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MSDS 82126 82126: 1/2 Lb Solid Solder Lead Free [1]82127: 1 Lb Solid Solder Lead Free [1] MSDS Last updated: 01/13/2010
IMPERIAL SUPPLIES LLC MSDS SHEET FOR 82127
Emergency phone: US & Canada: 800-424-9300
Mexico: 01 800 022 1400, (55) 5559 1588
Health 1 Health 1
Flammability 0 Flammability 0
Instability 0 Physical 0
hazards
Special Personal
protection
1. PRODUCT AND COMPANY IDENTIFICATION
Product name: Solder Alloy 96Sn/3.9Cu/0.1Ag
Bar, Solid Wire, Ribbon, Preforms
Vaculoy, Hi-flo, SMG, HAL, JetFlo, Fry-Lo, Exactalloy,
Copperflo, Flo-Temp, Cleanwave
Product code: 129921
Manufacturer: Cookson Electronics Cookson Electronics Mexico, S.A. de C.
109 Corporate Blvd. V.
South Plainfield, NJ Avenida Nafta No. 800,
07080 Parque Industrial Stiva Aeropuerto
Toll Free: (800) Apodaca, Nuevo Leon, C.P. 66600
367-5460 Mexico
Main Phone: (908) www.coosonelectronics.com
791-3000 Customer Service: (814) 946-1611
Fax: (908) 791-3090
www.alphametals.com
Validation 2/3/2009 Supersedes Date: 6/11/2008
date:
Prepared by: T. Valverde
(203)-799-4917
2. HAZARDS IDENTIFICATION
Physical state: Solid.
Odor: None.
OSHA/HCS status: This material is considered hazardous by the OSHA Hazard
Communication Standard (29 CFR 1910.1200).
Emergency overview: WARNING!
Harmful if swallowed. Irritating to eyes, respiratory
system and skin. Do not ingest. Avoid contact with eyes,
skin and clothing. Contains material that can cause target
organ damage. Use only with adequate ventilation. Keep
container tightly closed and sealed until ready for use.
Wash thoroughly after handling.
Routes of entry: Inhalation. Ingestion.
Potential acute health effects
Inhalation Irritating to respiratory system
:
Ingestion: Harmful if swallowed. Can cause target organ damage. Ingestion may
cause gastrointestinal irritation and diarrhea.
Skin: Irritating to skin. Skin inflammation is characterized by itching,
scaling, reddening or occasionally, blistering.
Eyes: Irritating to eyes. Adverse symptoms may include the following:
redness, itching, swelling, pain.
Potential chronic health effects
Chronic effects: Adverse symptoms may include the following:
Tin: Prolonged or repeated exposure may cause benign
pneumoconiosis (Stannosis).
Copper: Other adverse effects: metal fume fever, coughing,
headache, shortness of breath/breathing difficulty, anemia.
Chronic effects: jaundice, ulcerations.
Target organs: Contains material which causes damage to the following
organs: upper respiratory tract, skin, eye, lens or cornea.
Contains material which may cause damage to the following
organs: kidneys, liver.
Carcinogenicity: Not classified or listed by IARC, NTP, OSHA, EU and ACGIH.
Mutagenicity: No conclusive data is available to indicate product or any
component present at greater than 0.1% may cause heritable
genetic effects.
Developmental No conclusive data is available to indicate product or any
effects: component present at greater than 0.1% may cause
developmental abnormalities.
Fertility effects: No conclusive data is available to indicate product or any
component present at greater than 0.1% may impair
fertility.
Medical conditions Pre-existing digestive disorders and disorders involving
aggravated by any other target organs mentioned in this MSDS as being at
over-exposure: risk may be aggravated by over-exposure to this product.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Name CAS number % by weight
Tin 7440-31-5 80-100
Copper 7440-50-8 1-5
Any ingredient not listed in Section 3 is non-regulated or present in the
product in concentrations below legal disclosure limits.
4. FIRST AID MEASURES
Eye contact: Check for and remove any contact lenses. Get medical attention if
irritation occurs. Immediately flush eyes with running water for
at least 30 minutes keeping eyelids open.
Skin Flush contaminated skin with plenty of water. Remove contaminated
contact: clothing and shoes. Continue to rinse for at least 15 minutes.
