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MSDS 85353 85353: Iron Guard Lt Mach Gray 1 Gal [4]MSDS Last updated: 07/14/2009
MATERIAL SAFETY DATA SHEET
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NUMBER
K1100327-
PRODUCT NAME
KRYLON® Industrial IRON GUARD DTM Water-Based Anti-Rust Acrylic Coating,
Light Machine Gray
MANUFACTURER'S NAME
THE SHERWIN-WILLIAMS COMPANY
KRYLON PRODUCTS GROUP
Cleveland, OH 44115
Telephone Numbers and Websites
Product Information (800) 247-3266
www.kpg-industrial.com
Regulatory Information (216) 566-2902
www.paintdocs.com
Medical Emergency (216) 566-2917
Transportation Emergency* (800) 424-9300
*for Chemical Emergency ONLY (spill, leak, fire, exposure or accident)
SECTION 2 - COMPOSITION/ INFORMATION ON INGREDIENTS
% by Weight CAS Number Ingredient Units Vapor Pressure
1 29911-28-2 1-(2-Butoxymethylethoxy)-propanol
ACGIH TLV Not Available 0.06mm
OSHA PEL Not Available
7 13463-67-7 Titanium Dioxide
ACGIH TLV 10 mg/m3 as Dust
OSHA PEL 10 mg/m3 Total Dust
OSHA PEL 5 mg/m3 Respirable Fraction
SECTION 3 - HAZARDS IDENTIFICATION
HMIS Codes
Health 1*
Flammability 0
Reactivity 0
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation
INHALATION: Irritation of the upper respiratory system.
In a confined area vapors in high concentration may cause headache, nausea or
dizziness.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Redness and itching or burning sensation may indicate eye or excessive skin
exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
May cause allergic skin reaction in susceptible persons or skin sensitization.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
SECTION 4 - FIRST AID MEASURES
EYES: Flush eyes with large amounts of water for 15 minutes. Get
medical attention.
SKIN: Wash affected area thoroughly with soap and water.
Remove contamination clothing and launder before re-use.
INHILATION: If affected, remove from exposure. Restore breathing. Keep
warm and quiet.
INGESTION: Do not induce vomiting. Get medical attention immediately.
SECTION 5 - FIRE FIGHTING MEASURES
FLAMMABILITY CLASSIFICATION
FLASH POINT LEL UEL Not Applicable
Not Applicable N.A. N.A.
EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam
UNUSUAL FIRE AND EXPLOTION HAZARDS
Closed containers may explode (due to the build-up of pressure) when exposed
to extreme heat.
During emergency conditions overexposure to decomposition products may cause a
health hazard. Symptoms may not be immediately apparent. Obtain medical
attention
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self-contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are preferable.
Water may be used to cool closed containers to prevent pressure build-up and
possible auto ignition or explosion when exposed to extreme heat.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
- Remove all sources of ignition. Ventilate the area.
- Remove with inert absorbent.
SECTION 7 - HANDLING AND STORAGE
STORAGE CATEGORY
Not Applicable.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep container closed when not in use. Transfer only to approved containers
with complete and appropriate labeling. Do not take internally. Keep out of
the reach of children.
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates (listed
"as Dust" in Section 2) which may be present at hazardous levels only during
sanding or abrading of the dried film. If no specific dusts are listed in
Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10mg/m3
(total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5
mg/m3 (respirable fraction).
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits. Refer
to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator approved
by NIOSH/MSHA for dust which may be generated from this product, underlying
paint, or the abrasive.
PROTECTIVE GLOVES
Wear gloves which are recommended by glove supplier for protection against
materials in Section 2.
EYE PROTECTION
Wear safety spectacles with unperforated side shields.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
PRODUCT WEIGHT 8.98 lb/gal 1076 g/l
SPECIFIC GRAVITY 1.08
BOILING POINT 212 - 449 F 100 - 231 C
MELTING POINT Not Available
VOLATILE VOLUME 65%
EVAPORATION RATE Slower than ether
VAPOR DENSITY Heavier than air
SOLUBILITY IN WATER N.A.
pH 9.0
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)
0.81 lb/gal 97g/l Less Water and Federally Exempt Solvents
0.31 lb/gal 37g/l Emitted VOC
SECTION 10 - STABILITY AND REACTIVITY
STABILITY - Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur.
SECTION 11 - TOXICOLOGICAL INFORMATION
CHRONIC HEALTH HAZARDS
IARC's Monograph No. 93 reports that there is sufficient evidence of
carcinogenicity in experimental rats exposed to titanium dioxide but
inadequate evidence for carcinogenicity in humans and has assigned a Group 2B
rating. In addition, the IARC summary concludes, "No significant exposure to
titanium dioxide is thought to occur during the use of products in which
titanium is bound to other materials, such as paint."
TOXICOLOGY DATA
CAS No. Ingredient Name
29911-28-2 1-(2-butoxymethylethoxy)-propanol
LC50 RAT 4HR Not Available
LD50 RAT Not Available
13463-67-7 Titanium Dioxide
LC50 RAT 4HR Not Available
LD50 RAT Not Available
SECTION 12 - ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
No data available.
SECTION 13 - DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD
Waste from this product is not hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Incinerate in approved facility. Do not incinerate closed container. Dispose
of in accordance with Federal, State/Provincial, and Local regulations
regarding pollution.
SECTION 14 - TRANSPORT INFORMATION
US Ground (DOT)
Not Regulated for Transportation.
Canada (TDG)
Not Regulated for Transportation.
IMO
Not Regulated for Transportation.
SECTION 15 - REGULATORY INFORMATION
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No. CHEMICAL/COMPOUND % BY wt % Element
No ingredients in this product are subject to SARA 313 (40CFR 372.65C)
Supplier Notification.
CALIFORNIA PROPOSITION 65
WARNING: This product contains chemicals known to the State of California to
cause cancer and birth defects or other reproductive harm.
TSCA CERTIFICATION
All Chemicals in this product are listed, or are exempt for listing, on the
TSCA Inventory.
SECTION 16 - OTHER INFORMATION
This product has been classified in accordance with the hazard criteria of the
Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the
information required by the CPR.
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The above information pertains to this product as currently formulated, and is
based on the information available at this time. Addition of reducers or other
additives to this product may substantially alter the composition and hazards
of the product. Since conditions of use are outside our control, we make no
warranties, express or implied, and assume no liability in connection with any
use of this information.
The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance. For more product information by email, click here Imperial Supplies LLC does not provide services and products outside the United States |