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MSDS 85018 85018: Self Etching Gray Primer 16 Oz [12]MSDS Last updated: 02/01/2010
IMPERIAL SUPPLIES LLC MSDS SHEET FOR 85018
Date of Preparation
Jan 13, 2010
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NUMBER: C27869000
PRODUCT NAME: 85018 SELF ETCH PRIMER
MANUFACTURER'S NAME CBD Group
101 Prospect Ave.
Cleveland, OH 44115
Telephone Numbers and Websites
Regulatory Information (216) 566-2902
www.paintdocs.com
Medical Emergency (216) 566-2917
Transportation Emergency (800) 424-9300
*for Chemical Emergency ONLY (spill, leak, fire, exposure or accident)
SECTION 2 - COMPOSITION / INFORMATION ON INGREDIENTS
% by CAS Number Ingredient Units Vapor
Weight Pressure
11 74-98-6 Propane 760 mm
ACGIH TLV 2500 PPM
OSHA PEL 1000 PPM
11 106-97-8 Butane 760 mm
ACGIH TLV 800 PPM
OSHA PEL 800 PPM
8 108-88-3 Toluene 22 mm
ACGIH TLV 20 PPM
OSHA PEL 100 PPM (skin)
OSHA PEL 150 PPM (skin) STEL
34 67-64-1 Acetone 180 mm
ACGIH TLV 500 PPM
ACGIH TLV 750 PPM STEL
OSHA PEL 1000 PPM
2 78-93-3 Methyl Ethyl Ketone 70 mm
ACGIH TLV 200 PPM
ACGIH TLV 300 PPM STEL
OSHA PEL 200 PPM
OSHA PEL 300 PPM STEL
7 108-10-1 Methyl Isobutyl 16 mm
Ketone
ACGIH TLV 50 PPM
ACGIH TLV 75 PPM STEL
OSHA PEL 50 PM
OSHA PEL 75 PPM STEL
2 763-69-9 Ethyl 1.11 mm
3-Ethoxypropionate
ACGIH TLV Not Available
OSHA PEL Not Available
1 123-86-4 n-Butyl Acetate 10 mm
ACGIH TLV 150 PPM
ACGIH TLV 200 PPM STEL
OSHA PEL 150 PPM
OSHA PEL 200 PPM STEL
5 110-19-0 Isobutyl Acetate 12.5 mm
ACGIH TLV 150 PPM
OSHA PEL 150 PPM
6 14807-96-6 Talc
ACGIH TLV 2 mg/m3 as Resp.
Dust
OSHA PEL 2 mg/m3 as Resp.
Dust
3 13463-67-7 Titanium Dioxide
ACGIH TLV 10 mg/m3 as Resp.
Dust
OSHA PEL 10 mg/m3 as Total
Dust
OSHA PEL 5 mg/m3 Respirable Fraction
SECTION 3 - HAZARDS IDENTIFICATION
HMIS Codes Health: 2 Flammability: 3 Reactivity: 0
ROUTES OF EXPOSURE INHALATION of vapor or spray mist
EYE or SKIN contact with the product, vapor or spray
mist.
EFFECTS OF EYES: Irritation.
OVEREXPOSURE
SKIN: Prolonged or repeated exposure may cause
irritation.
INHALATION: Irritation of the upper respiratory
system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
Prolonged overexposure to solvent ingredients in Section 2 may cause adverse
effects to the liver, urinary, blood forming, cardiovascular and reproductive
systems.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive skin
exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
SECTION 4 - FIRST AID MEASURES
EYES: Flush eyes with large amounts of water for 15 minutes. Get
medical attention.
SKIN: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re-use.
INHALATION: If affected, remove from exposure. Restore breathing. Keep warm
and quiet.
INGESTION: Do not induce vomiting. Get medical attention immediately.
SECTION 5 - FIRE FIGHTING MEASURES
FLASH POINT LEL UEL EXTINGUISHING MEDIA
Propellant <0 F 1.0 12.8 Carbon Dioxide, Dry Chemical , Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may cause a
health hazard. Symptoms may not be immediately apparent. Obtain medical
attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self-contained breathing apparatus should
be used.
Water spray may be ineffective. If water is used, fog nozzles are preferable.
Water may be used to cool closed containers to prevent pressure build-up and
possible auto-ignition or explosion when exposed to extreme heat.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
SECTION 7 - HANDLING AND STORAGE
SOTRAGE CATEGORY
Not Available
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep away from heat, sparks and open flame. Vapors will accumulate readily and
may ignite explosively.
During use and until all vapors are gone: Keep area ventilated - Do not smoke
- Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric
tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Contents under pressure. Do not puncture, incinerate or expose to temperature
above 120F. Heat from sunlight, radiators, stoves, hot water and other heat
sources could cause container to burst. Do not take internally. Keep out of
the reach of children.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
PRECAUTIONS TO Use only with adequate ventilation.
BE TAKEN IN USE Avoid contact with skin and eyes. Avoid breathing vapor and
spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance
particulates (listed "as dust" in Section 2) which may present
at hazardous levels only during sanding or abrading of the
dried film. If no specific dusts are listed in Section 2, the
applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3
(total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).