Get medical attention if symptoms occur. Wash contaminated
clothing before reuse. Clean shoes thoroughly before reuse. Seek
medical attention if irritation persists. In case of contact,
immediately flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Inhalation: Get medical attention immediately. Move exposed person to fresh
air. If it is suspected that fumes are still present, the rescuer
should wear an appropriate mask of self-contained breathing
apparatus. Keep person warm and at rest. If not breathing, if
breathing is irregular or if respiratory arrest occurs, provide
artificial respiration or oxygen by trained personnel. It may be
dangerous to the person providing aid to give mouth to mouth
resuscitation. If unconscious, place in recovery position and get
medical attention immediately. Maintain an open airway. Loosen
tight clothing such as collar, tie, belt or waistband.
Ingestion: Get medical attention immediately. Wash out mouth with water.
Remove dentures if any. Move exposed person to fresh air. Keep
person warm and at rest. Do not induce vomiting unless directed
to do so by medical personnel. If vomiting occurs, the head
should be kept low so that vomit does not enter the lungs. Never
give anything by mouth to an unconscious person. If unconscious,
place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as collar,
tie, belt or waistband. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel.
Protection No action shall be taken involving any personal risk or without
of first suitable training. It may be dangerous to the person providing
aiders: aid to give mouth-to-mouth resuscitation. Wear suitable
protective clothing, gloves and eye/face protection. If it is
suspected that fumes are still present, the rescuer should wear
an appropriate mask or self-contained breathing apparatus.
5. FIRE-FIGHTING MEASURES
Flammability of the No specific fire or explosion hazard.
product:
Extinguishing media
Suitable: Use an extinguishing agent suitable for the surrounding fire.
Not suitable: None known.
Special exposure Promptly isolate the scene by removing all persons from
hazards: the vicinity of the incident if there is a fire. No
action shall be taken involving any personal risk or
without suitable training. Fire water contaminated with
this material must be contained and prevented from
being discharged to any waterway, sewer or drain.
Hazardous combustion Metal oxide/oxides
products:
Special remarks on Flammable in the presence of the following materials or
fire hazards: conditions: open flames, sparks and static discharge
and heat.
Special remarks on Explosive in the presence of the following materials or
explosion hazards: conditions: open flames, sparks and static discharge
and heat.
Special protective Fire-fighters should wear appropriate protective
equipment for equipment and self contained breathing apparatus (SCBA)
fire-fighters: with a full face-piece operated in positive pressure
mode.
6. ACCIDENTAL RELEASE MEASURES
Personal No action shall be taken involving any personal risk or
precautions: without suitable training. Evacuate surrounding areas. Keep
unnecessary and unprotected personnel from entering. Do not
touch or walk through spilled material. Provide adequate
ventilation. Wear appropriate respirator when ventilation
is inadequate. Put on appropriate personal protective
equipment (see section 8).
Environmental Avoid dispersal of spilled material and runoff and contact
precautions: with soil, waterways, drains and sewers. Inform the
relevant authorities if the product has caused
environmental pollution (sewers, waterways, soil or air).
Water polluting material. May be harmful to the environment
if released in large quantities.
Large spill: Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements
or confined areas. Vacuum or sweep up material and place in
a designated, labeled waste container. Dispose of via a
licensed waste disposal contractor. Note: see section 1 for
emergency contact information and section 13 for waste
disposal.
Small spill: Move containers from spill area. Vacuum or sweep up
material and place in a designated, labeled waste
container. Dispose of via a licensed waste disposal
contractor.
7. HANDLING AND STORAGE
Handling: Put on appropriate personal protective equipment (see section 8).
Eating, drinking and smoking should be prohibited in areas where
this material is handled, stored and processed. Workers should wash
hands and face before eating, drinking and smoking. Avoid contact
with eyes, skin or clothing. Do not ingest. Avoid release to the
environment. Use only with adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Keep in the original
container or approved alternative container. Containers should be
kept closed when not in use. Empty containers retain product residue
and can be hazardous. Do not reuse container.
Storage: Store in accordance with local regulations. Store in original
container protected from direct sunlight in a dry, cool and
well-ventilated area, away from incompatible materials (see section
10) and food and drink. Keep container tightly closed and sealed
until ready for use. Containers that have been opened must be
carefully resealed and kept upright to prevent leakage. Do not store
in unlabeled containers. Use appropriate containment to avoid
environmental contamination.
Keep container in a cool, well-ventilated area. Keep container
tightly closed and sealed until ready for use. Avoid all possible
sources of ignition (spark or flame).
