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MSDS 82121 82121: 1/2 Lb Rosin Solder [1]MSDS Last updated: 08/26/2009
Alpha
MATERIAL SAFETY DATA SHEET
Emergency phone: US & Canada: 800-424-9300
Mexico: 01 800 022 1400, (55) 5559 1588
Health 1
Flammability 1
Instability 0
Special
Health 1
Flammability 1
Physical hazards 0
Personal Protection
1. Product and company identification
Product name: Solder Wire Cored 96.5Sn/4Cu/0.5Ag Alloy, RA-32 Flux
Product code: M478RA32
Manufacturer: Cookson Electronics
109 Corporate Blvd
South Plainfield, NJ 07080
Toll Free: (800) 367-5460
Main Phone: (908) 791-3000
Fax: (908) 791-3090
www.alphametals.com
Cookson Electronics Mexico, S.A.de C.V
Avenida nafta NO. 800,
Parque Industrial Stiva Aeropuerto
Apodaca, Nuevo Leon, C.P. 66600
Mexico
www.cooksonelectronics.com
Customer Service: (814) 946-1611
Validation date: 2/3/2009. Supersedes Date : 6/6/2008
Prepared by: T. Valverde
(203)-799-4917
2. Hazards identification
Physical state: Solid.
Odor: None.
OSHA/HCS status: This material is considered hazardous by the OSHA
Hazard Communication Standard (29 CFR 1910.1200).
Emergency overview: DANGER!
Very toxic if swallowed. Irritating to eyes,
respiratory system and skin. May cause
sensitization by skin contact. Do not ingest. Do
not get on skin or clothing. Avoid contact with
eyes. Contains material that can cause target organ
damage. Use only with adequate ventilation. Keep
container tightly closed and sealed until ready for
use. Wash thoroughly after handling.
Routes of entry: Dermal contact. Eye contact. Inhalation. Ingestion.
Potential acute health effects
Inhalation: Irritating to respiratory system.
Ingestion: Very toxic if swallowed. Can cause target organ
damage. Ingestion may cause gastrointestinal
irritation and diarrhea.
Skin: Irritating to skin. May cause sensitization by skin
contact. Skin inflammation is characterized by
itching, scaling, reddening or, occasionally,
blistering. Prolonged or repeated contact may cause
dermatitis. Once sensitized a severe allergic
reaction may occur when subsequently exposed to very
low levels. In the event of any complaints or
symptoms, avoid further exposure. Persons with a
history of skin sensitization problems should not be
employed in any process in which this product is
used.
Eyes: Irritating to eyes. Adverse symptoms may include
the following: redness, itching, swelling, pain
Potential chronic health effects
Chronic effects: Adverse symptoms may include the following:
Tin: Prolonged or repeated exposure may cause benign
pneumoconiosis (Stannosis).
Rosin: May cause allergic skin reactions with
repeated exposure. Prolonged inhalation of fumes
may cause respiratory sensitization.
Copper: Other adverse effects: metal fume fever,
coughing, headache shortness of breath/breathing
difficulty, anemia. Chronic effects: jaundice,
ulcerations.
Target organs: Contains material which causes damage to the
following organs: upper respiratory tract, skin,
eye, lens or cornea.
Contains material which may cause damage to the
following organs: kidneys, liver.
Carcinogenicity: Not classified or listed by IARC, NTP, OSHA, EU and
ACGIH
Mutagenicity: No conclusive data is available to indicate product
or any component present at greater than 0.1% may
cause heritable genetic effects.
Developmental effects: No conclusive data is available to indicate product
or any component present at greater than 0.1% may
cause developmental abnormalities.
Fertility effects: No conclusive data is available to indicate product
or any component present at greater than 0.1% may
impair fertility.
Medical conditions Pre-existing skin and digestive disorders and
aggravated by disorders involving any other target organs
over-exposure: mentioned in this MSDS as being at risk may be
aggravated by overexposure to this product. Persons
with a history of skin sensitization problems should
not be employed in any process in which this product
is used.
3. Composition/information on ingredients
Name CAS number % by weight
Tin 7440-31-5 80-100
Copper 7440-50-8 1-5
Rosin 8050-09-7 1-5
Any ingredient not listed in Section 3 is non-regulated or present in the
product in concentrations below legal disclosure limits.
4. First aid measures
Eye contact: Check for and remove any contact lenses. Get medical
attention if irritation occurs. Immediately flush eyes
with running water for at least 30 minutes, keeping
eyelids open.
