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MSDS 85081

85081: Marking Paint- White [12]
MSDS Last updated: 08/27/2004
                            MATERIAL SAFETY DATA SHEET
                              acc. to ISO/DIS 11014

 
Printing date 02/04/2004                      Reviewed on 02/04/2004
 

                         1.  IDENTIFICATION OF SUBSTANCE

 
Trade name:         STRIPE INVERTED TIP WHITE
Product code:         0000200652

Manufacturer/Supplier:   SEYMOUR OF SYCAMORE
                            917 Crosby Avenue
                            Sycamore, IL  60178
                            (815)-895-9101, www.seymourpaint.com 
Information department:   Health & Safety Department
Emergency information:   CHEMTEL 1-800-255-3924, 813-248-0585 if located
                            outside the U.S.

 
                        2.  COMPOSITION/DATA ON COMPONENTS

 
Chemical Description:   This product is a mixture of the substances listed below 
            with nonhazardous additions. 

Dangerous components;   
--------------------------------------------------------------------------------
74-98-6       propane                  F+: R 12          17.64%
1317-65-3     Calcium Carbonate       Xi: R 36/37/38   16.93%
64742-89-8   VM&P Naptha             Xn: R 20/22        13.44%
106-97-8     n-butane                F+: R 12          10.36%   
13463-67-7   titanium dioxide       Xi: R 37          7.02%
64742-47-8   Mineral Spirits         Xn, F: R 11-65   5.32%

Additional information:   For the wording of the listed risk phrases refer to 
section 3.
 

                            3.  HAZARDS IDENTIFICATION

 
Hazard description:   Xi  Irritant
                       F+ Extremely flammable
 
Physical and
Environmental dangers: Warning!  Pressurized container.
            R 12  Extremely flammable.
            R 37  Irritating to respiratory system. 
            Pressurized container: protect from sunlight and do not expose to
            temperatures exceeding 50ºC, i.e. electric lights. Do not pierce or
            burn, even after use. 
            Keep out of the reach of children.
NFPA ratings (scale 0 - 4):    Health - 1
                                  Flammability -     3
                                  Reactivity -  3
HMIS ratings (scale 0 - 4):     Health -  1
                                  Flammability -  3
                                  Physical Hazard -  3
 

                              4.  FIRST AID MEASURES

 
After inhalation:   In case of unconsciousness, place patient in side position for
transportation. 

After skin contact;   Generally the product does not irritate the skin.

After eye contact:   Rinse opened eye for several minutes under running water.
Then consult a doctor. 

After swallowing:   Consult a doctor if symptoms persist. 
 

                            5.  FIRE FIGHTING MEASURES

 
Extinguishing agents:   CO2, sand, extinguishing powder, or water spray.
Fight larger fires with water spray or alcohol resistant foam. 

Protective equipment: No special measures required.
 

                         6.  ACCIDENTAL RELEASE MEASURES

 
Personal safety
precautions:       Wear protective equipment. Keep unprotected persons away.

Environmental
safety precautions:   Do not allow product to reach sewage systems or ground 
water. Inform appropriate authorities in case of seepage into water
coarse or sewage system.

Measures for 
cleaning/collecting:   Do not flush with water or aqueous cleansing agents.
Use diluted caustic solution. Soak up spills with inert absorbent material. 
Refer to section 13 for disposal information.
 

                             7.  HANDLING AND STORAGE

 
Safe handling 
information:      Ensure good ventilation/exhaustion at the workplace.
Handle carton and cans with care. Avoid dropping. 

Fire/explosion
protection:       Do not spray on a naked flame or any incandescent material.
Keep ignition sources away - Do not smoke. Protect against electrostatic 
charges. 

Storage requirements:   Observe official regulations on storing packaging with
pressurized containers. Consult with your local authorities. Keep away from 
sources of heat and direct sunlight. Do not warehouse in subfreezing conditions. 
 

                  8.  EXPOSURE CONTROLS AND PERSONAL PROTECTION:

 
Components with limit values that require monitoring at the workplace:
74-98-6           propane
                  PEL   1800 mg/m3, 1000 ppm
                  REL   1800 mg/m3, 1000 ppm
                  TLV   (4508) mg/m3, (2500) ppm
1317-65-3         Calcium Carbonate
                  PEL   15*: 5** mg/m3
                   *Total dust **Respirable fraction
                  REL   10: 5** mg/m3
                   *Total dust **Respirable fraction
                  TLV   10 mg/m3
                   (e)
106-97-8          n-butane
                  REL   1900 mg/m3, 800 ppm
                  TLV   1900 mg/m3, 800 ppm
64742-47-8         Mineral Spirits
                  TLV   200 mg/m3
                   As total hydrocarbon vapor: Skin: (P)

Protective hygienic
measures:    Keep away from foodstuffs, beverages, and animal feed. 
Immediately remove all soiled and contaminated clothing. Wash hands before 
breaks and at the end of work.

Breathing 
equipment:   A respirator is generally not necessary when using this product 
outdoors or in large open areas. In cases of inadequate ventilation, a 
respiratory protective device should be worn to prevent overexposure. 
Use suitable respiratory protective device in case of insufficient ventilation. 

