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MSDS 85018

85018: Self Etching Gray Primer 16 Oz [12]
MSDS Last updated: 02/01/2010

IMPERIAL SUPPLIES LLC  MSDS SHEET FOR 85018 
Date of Preparation                                                           
Jan 13, 2010                                                                  
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION                                
                                                                              
PRODUCT NUMBER:          C27869000                                            
PRODUCT NAME:            85018 SELF ETCH PRIMER                               
MANUFACTURER'S NAME      CBD Group                                            
                         101 Prospect Ave.                                    
                         Cleveland, OH 44115                                  
Telephone Numbers and Websites                                                
Regulatory Information   (216) 566-2902                                       
                         www.paintdocs.com                                    
Medical Emergency        (216) 566-2917                                       
Transportation Emergency (800) 424-9300                                       
*for Chemical Emergency ONLY (spill, leak, fire, exposure or accident)        
                                                                              
SECTION 2 - COMPOSITION / INFORMATION ON INGREDIENTS                          
                                                                              
% by       CAS Number  Ingredient           Units                Vapor        
Weight                                                           Pressure     
11         74-98-6     Propane                                   760 mm       
                       ACGIH TLV            2500 PPM                          
                       OSHA PEL             1000 PPM                          
11         106-97-8    Butane                                    760 mm       
                       ACGIH TLV            800 PPM                           
                       OSHA PEL             800 PPM                           
8          108-88-3    Toluene                                   22 mm        
                       ACGIH TLV            20 PPM                            
                       OSHA PEL             100 PPM (skin)                    
                       OSHA PEL             150 PPM (skin) STEL               
34         67-64-1     Acetone                                   180 mm       
                       ACGIH TLV            500 PPM                           
                       ACGIH TLV            750 PPM STEL                      
                       OSHA PEL             1000 PPM                          
2          78-93-3     Methyl Ethyl Ketone                       70 mm        
                       ACGIH TLV            200 PPM                           
                       ACGIH TLV            300 PPM STEL                      
                       OSHA PEL             200 PPM                           
                       OSHA PEL             300 PPM STEL                      
7          108-10-1    Methyl Isobutyl                           16 mm        
                       Ketone                                                 
                       ACGIH TLV            50 PPM                            
                       ACGIH TLV            75 PPM STEL                       
                       OSHA PEL             50 PM                             
                       OSHA PEL             75 PPM STEL                       
2          763-69-9    Ethyl                                     1.11 mm      
                       3-Ethoxypropionate                                     
                       ACGIH TLV            Not Available                     
                       OSHA PEL             Not Available                     
1          123-86-4    n-Butyl Acetate                           10 mm        
                       ACGIH TLV            150 PPM                           
                       ACGIH TLV            200 PPM STEL                      
                       OSHA PEL             150 PPM                           
                       OSHA PEL             200 PPM STEL                      
5          110-19-0    Isobutyl Acetate                          12.5 mm      
                       ACGIH TLV            150 PPM                           
                       OSHA PEL             150 PPM                           
6          14807-96-6  Talc                                                   
                       ACGIH TLV            2 mg/m3 as Resp.                  
                                            Dust                              
                       OSHA PEL             2 mg/m3 as Resp.                  
                                            Dust                              
3          13463-67-7  Titanium Dioxide                                       
                       ACGIH TLV            10 mg/m3 as Resp.                 
                                            Dust                              
                       OSHA PEL             10 mg/m3 as Total                 
                                            Dust                              
                       OSHA PEL             5 mg/m3 Respirable Fraction       
                                                                              
SECTION 3 - HAZARDS IDENTIFICATION                                            
                                                                              
HMIS Codes          Health: 2           Flammability: 3     Reactivity: 0      
                                                                              
ROUTES OF EXPOSURE     INHALATION of vapor or spray mist                      
                       EYE or SKIN contact with the product, vapor or spray   
                       mist.                                                  
EFFECTS OF             EYES:        Irritation.                              
OVEREXPOSURE                                                                 
                       SKIN:        Prolonged or repeated exposure may cause 
                                    irritation.                              
                       INHALATION:  Irritation of the upper respiratory      
                                    system.                                  
                                                                              
May cause nervous system depression. Extreme overexposure may result in       
unconsciousness and possibly death.                                           
Prolonged overexposure to solvent ingredients in Section 2 may cause adverse  
effects to the liver, urinary, blood forming, cardiovascular and reproductive 
systems.                                                                      
                                                                              
SIGNS AND SYMPTOMS OF OVEREXPOSURE                                            
Headache, dizziness, nausea, and loss of coordination are indications of      
excessive exposure to vapors or spray mists.                                  
Redness and itching or burning sensation may indicate eye or excessive skin   
exposure.                                                                     
                                                                              
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE                                     
None generally recognized.                                                    
                                                                              
CANCER INFORMATION                                                            
For complete discussion of toxicology data refer to Section 11.               
                                                                              
