MSDS 85355

MATERIAL SAFETY DATA SHEET

DATE OF PREPARATION
Feb 9, 2009


SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NUMBER
    K1107250-
PRODUCT NAME
    KRYLON® Industrial IRON GUARD DTM Water-Based Anti-Rust Acrylic Coating,
    White Base
MANUFACTURER'S NAME
    THE SHERWIN-WILLIAMS COMPANY
    KRYLON PRODUCTS GROUP
    Cleveland, OH 44115

Telephone Numbers and Websites
Product Information         (800) 247-3266             
                            www.kpg-industrial.com     
Regulatory Information      (216) 566-2902             
                            www.paintdocs.com          
Medical Emergency           (216) 566-2917             
Transportation Emergency*   (800) 424-9300             
*for Chemical Emergency ONLY (spill, leak, fire exposure or accident)           
                      

SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS

% by Weight  CAS Number   Ingredient           Units           Vapor Pressure  
15           13463-67-7   Titanium Dioxide                                     
                             ACGIH TLV         10 mg/m3 as Dust                 
                             OSHA PEL          10 mg/m3 Total Dust              
                            OSHA PEL           5 mg/m3 Respirable Fraction     

SECTION 3 - HAZARDS IDENTIFICATION

HMIS Codes      
Health        1*  
Flammability  0   
Reactivity    0   

ROUTES OF EXPOSURE
    INHALATION of vapor or spray mist.
    EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
    EYES:         Irritation.
    SKIN:         Prolonged or repeated exposure may cause irritation.
    INHALATION:   Irritation of the upper respiratory system.

   In a confined area vapors in high concentration may cause headache, nausea or
   dizziness.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
    Redness and itching or burning sensation may indicate eye or excessive skin
    exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
    May cause allergic skin reaction in susceptible persons or skin
    sensitization.
CANCER INFORMATION
    For complete discussion of toxicology data refer to Section 11.


SECTION 4 - FIRST AID MEASURES

EYES:       Flush eyes with large amounts of water for 15 minutes. Get medical
            attention.
SKIN:       Wash affected area thoroughly with soap and water.
            Remove contaminated clothing and launder before re-use.
INHALATION: If affected, remove from exposure. Restore breathing. Keep
            warm and quiet.
INGESTION:  Do not induce vomiting. Get medical attention immediately.


SECTION 5 - FIRE FIGHTING MEASURES

FLASH POINT           LEL         UEL        FLAMMABILITY CLASSIFICATION
  Not Applicable      N.A.        N.A.       Not Applicable

EXTINGUISHING MEDIA
    Carbon Dioxide, Dry Chemical, Alcohol Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
    Closed containers may explode (due to the build-up of pressure) when exposed
    to extreme heat.
    During emergency conditions overexposure to decomposition products may cause
    a health hazard. Symptoms may not be immediately apparent. Obtain medical
    attention.
SPECIAL FIRE FIGHTING PROCEDURES
    Full protective equipment including self-contained breathing apparatus
    should be used.
    Water spray may be ineffective. If water is used, fog nozzles are
    preferable. Water may be used to cool closed containers to prevent pressure
    build-up and possible autoignition or explosion when exposed to extreme
    heat.


SECTION 6 - ACCIDENTAL RELEASE MEASURES

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
    - Remove all sources of ignition. Ventilate the area.
    - Remove with inert absorbent.


SECTION 7 - HANDLING AND STORAGE

STORAGE CATEGORY
    Not Applicable
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
    Keep container closed when not in use. Transfer only to approved containers
    with complete and appropriate labeling. Do not take internally.
    Keep out of the reach of children.


SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION

PRECAUTIONS TO BE TAKEN IN USE
    Use only with adequate ventilation.
    Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
    Wash hands after using.
    This coating may contain materials classified as nuisance particulates
    (listed "as Dust" in Section 2) which may be present at hazardous levels
    only during sanding or abrading of the dried film. If no specific dusts are
    listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV
    10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
    (total dust), 5 mg/m3 (respirable fraction).
VENTILATION
    Local exhaust preferable. General exhaust acceptable if the exposure to
    materials in Section 2 is maintained below applicable exposure limits. Refer
    to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
    If personal exposure cannot be controlled below applicable limits by
    ventilation, wear a properly fitted organic vapor/particulate respirator
    approved by NIOSH/MSHA for protection against materials in Section 2.
    When sanding or abrading the dried film, wear a dust/mist respirator
    approved by NIOSH/MSHA for dust which may be generated from this product,
    underlying paint, or the abrasive.
PROTECTIVE GLOVES
    Wear gloves which are recommended by glove supplier for protection against
    materials in Section 2.
EYE PROTECTION
    Wear safety spectacles with unperforated sideshields.


SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

PRODUCT WEIGHT             9.57 lb/gal           1146 g/l                       
SPECIFIC GRAVITY           1.15                                                 
BOILING POINT              212 - 369 °F          100 - 187 °C                   
MELTING POINT              Not Available                                        
VOLATILE VOLUME            65%                                                  
EVAPORATION RATE           Slower than ether                                    
VAPOR DENSITY              Heavier than air                                     
SOLUBILITY IN WATER        N.A.                                                 
pH                         9.0                                                  

VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)                      

0.78 lb/gal         93g/l              Less Water and Federally Exempt Solvents
0.30 lb/gal         36g/l              Emitted VOC                     


SECTION 10 - STABILITY AND REACTIVITY

STABILITY - Stable
CONDITIONS TO AVOID
    None known.
INCOMPATIBILITY
    None known.
HAZARDOUS DECOMPOSITION PRODUCTS
    By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
    Will not occur


SECTION 11 - TOXICOLOGICAL INFORMATION

CHRONIC HEALTH HAZARDS
    IARC's Monograph No. 93 reports there is sufficient evidence of
    carcinogenicity in experimental rats exposed to titanium dioxide but
    inadequate evidence for carcinogenicity in humans and has assigned a Group
    2B rating. In addition, the IARC summary concludes, "No significant exposure
    to titanium dioxide is thought to occur during the use of products in which
    titanium is bound to other materials, such as paint."
TOXICOLOGY DATA
CAS No.          Ingredient Name                                    
13463-67-7       Titanium Dioxide                                  
                    LC50 RAT      4HR              Not Available   
                    LD50 RAT                       Not Available   


SECTION 12 - ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL INFORMATION
    No data available.


SECTION 13 - DISPOSAL CONSIDERATIONS

WASTE DISPOSAL METHOD
    Waste from this product is not hazardous as defined under the Resource
    Conservation and Recovery Act (RCRA) 40 CFR 261.
    Incinerate in approved facility. Do not incinerate closed container. Dispose
    of in accordance with Federal, State/Provincial, and Local regulations
    regarding pollution.


SECTION 14 - TRANSPORT INFORMATION

US Ground (DOT)
    Not Regulated for Transportation.
Canada (TDG)
    Not Regulated for Transportation.
IMO
    Not Regulated for Transportation.


SECTION 15 - REGULATORY INFORMATION

SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.            CHEMICAL/COMPOUND            % BY wt    % Element         
    No ingredients in this product are subject to SARA 313 (40 CFR 372.65C)
    Supplier Notification.
CALIFORNIA PROPOSITION 65
    WARNING: This product contains chemicals known to the State of California to
    cause cancer and birth defects or other reproductive harm.
TSCA CERTIFICATION
    All chemicals in this product are listed, or are exempt from listing, on the
    TSCA Inventory.


SECTION 16 - OTHER INFORMATION

This product has been classified in accordance with the hazard criteria of the
Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the
information required by the CPR.



The above information pertains to this product as currently formulated, and is
based on the information available at this time. Addition of reducers or other
additives to this product may substantially alter the composition and hazards
of the product. Since conditions of use are outside our control, we make no
warranties, express or implied, and assume no liability in connection with any
use of this information.

The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance.

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