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Product name CAS number Exposure limits
Tin 7440-31-5 OSHA PEL (United States, 9/2005).
TWA: 2 mg/m3 8 hour(s).
ACGIH TLV (United States, 1/2008).
TWA: 2 mg/m3 8 hour(s).
NIOSH REL (United States, 6/2008). Notes: Note: The
REL and PEL also apply to other inorganic tin
compounds (as Sn) except tin oxides.
TWA: 2 mg/m3 10 hour(s).
Copper 7440-50-8 OSHA Final Rule (United States, 1989). Notes: As
copper
TWA: 1 mg/m3 8 hour(s). Form:
TWA: 0.1 mg/m3 8 hour(s). Form:
NIOSH REL (United States, 6/2008). Notes: Note: The
ERL and PEL also apply to other copper compounds (as
Cu) except Copper fumes.
TWA: 1 mg/m3 10 hour(s). Form: Dusts and Mists
OSHA PEL (United States, 11/2006).
TWA: 1 mg/m3 8 hour(s). Form Dusts and Mists
TWA: 0.1 mg/m3 8 hour(s). Form: Fume
OSHA PEL 1989 (United States, 11/2006).
TWA: 1 mg/m3, (as Cu) 8 hour(s). Form Dusts and
Mists
TWA: 0.1 mg/m3, (as Cu) 8 hour(s). Form: Fume
ACGIH TLV (United States, 1/2008). Notes: as Cu
TWA: 1 mg/m3, (as Cu) 8 hour(s).
ACGIH TLV (United States, 1/2008). Notes: Substances
for which the TLV is higher than the OSHA
Permissible Exposure Limit (PEL) and/or the NIOSH
Recommended Exposure Limite(REL). See CFR 58(124)
:36338-33351, June 30, 1993, for revised OSHA PEL.
Adopted Values enclosed are those for which changes
are proposed. Consult the Notice of Intended Changes
for current proposal. See Notice of Intended
changes.
TWA: 0.2 mg/m3 8 hour(s). Form: Fume
Consult local authorities for acceptable exposure limits
Recommended If this product contains ingredients with exposure limits,
monitoring personal, workplace atmosphere or biological monitoring may
procedures: be required to determine the effectiveness of the
ventilation or other control measures and/or the necessity
to use respiratory protective equipment.
Engineering Use only with adequate ventilation. If user operations
measures: generate dust, fumes, gas, vapor or mist, use process
enclosures, local exhaust ventilation or other engineering
controls to keep worker exposure to airborne contaminants
below any recommended or statutory limits. Processes
should be designed to minimize airborne and skin exposure
to hazardous substances.
Hygiene measures: Wash hands, forearms and face thoroughly after handling
chemical products, before eating, smoking and using the
lavatory and at the end of the working period. Appropriate
techniques should be used to remove potentially
contaminated clothing. Wash contaminated clothing before
reusing. Ensure that eyewash stations and safety showers
are close to the workstation location. Eating, drinking and
smoking should be prohibited in areas where this material
is handled, stored and processed. Remove/Take off
immediately all contaminated clothing. Contaminated work
clothing should not be allowed out of the workplace.
Personal protection
Respiratory: Use a properly fitted, air-purifying or air-fed respirator
complying with an approved standard if a risk assessment
indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of
the product and the safe working limits of the selected
respirator.
Hands: Chemical-resistant, impervious gloves complying with an
approved standard should be worn at all times when handling
chemical products if a risk assessment indicates this is
necessary. The user must check that the final choice of type
of glove selected for handling this product is the most
appropriate and takes into account the particular conditions
of use, as included in the user's risk assessment.
Eyes: Avoid contact with eyes. Safety eyewear should be used when
there is a likelihood of exposure.
Skin: Avoid contact with skin and clothing. Wear protective
clothing. Body garments used should be based upon the task
being performed (e.g., lab coat, chemical resistant protective
suit, sleevelets, synthetic apron, gauntlets) to avoid exposed
skin surfaces. Wash contaminated clothing thoroughly with
water before removing it, or wear gloves.
Environmental Emissions from ventilation or work process equipment should be
exposure checked to ensure they comply with the requirements of an
controls: environmental protection legislation. In some cases, fume
scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable
levels.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Solid
Flash point: Not available
Auto Ignition Not available
temperature:
Flammable limits: Not available
Color: Gray
Odor: None
pH: Not available
Boiling/condensation Not available
point:
Melting/freezing Not available
point:
Vapor pressure: Not available
Vapor density: Not available
Odor threshold: Not available
Evaporation rate: Not available
VOC: 0 g/l
Solubility: Insoluble in the following materials: cold water and
hot water.