VENTILATION Local exhaust preferable. General exhaust acceptable if the
exposure to materials in Section 2 is maintained below
applicable exposure limits. Refer to OSHA Standards 1910.94,
1910.107, 1910.108.
RESPIRATORY If personal exposure cannot be controlled below applicable
PROTECTION limits by ventilation, wear a properly fitted organic
vapor/particulate respirator approved by NIOSH/MSHA for
protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist
respirator approved by NIOSH/MSHA for dust which may be
generated from this product, underlying paint, or the
abrasive.
PROTECTIVE None required for normal application of aerosol products where
GLOVES minimal skin contact is expected. For long or repeated
contact, wear chemical resistant gloves.
EYE PROTECTION Wear safety spectacles with unperforated sideshields.
OTHER Intentional misuse by deliberately concentrating and inhaling
PRECAUTIONS the contents can be harmful or fatal.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
PRODUCT WEIGHT 6.65 lb/gal 796 g/l
SPECIFIC GRAVITY 0.80
BOILING POINT <0 - 342 F <-18 - 172 C
MELTING POINT Not Available
VOLATILE VOLUME 92%
EVAPORATION RATE Faster than ether
VAPOR DENSITY Heavier than air
SOLUBILITY IN WATER N.A.
pH 7.0
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As packaged
Volatile Weight 49.07 % Less Water and Federally Exempt
Solvents
SECTION 10 - STABILITY AND REACTIVITY
STABILITY Stable
CONDITIONS TO AVOID None Known.
IMCOMPATABILITY None Known.
HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide,
Hydrogen Chloride
HAZARDOUS POLYMERIZATION Will not occur
SECTION 11 - TOXICOLOGICAL INFORMATION
CHRONIC HEALTH HAZARDS
Methyl Ethyl Ketone may increase the nervous system effects of other solvents.
Reports have associated repeated and prolonged overexposure to solvents with
permanent brain and nervous system damage.
IARC's Monograph No. 93 reports there is sufficient evidence of
carcinogenicity in experimental rats exposed to titanium dioxide but
inadequate evidence for carcinogenicity in humans and has assigned a Group 2B
rating. In addition, the IARC summary concludes, "No significant exposure to
titanium dioxide is thought to occur during the use of products in which
titanium is bound to other materials, such as paint."
TOXICOLOGY DATA
CAS No. Ingredient Name
74-98-6 Propane LC50 RAT 4HR Not Available
LD50 RAT
Not Available
106-97-8 Butane LC50 RAT 4HR Not Available
LD50 RAT
Not Available
108-88-3 Toluene LC50 RAT 4HR 4000 ppm
LD50 RAT 5000 mg/kg
67-64-1 Acetone LC50 RAT 4HR Not Available
LD50 RAT
5800 mg/kg
78-93-3 Methyl Ethyl Ketone LC50 RAT 4HR Not Available
LD50 RAT
2740 mg/kg
108-10-1 Methyl Isobutyl Ketone LC50 RAT 4HR Not Available
LD50 RAT
2080 mg/kg
763-69-9 Ethyl 3-Ethoxypropionate LC50 RAT 4HR Not Available
LD50 RAT
5000 mg/kg
123-86-4 n-Butyl Acetate LC50 RAT 4HR 2000 ppm
LD50 RAT 13100 mg/kg
110-19-0 Isobutyl Acetate LC50 RAT 4HR Not Available
LD50 RAT
13400 mg/kg
14807-96-6 Talc LC50 RAT 4HR Not Available
LD50 RAT
Not Available
13463-67-7 Titanium Dioxide LC50 RAT 4HR Not Available
LD50 RAT
Not Available
SECTION 12 - ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
No data available.
SECTION 13 - DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Do not incinerate. Depressurize container. Dispose of in accordance with
Federal, State/Provincial, and Local regulations regarding pollution.
SECTION 14 - TRANSPORT INFORMATION
US Ground (DOT)
May be classed as Consumer Commodity, ORM-D
UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126)
Canada (TDG)
May be classed as Consumer Commodity, ORM-D
UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126)
IMO
May be shipped as Limited Quantity
UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, EmS F-D, S-U, ADR (D)
SECTION 15 - REGULATORY INFORMATION
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No. CHEMICAL/COMPOUND % by WT % Element
108-88-3 Toluene 8
108-10-1 Methyl Isobutyl Ketone 7
CALIFORNIA PROPOSITION 65
WARNING: This product contains chemicals known to the State of California to
cause cancer and birth defects or other reproductive harm.
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing, on the
TSCA Inventory.
SECTION 16 - OTHER INFORMATION
This product has been classified in accordance with the hazard criteria of the
Canadian Controlled Products Regulations (CPR) and the
MSDS contains all of the information required by the CPR.
The above information pertains to this product as currently formulated, and is
based on the information available at this time. Addition of reducers or other
additives to this product may substantially alter the composition and hazards
of the product. Since conditions of use are outside our control, we make no
warranties, express or implied, and assume no liability in connection with any
use of this information.
The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance. For more product information by email, click here Imperial Supplies LLC does not provide services and products outside the United States |
