during 
                rinsing. Get medical attention if irritation persists.      
Skin Contact:   Minimal effects, if any; rinse skin with water, rinse shoes 
                and launder clothing before reuse. Reversible reddening may 
                occur in some dermal-sensitive users; thoroughly rinse area 
                and get medical attention if reaction persists.             
Swallowing;     Essentially non-toxic. Give several glasses of water to     
                dilute; do not induce vomiting. If stomach upset occurs,    
                consult physician.                                          
Inhalation:     Non-toxic. Exposure to concentrate may cause mild irritation
                of nasal passages or throat; remove to fresh air. Get       
                medical attention if irritation persists.                   


Section 5: FIRE FIGHTING MEASURES

Simple Green® is stable, not flammable, and will not burn. No special
procedures required.

Flash Point/Auto-Ignition:         Not flammable. 
Extinguishing Media:               Not flammable/non-explosive.
Flammability Limits:               Not flammable. 
Special Fire Fighting Procedures:  None required.


Section 6: ACCIDENTAL RELEASE MEASURES

Personal Precautions: Avoid contact with eyes. Do not rub eyes with hands
during cleanup. No special precautions for dermal contact are needed. Wash
hands thoroughly after cleaning up spill or leak.

Method for cleaning up: Recover usable material by convenient method, residual
may be removed by wipe or wet mop.  If necessary, unrecoverable material may be
washed to drain with large quantities of water.


Section 7: HANDLING AND STORAGE

No Special precautions are required. This product is non-hazardous for storage
and transport according to the U.S. Department of Transportation Regulations.
Simple Green® requires no special labeling or placarding to meet U.S.
Department of Transportation requirements.

UN Number:              Not Required
Dangerous Goods Class:  Non-hazardous


Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Limits:      The Simple Green® formulation presents no health hazards
                      to the user when used according to label directions for 
                      its intended purposes. Mild skin and eye irritation is  
                      possible (please see Eye contact and Skin contact in    
                      section IV.) No special precautionary measures required 
                      under normal use conditions.                            
Ventilation:          No special ventilation, precautions or respiratory      
                      protection is required during normal use. Large-scale   
                      use indoors should provide an increased rate of air     
                      exchange.                                               
Human Health Effects  Adverse effects on human health are not expected from   
or Risks From         Simple Green®, based on 20 years of use of Simple Green®
Exposure:             without reported adverse health incidence in diverse    
                      population groups, including extensive use by inmates of
                      U.S. Federal prisons in cleaning operations             
Eye protection:       Simple Green® is a mild eye irritant; mucous membranes  
                      may become irritated by concentrate. Eye protection not 
                      generally required. Wash hands after using wipes.       
Skin protection:      Simple Green® is not likely to irritate the skin in the 
                      majority of users. Repeated daily application to the    
                      skin without rinsing, or continuous contact on the skin 
                      may lead to temporary, but reversible, irritation. Rinse
                      completely from skin after contact.                     
General hygiene       There are no known hazards associated with this material
conditions:           when used as recommended. The following general hygiene 
                      considerations are recognized as common good industrial 
                      hygiene practices:                                      
                      - Avoid breathing vapor or mist.                        
                      - Avoid contact with eyes.                              
                      - Wash thoroughly after handling and before eating,     
                        drinking, or smoking.                                   


Section 9: PHYSICAL AND CHEMICAL PROPERTIES

Appearance & Odor: Cleaner is a dark green liquid, pad is a fibrous green     
matrix; both exhibit a sassafras odor.                                        

Specific Gravity:    1.010 ± 0.010       Vapor Pressure:     18 mm Hg @ 20°C;   
                                                            23.5 mmHg @ 26°C   
Evaporation:         >1 (butyl acetate = 1)  Vapor Density:  1.3 (air = 1)      
Water Solubility:    100%                    Density:        8.5 lbs/gallon     

Boiling Point:       100.6°C (212°F)         pH:             9.5 ± 0.3          
Ash Content:         At 600°F: 1.86% by      Nutrient Content:                  
                     weight                  Phosphorus: 0.3% by formula        
                                             Nitrogen <1.0% by weight (fusion   
                                          and qualitative test for ammonia)     
                                          Sulfur: 0.6% by weight (barium        
                                          chloride precipitation method)        
Freezing Point:      Approx -9 °C (16°F)                                       
If product freezes, it will reconstitute without loss of efficacy               
when brought back to room temperature and agitated                              

VOC Composite Partial Pressure: 0.006 mmHg @ 20°C                             

Volatile Organic Compounds (VOCs):                                            
CARB Method 310     3.8%
SCAQMD Method 313   2.8%

Cleaner meets CARB & BAAQMD regulations.  Cleaner must be diluted 1:1 with    
water to meet SCAQMD Rule 1171 & Rule 1122 VOC requirements for solvent       
cleaning operations. [Scrubber VOCs = 3.3% to dilution w/water]               
                                                                              
                                                                              
Section 10: STABILITY AND REACTIVITY

Stability:                         Stable
Materials to Avoid:                None known
Hazardous Decomposition Products:  None expected


Section 11: TOXICOLOGICAL INFORMATION

Toxicology information is based on chemical profile of ingredients and
extrapolation of data from similar formulas.

