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MSDS 85017 85017: Light Machine Gray 20 Oz [6]MSDS Last updated: 03/22/2004
MATERIAL SAFETY DATA SHEET
Acc. To ISO/DIS 11014
Printing date 01/27/2004
Reviewed on 01/26/2004
1. IDENTIFICATION OF SUBSTANCE
Trade Name: MRO LIGHT GRAY ASA 70
Product Code; 0006201418
Manufacturer/Supplier: SEYMOUR OF SYCAMORE
917 Crosby Avenue
Sycamore, IL 60178
(815)-895-9101, www.seymourpaint.com
Information department: Health & Safety Department
Emergency information: CHEMTEL 1-800-255-3924, 813-248-0585 if located
outside the U.S.
Imperial part #85017
2. CHEMICAL DATA
Chemical Description: This product is a mixture of the substances listed
below with nonhazardous additions.
Dangerous Components:
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67-64-1 acetone Xi, F: R 11-36-66-67 20.89%
74-98-6 propane F+: R 12 15.74%
106-97-8 n-butane F+: R 12 9.25%
7727-43-7 barium sulphate, natural Xi: R 37 8.81 %
2807-30-9 Glycol Ether EP Xi: R 10-36/37/38 5.64%
108-10-1 methyl isobutyl ketone Xn, F: R 11-20-36/37-66 5.45%
13463-67-7 titanium dioxide Xi: R 37 4.14%
107-87-9 Methyl Propyl Ketone F:R 11 3.51%
110-19-0 isobutyl acetate F: R 11-66 2.82%
1330-20-7 xylene (mix) Xn: R 10-20/21-38 2.63%
Additional information: For the wording of the listed risk phrases refer to
Section 3.
3. HAZARDS IDENTIFICATION
Hazard description: Xi Irritant
F+ Extremely flammable
Physical and
Environmental dangers: Warning! Pressurized container.
Has a narcotizing effect R12 Extremely flammable.
R 36/37 Irritating to eyes and respiratory system.
R 67 Vapors may cause drowsiness and dizziness
Pressurized container: protect from sunlight and do not
expose to temperatures exceeding 50°C, i.e. electric
lights. Do not pierce or burn, even after use.
Keep out of the reach of children.
NFPA ratings (scale 0-4); Health = 1
Fire = 4
Reactivity = 3
HMIS-ratings (scale 0 – 4): Health = 1
Fire = 4
Physical Hazard = 3
4. FIRST AID MEASURES
After inhalation; Supply fresh air: consult doctor in case of complaints.
After skin contact; Generally the product does not irritate the skin.
After eye contact: Rinse opened eye for several minutes under running water.
If symptoms persist, consult a doctor.
After swallowing: Consult a doctor if symptoms persist.
5. FIRE FIGHTING MEASURES
Extinguishing agents: CO2, sand, extinguishing powder, or water spray. Fight
larger fires with water spray or alcohol resistant foam.
Protective equipment: No special measures required.
6. ACCIDENTAL RELEASE MEASURES
Personal safety
precautions: Wear protective equipment. Keep unprotected persons away.
Environmental safety
precautions: Do not allow product to reach sewage systems or ground
water. Inform appropriate authorities in case of seepage
into water course or sewage system.
Measures for cleaning/
collecting: Do not flush with water or aqueous cleansing agents. Use
diluted caustic solution. Soak up spills with inert
absorbent material. Refer to section 13 for disposal
information.
7. HANDLING AND STORAGE
Safe handling
information: Ensure good ventilation/exhaustion at the workplace.
Handle carton and cans with care. Avoid dropping.
Fire/explosion protection: Do not spray on a naked flame or any incandescent
material. Keep ignition sources away – Do not
smoke.
Protect against electrostatic charges.
Storage requirements; Observe official regulations on storing packaging with
pressurized containers. Consult with your local
authorities.
Keep away from sources of heat and direct sunlight. Do
not warehouse in subfreezing conditions.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with limit values that require monitoring at the workplace:
--------------------------------------------------------------------------------
67-64-1 acetone
PEL 2400 mg/m3, 1000 ppm
REL 590 mg/m3, 250 ppm
TLV Short-term value: 1782 mg/m3, 750 ppm
Long-term value: 1188 mg/m3, 500 ppm
BEI
74-98-6 propane
PEL 1800 mg/m3, 1000 ppm
REL 1800 mg/m3, 1000 ppm
TLV (4508) mg/m3, (2500) ppm
106-97-8 n-butane
REL 1900 mg/m3, 800 ppm
TLV 1900 mg/m3, 800 ppm
7727-43-7 barium sulphate, natural
PEL 15*, 5** mg/m3
Total dust** Respirable fraction
REL 10*,5**mg/m3
Total dust**Respirable fraction
TLV 10mg/m3
(e)
108-10-1 methyl isobutyl ketone
PEL 410 mg/m3, 100 ppm
REL Short-term value: 300 mg/m3, 75 ppm
Long-term value: 205 mg/m3, 50 ppm
TLV Short-term value: 307 mg/m3, 75 ppm
Long-term value: 205 mg/m3, 50 ppm
BEI
107-87-9 Methyl Propyl Ketone
PEL 700 mg/m3, 200 ppm
REL 530 mg/m3, 150 ppm
TLV Short-term value; 881 mg/m3, 250 ppm
Long-term value; 705 mg/m3, 200 ppm
110-19-09 isobutyl acetate
PEL 700 mg/m3, 150 ppm
REL 700 mg/m3, 150 ppm
TLV 713 mg/m3, 150 ppm
1330-20-7 xylene (mix)
PEL 435 mg/m3, 100 ppm
REL Short-term value: 655 mg/m3, 150 ppm
Long-term value: 435 mg/m3, 100 ppm
(o-,m-,& p-isomers)
TLV Short-term value: 651 mg/m3,150 ppm
Long-term value: 434 mg/m3, 100 ppm
BEI
Protective hygienic
measures: Keep away from foodstuffs, beverages, and animal feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Breathing
Equipment; A respirator is generally not necessary when using this
product outdoors or in large open area. In cases of
inadequate ventilation, a respiratory protective device
should be worn to prevent overexposure. Use suitable
respiratory protective device in case of insufficient
ventilation.