10. STABILITY AND REACTIVITY
Stability: The product is stable
Conditions to avoid: No specific data
Incompatibility with Reactive with oxidizing agents, reducing agents, acids,
various substances: alkalis.
Chlorine, peroxides.
Hazardous Under normal conditions of storage and use, hazardous
decomposition decomposition products should not be produced.
products:
Other Hazardous Metal oxides, toxic. fumes
decomposition
products:
Hazardous Under normal conditions of storage and use, hazardous
polymerization: polymerization will not occur.
11. TOXICOLOGICAL INFORMATION
Alpha has not conducted specific studies on the toxicity of this product.
12. ECOLOGICAL INFORMATION
Aquatic ecotoxicity
Product/ingredient Test Result Species Exposure
name
Copper - Acute EC50 0.017 Daphnia - Water flea - 48 hours
to 0.026 mg/L Daphnia obtuse -
Fresh water neonate - <24 hours
1 Acute EC50 12 Daphnia - Water flea - 48 hours
ug/L Fresh water Ceriodaphnia dubia -
Neonate - <24 hours
2 Acute EC50 11 Daphnia - Water flea - 48 hours
ug/L Fresh water Ceriodaphnia dubia -
Neonate - <24 hours
3 Acute EC50 9 ug/L Daphnia - Water flea - 48 hours
Fresh water Ceriodaphnia dubia -
Neonate - <24 hours
4 Acute EC50 1.6 Daphnia - Water flea - 48 hours
ug/L Fresh water Ceriodaphnia dubia -
Neonate - <24 hours
5 Acute LC50 161 to Crustaceans - Shrimp - 48 hours
566 ug/L Fresh Paratya australiensis
water
6 Acute LC50 120 Crustaceans - Giant 48 hours
ug/L Marine water river prawn -
Macrobrachium
rosenbergii - LARVAE
7 Acute LC50 105 Crustaceans - Calanoida 48 hours
ug/L Marine water
8 Acute LC50 85 to Crustaceans - Fleshy 48 hours
138 ug/L Marine prawn - Penaeus
water chinensis
9 Acute LC50 57 to Crustaceans - Water 48 hours
64 ug/L Fresh flea - Simocephalus
water vetulus - <24 hours
10 Acute LC50 30 Fish - Chinook salmon - 96 hours
ug/L Fresh water Oncorhynchus
tshawytscha - 3 months
- 1.35 g
11 Acute LC50 27.8 Fish - Fathead minnow - 96 hours
to 42 ug/L Fresh Pimephales promelas -
water Juvenile (Fledgling,
Hatchling, Weanling) -
<1 months
12 Acute LC50 24 Fish - Striped bass - 96 hours
ug/L Fresh water Morone saxatilis -
LARVAE - 16 days
13 Acute LC50 >20 Fish - Chinook salmon - 96 hours
ug/L Oncorhynchus
tshawytscha - 1.35 g
14 Acute LC50 20 Fish - Chinook salmon - 96 hours
ug/L Fresh water Oncorhynchus
tshawytscha - 3 months
- 1.35 g
15 Acute LC50 17 to Daphnia - Water flea - 48 hours
21 ug/L Fresh Ceriodaphnia reticulate
water - <4 hours
16 Acute LC50 17 to Daphnia - Water flea - 48 hours
23 ug/L Fresh Ceriodaphnia dubia -
water Neonate - <12 hours
17 Acute LC50 14 to Daphnia - Water flea - 48 hours
17 ug/L Fresh Ceriodaphnia dubia -
water Neonate
18 Acute LC50 12 Daphnia - Water flea - 48 hours
ug/L Fresh water Ceriodaphnia dubia -
Neonate - <24 hours
19 Acute LC50 240 Crustaceans - Giant 48 hours
ug/L Marine water river prawn -
Macrobrachium
rosenbergii - LARVAE
20 Acute LC50 10.3 Fish - Fathead minnow - 96 hours
to 15.6 ug/L Pimephales promelas -
Fresh water Juvenile (Fledling,
Hatchling, Weanling) -
<1 months
21 Acute LC50 >10 Fish - Chinook salmon - 96 hours
ug/L Oncorhynchus tshawtscha
- 1.35 g
22 Acute LC50 9.4 to Fish - Fathead minnow - 96 hours
11.5 ug/L Fresh Pimephales promelas -
water Juvenile (Fledling,
Hatchling, Weanling) -
<1 months
23 Acute LC50 195 Crustaceans - Giant 48 hours
ug/L Marine water Giant river prawn -
Macrobrachium
rosenbergii - LARVAE
24 Acute Lc50 183 to Crustaceans - Shrimp - 48 hours
477 ug/L Fresh Paratya australiensis
water
25 Acute LC50 255 Crustaceans - Giant 48 hours
ug/L Marine water Giant river prawn -
Macrobrachium
rosenbergii - LARVAE
26 Acute LC50 248 to Crustaceans - Shrimp - 48 hours
2340 ug/L Fresh Paratya australiensis
water
27 Chronic NEL 0.01 Daphnia - Water flea - 48 hours