Acute Toxicity:     Oral LD50 (rat)       >5 g/kg body weight*                  
                   Dermal LD50 (rabbit)  >2 g/kg body weight
                    *Calculation from OECD series on testing and              
                    assessment number 33, Chapter 3.2                         
                                                                              
Eye Irritation:     Moderate/Mild reversible eye irritation may occur based on
                    relevant laboratory studies. This potential is reduced by 
                    immediate rinsing of eyes in case of eye contact.         
Dermal Irritation:  Mild, reversible skin irritation may occur based on       
                    relevant laboratory studies. A 6-hour exposure to human   
                    skin under a patch did not produce irritation.            
Repeat Exposure     Based on relevant laboratory studies, no toxic effects are
Via Skin Contact:   expected to be associated with daily skin exposures (with 
                    up to 2 g/kg/day tested for 13 weeks on rabbits). Skin    
                    irritation may, however, occur with repeated or prolonged 
                    exposures.                                                
Reproductive        Based on relevant laboratory studies (CD-1 mouse 18-week  
Effects Assessment: fertility assessment continuous breeding), no adverse     
                    effects on reproduction, fertility, or health of offspring
                    are expected.                                             


Section 12: ECOLOGICAL INFORMATION

Hazard to wild animals & aquatic organisms: Low, based on toxicological
                                            profile.

Biodegradability: Readily biodegradable based on biodegradation profile,
PRO/FT CBT-AC 014-7 "Ready Biodegradability: Closed Bottle Test" OECD, and OECD
302B laboratory tests

Environmental Toxicity Information: It is important not to allow the runoff
from cleaning into closed systems such as decorative ponds. Always protect
closed systems with tarps or dikes if necessary.


Section 13: DISPOSAL CONSIDERATIONS

Dispose of in accordance with all applicable local, state and federal laws.
Dispose of used or unused product, and empty containers in accordance with the
local, State, Provincial, and Federal regulations for your location.  Never
dispose of used degreasing rinsates into lakes, streams and open bodies of
water or storm drains.


Section 14:  TRANSPORTATION INFORMATION

This product is non-hazardous for transport according to the U.S. Department of
Transportation Services
   UN Number:   Not required       Dangerous Goods Class:  Non-Hazardous


Section 15:  REGULATORY INFORMATION

*Reportable components:                                                         
   
All components are listed on: EINECS and TSCA Inventory                       
No components listed under:   Clean Air Act Section 112                     
SARA:                         This material contains 2-Butoxyethanol, <4% (CAS#
                              111-76-2) which is subject to the reporting      
                              requirements of Section 313 of SARA Title III and
                              49 CFR Part 373.                                 
RCRA Status:                  Not a hazardous waste                            
CERCLA Status:                No components listed                             
TSCA TRI Reporting:           Not required / Not listed                        
CA PROP. 65 Status:           No components listed                             
                                                                        

Section 16:  OTHER INFORMATION

Questions about the information found on this MSDS should be directed to:
SUNSHINE MAKERS, INC. - TECHNICAL DEPARTMENT
15922 Pacific Coast Hwy. Huntington Harbour, CA 92649

Phone: 800-228-0709 [8am-5pm Pacific time, Mon-Fri]
Fax: 562-592-3830
Email:  infoweb@simplegreen.com


CAGE CODE 1Z575
GSA/FSS - CONTRACT NO. GS-07F-0065J
National Stock numbers and Industrial Part Numbers:
Simple Green    Part Number  NSN                 Size             
                13012        7930-01-342-5315    24 oz spray (12/case)     
                13005        7930-01-306-8369    1 Gallon (6/case)
                13006        7930-01-342-5316    5 Gallon         
                13016        7930-01-342-5317    15 Gallon        
                13008        7930-01-342-4145    55 Gallon        
                13275        N/A                 275 Gallon tote  
Scrubbing Pad   10224        7930-01-346-9148    Each (24/case)   

Retail Numbers:
Part Number  Size              
13002        16 oz Trigger (12/case)     
13005        1 Gallon (6/case) 
13013        24 oz Trigger (12/case)    
13014        67 oz / 2L (6/case)       
13033        32 oz Trigger (12/case)         

*part number is for both industrial and retail
**International Part Numbers May Differ.


DISCLAIMER:  The information provided with this MSDS is furnished in good faith
and without warranty of any kind.  Personnel handling this material must make
independent determinations of the suitability and completeness of information
from all sources to assure proper use and disposal of this material and the
safety and health of employees and customers.  Sunshine Makers, Inc. assumes no
additional liability or responsibility resulting from the use of, or reliance
on this information.

The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance.

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