Protection of
hands; Protective gloves. The glove material has to be impermeable
and resistant to the substance. No glove recommendation can
be given.
Eye Protection; Tightly sealed goggles.
9. PHYSICAL AND CHEMICAL PROPERTIES
General Information;
Form; Aerosol
Color: According to trade name description in section 1.
Odor: Solvent
Boiling point/
Boiling range: -44°C (-47°F)
Flash point; -19°C (-2°F)
Ignition temperature: 230.0°C (446°F)
Auto igniting: Product is not self-igniting.
Danger of explosion: Heating may cause an explosion.
In use, may form flammable/explosive vapor-air mixture.
Lower Explosion Limit; 1.7 Vol %
Upper Explosion Limit: 13.0 Vol %
Vapor Pressure: 40 PSI, 2750 hPa
Density; Not determined.
Specific Gravity; Between 0.77 and 0.90 (Water equals 1.00)
VOC content: 0.46 kg/l / 3.84 lb/gl
VOC in weight percent (less acetone); 46.0%
Solids content; 32.7%
10. STABILITY AND REACTIVITY
Conditions to be avoided; Do not allow the can to exceed 120 degrees
Fahrenheit. Stable at normal temperatures.
Possibility of Hazardous
Reactions: No dangerous reactions known.
11. TOXICOLOGICAL INFORMATION
Primary effect on the skin: No irritant effect.
Primary effect on the eye: Irritating effect.
Sensitization: No sensitizing effects known.
12. ECOLOGICAL INFORMATION
Other information; The product does not contain any chlorinated solvents
or lead. No specific ecological data is available for
this product.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD; Dispose of in accordance with local, state, and federal
regulations. Do not puncture, incinerate, or compact. Partially empty cans
cannot be disposed of with regular trash. Do not heat or cut empty containers
with electric or gas torches.
Recommendation: Empty cans should be recycled.
14. TRANSPORT INFORMATION
Hazard class; 2.3
Identification number N/A
Label 2.3+2.1+8
ADR/RID class; 2 5TFC Gases
UN-number: 1950
IMDG Class: 2.3
Packing group: II
EMS Number: F-D,S-U
Marine pollutant: No
ICAO/IATA Class: 2.3
Proper shipping name: Aerosols, Flammable
Consumer Commodity ORM-D
15. REGULATIONS
SARA Section 355 (extremely hazardous substances):
None of the ingredients in this product are listed.
SARA Section 313 (Specific toxic chemical listings):
108-10-1 methyl isobutyl ketone
1330-20-7 xylene (mix)
100-41-4 ethyl benzene
TSCA (Toxic Substances Control Act):
67-64-1 acetone
74-98-6 propane
106-97-8 n-butane
7727-43-7 barium sulphate, natural
2807-30-9 Glycol Ether EP
108-10-1 methyl isobutyl ketone
13463-67-7 titanium dioxide
107-87-9 Methyl Propyl Ketone
110-19-0 isobutyl acetate
1330-20-7 xylene (mix)
100-41-4 ethyl benzene
8002-43-5 Soya Lecithin
22464-99-9 solid zirco drier
64742-47-8 Mineral Spirits
96-29-7 2-butanone oxime
PROPOSITION 65 Chemicals known to cause cancer;
None of the ingredients in this product are listed.
PROPOSITION 65 Chemicals known to cause reproductive toxicity;
None of the ingredients in this product are listed.
Canadian WHMIS; This product has been classified according to the Controlled
Product Regulations and the MSDS contains all the necessary
Information required by the CPR.
Class B, D5---Flammable Aerosols
EPA; A=Known human carcinogen
B=Probable human carcinogen
C=possible human carcinogen
D=Not classifiable as to human carcinogenicity; Inadequate human
and animal evidence of carcinogenicity (or no data is
available).
67-64-1 acetone D
110-19-0 isobutyl acetate D
1330-20-7 xylene (mix) D
100-41-4 ethyl benzene D
IARC: Group 2B; The ingredient is possibly carcinogenic to humans.
There is limited evidence of carcinogenicity.
Group 3: The ingredient is unclassifiable as to its
carcinogenicity to humans.
13463-67-7 titanium dioxide 3
1330-20-7 xylene (mix) 3
1333-86-4 Carbon black 2B
ACHIH TLV’s A1-designates a confirmed human carcinogen.
A2-designates a suspected human carcinogen.
A3-designates an animal carcinogen.
A4-designates “not classifiable as a human carcinogen.”
67-64-1 acetone A4
13463-67-7 titanium dioxide A4
110-19-0 isobutyl acetate A4
1330-20-7 xylene (mix) A4
1333-86-4 Carbon black A4
NIOSH
13463-67-7 titanium dioxide
1333-86-4 Carbon black
16. OTHER INFORMATION
This information is based on our present knowledge. However, this shall not
constitute a guarantee for any specific product features and shall not establish
a legally valid contractual relationship.
Contact; Craig Swafford, Regulatory Affairs:
Email: cswafford@seymourpaint.com
The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance. For more product information by email, click here Imperial Supplies LLC does not provide services and products outside the United States |
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