mg/L Fresh water Daphnia magna - 24
hours
28 Chronic NOEC 11.7 Fish - Chinook salmon - 96 hours
ug/L Fresh water Oncorhynchus
tshawytscha
13. DISPOSAL CONSIDERATIONS
Waste The generation of waste should be avoided or minimized wherever
disposal: possible. Empty containers or liners may retain some product
residues. This material and its container must be disposed of in
a safe way. Dispose of surplus and non-recyclable products via a
licensed waste disposal contractor. Disposal of this product,
solutions and any by-products should at all times comply with
the requirements of environmental protection and waste disposal
legislation and any regional local authority requirements. Avoid
dispersal of spilled material and runoff and contact with soil,
waterways, drains and sewers.
Disposal should be in accordance with applicable regional, national and local
laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE
CONTROLS/PERSONAL PROTECTION for additional handling information and
protection of employees.
14. TRANSPORT INFORMATION
Regulatory UN number Proper shipping Classes PG* Label Additional
information name information
DOT Classification Not - - -
regulated
*PG: Packing Group
15. REGULATORY INFORMATION
United States
HCS Irritating material
Classification: Target organ effects
U.S. Federal All ingredients comply with applicable rules or orders under
regulations: United States TSCA.
All components are listed or exempted.
TSCA 5(a)2 proposed significant rules: No products were
found.
TSCA 5(a)2 final significant rules: No products were found.
TSCA 12(b) one-time export: No products were found.
SARA 313
Product name
Form R - Reporting copper
requirements:
Supplier copper
notification:
Canada
WHMIS (Canada): Not controlled under WHMIS (Canada).
Canada Inventory: All components are listed or exempted.
International lists
China inventory All components are listed or exempted.
(IECSC):
Europe inventory: All components are listed or exempted.
Australia inventory All components are listed or exempted.
(AICS):
Japan inventory Not determined.
(ENCS):
Korea inventory All components are listed or exempted
(KECI):
Philippines inventory All components are listed or exempted.
(PICCS):
16. OTHER INFORMATION
Definition of Terms
ACGIH American Conference of Governmental Industrial
Hygienists
Ceiling Maximum exposure limit defined by OSHA
CAS Chemical Abstract Service
IARC International Agency for Research on Cancer
NIOSH National Institute for Occupational Safety and Health
NTP National Toxicology Program
OSHA Occupational Safety and Health Administration
PEL Permissible Exposure Limit
REL Recommended Exposure Limit
RTK Right to Know
SARA Superfund Amendments and Reauthorization Act
STEL Short Term Exposure Limit
TLV ACGIH Threshold Limit Value
TLV-C ACGIH Threshold Limit Value, Ceiling
TRADE SECRET Claimed as allowed under 29CFRS1910-1200
TSCA Toxic Substances Control Act
PPE Personal Protection Equipment
CEPA Canadian Environmental Protection Act
DSL Domestic Substance List
NDSL Non-domestic Substance List
NSN New Substance Notification Rules
Disclaimer
The information contained herein is based on data considered accurate.
However, no warranty is expressed of implied regarding the accuracy of these
data or the results to be obtained from the use thereof. Additionally, Cookson
Electronics assumes no responsibility for injury to the vendee or third
persons proximately caused by the material even if reasonable safety
procedures are followed. Furthermore, vendee assumes the risk in his use of
the material.
The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance. For more product information by email, click here Imperial Supplies LLC does not provide services and products outside the United States |