SECTION 4 - FIRST AID MEASURES                                                
                                                                              
EYES:        Flush eyes with large amounts of water for 15 minutes. Get       
             medical attention.                                               
SKIN:        Wash affected area thoroughly with soap and water.               
             Remove contaminated clothing and launder before re-use.          
INHALATION:  If affected, remove from exposure. Restore breathing. Keep warm  
             and quiet.                                                       
INGESTION:   Do not induce vomiting. Get medical attention immediately.       
                                                                              
SECTION 5 - FIRE FIGHTING MEASURES                                            
                                                                              
FLASH POINT         LEL  UEL      EXTINGUISHING MEDIA                         
Propellant <0 F     1.0  12.8     Carbon Dioxide, Dry Chemical , Foam         
                                                                              
UNUSUAL FIRE AND EXPLOSION HAZARDS                                            
Containers may explode when exposed to extreme heat.                          
Application to hot surfaces requires special precautions.                     
During emergency conditions overexposure to decomposition products may cause a
health hazard. Symptoms may not be immediately apparent. Obtain medical       
attention.                                                                    
                                                                              
SPECIAL FIRE FIGHTING PROCEDURES                                              
Full protective equipment including self-contained breathing apparatus should 
be used.                                                                      
Water spray may be ineffective.  If water is used, fog nozzles are preferable.
Water may be used to cool closed containers to prevent pressure build-up and  
possible auto-ignition or explosion when exposed to extreme heat.             
                                                                              
SECTION 6 - ACCIDENTAL RELEASE MEASURES                                       
                                                                              
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED                     
Remove all sources of ignition. Ventilate the area.                           
Remove with inert absorbent.                                                  
                                                                              
SECTION 7 - HANDLING AND STORAGE                                              
                                                                              
SOTRAGE CATEGORY                                                              
Not Available                                                                 
                                                                              
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE                               
Keep away from heat, sparks and open flame. Vapors will accumulate readily and
may ignite explosively.                                                       
During use and until all vapors are gone: Keep area ventilated - Do not smoke 
- Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric
tools and appliances, and any other sources of ignition.                      
Consult NFPA Code. Use approved Bonding and Grounding procedures.             
Contents under pressure. Do not puncture, incinerate or expose to temperature 
above 120F. Heat from sunlight, radiators, stoves, hot water and other heat   
sources could cause container to burst. Do not take internally. Keep out of   
the reach of children.                                                        
                                                                              
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION                           
                                                                              
PRECAUTIONS TO  Use only with adequate ventilation.                           
BE TAKEN IN USE Avoid contact with skin and eyes. Avoid breathing vapor and   
                spray mist.                                                   
                Wash hands after using.                                       
                This coating may contain materials classified as nuisance     
                particulates (listed "as dust" in Section 2) which may present
                at hazardous levels only during sanding or abrading of the    
                dried film. If no specific dusts are listed in Section 2, the 
                applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3   
                (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3  
              (total dust), 5 mg/m3 (respirable fraction).                   
                                                                              
VENTILATION     Local exhaust preferable. General exhaust acceptable if the   
                exposure to materials in Section 2 is maintained below        
                applicable exposure limits. Refer to OSHA Standards 1910.94,  
                1910.107, 1910.108.                                           
                                                                              
RESPIRATORY     If personal exposure cannot be controlled below applicable    
PROTECTION      limits by ventilation, wear a properly fitted organic         
                vapor/particulate respirator approved by NIOSH/MSHA for       
                protection against materials in Section 2.                    
                When sanding or abrading the dried film, wear a dust/mist     
                respirator approved by NIOSH/MSHA for dust which may be       
                generated from this product, underlying paint, or the         
                abrasive.                                                     
                                                                              
PROTECTIVE      None required for normal application of aerosol products where
GLOVES          minimal skin contact is expected. For long or repeated        
                contact, wear chemical resistant gloves.                      
                                                                              
EYE PROTECTION  Wear safety spectacles with unperforated sideshields.         
                                                                              
OTHER           Intentional misuse by deliberately concentrating and inhaling 
PRECAUTIONS     the contents can be harmful or fatal.                         
                                                                              
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES                                  
                                                                              
PRODUCT WEIGHT         6.65 lb/gal                 796 g/l                    
SPECIFIC GRAVITY       0.80                                                   
BOILING POINT          <0 - 342 F                  <-18 - 172 C               
MELTING POINT          Not Available                                          
VOLATILE VOLUME        92%                                                    
EVAPORATION RATE       Faster than ether                                      
VAPOR DENSITY          Heavier than air                                       
SOLUBILITY IN WATER    N.A.                                                   
pH                     7.0                                                    
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As packaged                     
Volatile Weight 49.07 %                Less Water and Federally Exempt       
                                       Solvents                              
                                                                              
SECTION 10 - STABILITY AND REACTIVITY                                         
                                                                              
STABILITY                          Stable                                     
CONDITIONS TO AVOID                None Known.                                
IMCOMPATABILITY                    None Known.                                
HAZARDOUS DECOMPOSITION PRODUCTS   By fire: Carbon Dioxide, Carbon Monoxide,  
                                   Hydrogen Chloride                          
HAZARDOUS POLYMERIZATION           Will not occur                             
                                                                              