Protection of
hands:       Protective gloves. The glove material has to be impermeable and
resistant to the substance. No glove recommendation can be given.

Eye Protection: Tightly sealed goggles. 
 

                      9.  PHYSICAL AND CHEMICAL PROPERTIES:

 
General Information:
Form:         Aerosol
Color:         According to trade name description in section 1.
Odor:         Solvent
Boiling Point/      -44ºC (-47ºF)
Boiling Range: 
Flash point:      -19ºC (-2ºF)
Ignition temperature;   210.0ºC (410ºF)
Auto igniting;      Product is not self-igniting. 
Danger of explosion;   Heating may cause an explosion.
                         In use, may form flammable/explosive vapor-air mixture.

Lower Explosion
Limit:         0.9 Vol %
Upper Explosion
Limit;         10.9 Vol %
Vapor Pressure:   40 PSI, 2750 hPa
Density:      
Specific Gravity;   Between 0.77 and 0.09 (Water equals 1.00)
VOC content;      0.48 kg/l / 3.98 lb/gl
VOC in weight percent
(less acetone);      47.7 %
Water;         20.0 %
Solids content;      32.0 %
 

                          10.  STABILITY AND REACTIVITY:

 
Conditions to be avoided: Do not allow the can to exceed 120 degrees Fahrenheit.
Stable at normal temperatures. 

Possibility of Hazardous
Reactions:  No dangerous reactions known. 
 

                          11.  TOXICOLOGICAL INFORMATION

 
Primary effect on the skin:   No irritant effect.
Primary effect on the eye:   No irritating effect.
Sensitization;   No sensitizing effects known.
 

                           12.  ECOLOGICAL INFORMATION

 
Other information:   This product does not contain any chlorinated solvents or 
lead. No specific ecological data is available for this product.

Aquatic toxicity;   Harmful to aquatic organisms.
Hazardous for water, do not empty into drains.
 

                           13.  DISPOSAL CONSIDERATIONS

 
DISPOSAL METHOD:  Dispose of in accordance with local, state, and federal 
regulations. Do not puncture, incinerate, or compact. Partially empty cans 
cannot be disposed of with regular trash. Do not heat or cut empty containers 
with electric or gas torches.

Recommendation:     Empty cans should be recycled. 
 

                           14.  TRANSPORT INFORMATION:

 
Hazard class;      2.1
Identification number: N/A
Label:         2.1
ADR/RID class;   2  5F Gases
UN-Number:      1950
IMDG Class:      2.1
Packing group:   II
EMS Number:      F-D,S-U
Marine pollutant:     No
ICAO/IATA Class:   2.1
Proper shipping name: Aerosols, Flammable
          Consumer Commodity ORM-D
 

                                 15.  REGULATIONS

 
SARA Section 355 (extremely hazardous substances):
None of the ingredients in this product are listed. 

SARA Section 313 (Specific toxic chemical listings):
1330-20-7              xylene (mix)
100-41-4                  ethyl benzene

TSCA (Toxic Substances Control Act):
7732-18-5              Water
74-98-6                propane
1317-65-3              Calcium Carbonate
64742-89-8              VM & P Naptha
106-97-8               n-butane
13463-67-7              titanium dioxide
71243-64-6              V.T. Alkyd Resin
64742-47-8              Mineral Spirits
1330-20-7              xylene (mix)
68953-58-2              Alkyl Quanternary Ammonium Montmorillonite
8002-43-5              Soya Lecithin
100-41-4               ethyl benzene

PROPOSITION 65 Chemicals known to cause cancer:
None of the ingredients in this product are listed.

PROPOSITION 65 Chemicals known to cause reproductive toxicity:
None of the ingredients in this product are listed. 

Canadian WHMIS:  This product has been classified according to the Controlled
Product Regulations and the MSDS contains all the necessary information required 
by the CPR.  Class B, D5 --- Flammable Aerosols 

EPA:               A=Known human carcinogen            B=Probable human carcinogen
                   C=Possible human carcinogen
                   D=Not classifiable as to human carcinogenicity: Inadequate 
                   human and animal evidence of carcinogenicity (or no data is 
                   available).
1330-20-7   xylene (mix)   D
100-41-4   ethyl benzene   D
 
IARC:
13463-67-7   titanium dioxide  3
1330-20-7     xylene (mix)       3
110-91-8     morpholine        3
 
ACGIH TLV's:   A1-designates a confirmed human carcinogen.
                 A2-designates a suspected human carcinogen.
                 A3-designates an animal carcinogen. 
                 A4-designates "not classifiable as a human carcinogen".
13463-67-7   titanium dioxide   A4
1330-20-7     xylene (mix)        A4
110-91-8     morpholine          A4
 
NIOSH:
13463-67-7   titanium dioxide
 

                              16.  OTHER INFORMATION

 
This information is based on our present knowledge. However, this shall not 
constitute a guarantee for any specific product features and shall not establish 
a legally valid contractual relationship.
Contact:   Craig Swafford, Regulatory Affairs. Email: cswafford@seymourpaint.com 

The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance.

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Imperial Supplies LLC does not provide services and products outside the United States

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