SECTION 11 - TOXICOLOGICAL INFORMATION                                        
                                                                              
CHRONIC HEALTH HAZARDS                                                        
Methyl Ethyl Ketone may increase the nervous system effects of other solvents.
                                                                              
Reports have associated repeated and prolonged overexposure to solvents with  
permanent brain and nervous system damage.                                    
IARC's Monograph No. 93 reports there is sufficient evidence of               
carcinogenicity in experimental rats exposed to titanium dioxide but          
inadequate evidence for carcinogenicity in humans and has assigned a Group 2B 
rating. In addition, the IARC summary concludes, "No significant exposure to  
titanium dioxide is thought to occur during the use of products in which      
titanium is bound to other materials, such as paint."                         
                                                                              
TOXICOLOGY DATA                                                               
CAS No.      Ingredient Name                                                  
74-98-6      Propane                        LC50 RAT    4HR      Not Available
                                            LD50 RAT                          
                                                                 Not Available
106-97-8     Butane                         LC50 RAT    4HR      Not Available
                                            LD50 RAT                          
                                                                 Not Available
108-88-3     Toluene                        LC50 RAT    4HR      4000 ppm     
                                            LD50 RAT             5000 mg/kg   
67-64-1      Acetone                        LC50 RAT    4HR      Not Available
                                            LD50 RAT                          
                                                                 5800 mg/kg   
78-93-3      Methyl Ethyl Ketone            LC50 RAT    4HR      Not Available
                                            LD50 RAT                          
                                                                 2740 mg/kg   
108-10-1     Methyl Isobutyl Ketone         LC50 RAT    4HR      Not Available
                                            LD50 RAT                          
                                                                 2080 mg/kg   
763-69-9     Ethyl 3-Ethoxypropionate       LC50 RAT    4HR      Not Available
                                            LD50 RAT                          
                                                                 5000 mg/kg   
123-86-4     n-Butyl Acetate                LC50 RAT    4HR      2000 ppm     
                                            LD50 RAT             13100 mg/kg  
110-19-0     Isobutyl Acetate               LC50 RAT    4HR      Not Available
                                            LD50 RAT                          
                                                                 13400 mg/kg  
14807-96-6   Talc                           LC50 RAT    4HR      Not Available
                                            LD50 RAT                          
                                                                 Not Available
13463-67-7   Titanium Dioxide               LC50 RAT    4HR      Not Available
                                            LD50 RAT                          
                                                                 Not Available
                                                                              
SECTION 12 - ECOLOGICAL INFORMATION                                           
                                                                              
ECOTOXICOLOGICAL INFORMATION                                                  
No data available.                                                            
                                                                              
SECTION 13 - DISPOSAL CONSIDERATIONS                                          
                                                                              
WASTE DISPOSAL METHOD                                                         
Waste from this product may be hazardous as defined under the Resource        
Conservation and Recovery Act (RCRA) 40 CFR 261.                              
Waste must be tested for ignitability to determine the applicable EPA         
hazardous waste numbers.                                                      
Do not incinerate. Depressurize container. Dispose of in accordance with      
Federal, State/Provincial, and Local regulations regarding pollution.         
                                                                              
SECTION 14 - TRANSPORT INFORMATION                                            
                                                                              
US Ground (DOT)                                                               
May be classed as Consumer Commodity, ORM-D                                   
UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126)                            
                                                                              
Canada (TDG)                                                                  
May be classed as Consumer Commodity, ORM-D                                   
UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126)                      
                                                                              
IMO                                                                           
May be shipped as Limited Quantity                                            
UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, EmS F-D, S-U, ADR (D)          
                                                                              
SECTION 15 - REGULATORY INFORMATION                                           
                                                                              
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION                               
CAS No.             CHEMICAL/COMPOUND            % by WT    % Element          
108-88-3            Toluene                      8                             
108-10-1            Methyl Isobutyl Ketone       7                             
CALIFORNIA PROPOSITION 65                                                     
WARNING: This product contains chemicals known to the State of California to  
cause cancer and birth defects or other reproductive harm.                    
                                                                              
TSCA CERTIFICATION                                                            
All chemicals in this product are listed, or are exempt from listing, on the  
TSCA Inventory.                                                               
                                                                              
SECTION 16 - OTHER INFORMATION                                                
                                                                              
This product has been classified in accordance with the hazard criteria of the
Canadian Controlled Products Regulations (CPR) and the                        
MSDS contains all of the information required by the CPR.                     
                                                                              
The above information pertains to this product as currently formulated, and is
based on the information available at this time. Addition of reducers or other
additives to this product may substantially alter the composition and hazards 
of the product. Since conditions of use are outside our control, we make no   
warranties, express or implied, and assume no liability in connection with any
use of this information.                                                      
                                                                              
                                                                              
                                                                              
                                                                              
                                                                              
                                                                              
                                                                              
                                                                              
                                                                              
                                                                              
                                                                              
                                                                              
                                                                              
                                                                              
                                                                              

The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance.

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