Skin contact: Flush contaminated skin with plenty of water. Remove
contaminated clothing and shoes. Continue to rinse for
at least 15 minutes. Get medical attention. May cause
sensitization by skin contact. Once sensitized, a
severe allergic reaction may occur when subsequently
exposed to very low levels. Wash contaminated clothing
before reuse. Clean shoes thoroughly before reuse. In
case of contact, immediately flush skin with plenty of
water for at least 15 minutes while removing
contaminated clothing and shoes.
Inhalation: Get medical attention immediately. Move exposed person
to fresh air. If it is suspected that fumes are still
present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. Keep person warm
and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide
artificial respiration or oxygen by trained personnel.
It may be dangerous to the person providing aid to give
mouth to mouth resuscitation. If unconscious, place in
recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight
clothing such as a collar, tie, belt or waistband.
Ingestion: Get medical attention immediately. Wash out mouth with
water. Remove dentures if any. Move exposed person to
fresh air. Keep person warm and at rest. Do not
induce vomiting unless directed to do so by medical
personnel. If vomiting occurs, the head should be kept
low so that vomit does not enter the lungs. Never give
anything by mouth to an unconscious person. If
unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie belt or
waistband. If not breathing, if breathing is irregular
or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel.
Protection of No action shall be taken involving any personal risk or
first-aiders: without suitable training. It may be dangerous to the
person providing aid to give mouth to mouth
resuscitation. Wear suitable protective clothing,
gloves and eye/face protection. If it is suspected
that fumes are still present, the rescuer should wear
an appropriate mask or self-contained breathing
apparatus. Wash contaminated clothing thoroughly with
water before removing it, or wear gloves.
5. Fire-fighting measures
Flammability of the No specific fire or explosion hazard.
product:
Extinguishing media
Suitable: Use an extinguishing agent suitable for the surrounding
fire.
Not Suitable: None known.
Special exposure Promptly isolate the scene by removing all persons from
hazards: the vicinity of the incident if there is a fire. No
action shall be taken involving any personal risk or
without suitable training. Fire water contaminated with
this material must be contained and prevented from
being discharged to any waterway, sewer or drain.
Hazardous combustion Metal oxide/oxides
products:
Special remarks on Flammable in the presence of the following materials or
fire hazards: conditions: open flames, sparks and static discharge
and heat.
Special remarks on Explosive in the presence of the following materials or
explosion hazards: conditions: open flames, sparks and static discharge
and heat.
Special protective Fire-fighters should wear appropriate protective
equipment for equipment and self-contained breathing apparatus (SCBA)
fire-fighters with a full face-piece operated in positive pressure
mode.
6. Accidental release measures
Personal precautions: No action shall be taken involving any personal risk or
without suitable training. Evacuate surrounding areas.
Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled
material. Provide adequate ventilation. Wear
appropriate respirator when ventilation is inadequate.
Put on appropriate personal protective equipment (see
section 8).
Environmental Avoid dispersal of spilled material and runoff and
precautions: contact with soil, waterways, drains and sewers.
Inform the relevant authorities if the product has
caused environmental pollution (sewers, waterways, soil
or air). Water polluting material. May be harmful to
the environment if released in large quantities.
Large spill: Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses,
basements or confined areas. Vacuum or sweep up
material and place in a designated, labeled waste
container. Dispose of via a licensed waste disposal
contractor. Note: see section 1 for emergency contact
information and section 13 for waste disposal.
Small spill: Move containers from spill area. Vacuum or sweep up
material and place in a designated, labeled waste
container. Dispose of via a licensed waste disposal
contractor.
7. Handling and storage
Handling: Put on appropriate personal protective equipment (see section 8).
Eating, drinking and smoking should be prohibited in areas where
this material is handled, stored and processed. Workers should
wash hands and face before eating, drinking and smoking. Persons
with a history of skin sensitization problems should not be
employed in any process in which this product is used. Do not get
in eyes or on skin or clothing. Do not ingest. Avoid release to
the environment. Use only with adequate ventilation. Wear
appropriate respirator when ventilation is inadequate. Keep in the
original container or approved alternative container. Containers
should be kept closed when not in use. Empty containers retain
product residue and can be hazardous. Do not reuse container.
Storage: Store in accordance with local regulations. Store in original
container protected from direct sunlight in a dry, cool and
well-ventilated area away from incompatible materials (see section
10) and food and drink. Keep container tightly closed and sealed
until ready for use. Containers that have been opened must be
carefully resealed and kept upright to prevent leakage. Do not
store in unlabeled containers. Use appropriate containment to
avoid environmental contamination.
Keep container in a cool, well-ventilated area. Keep container
tightly closed and sealed until ready for use. Avoid all possible
sources of ignition (spark or flame).
8. Exposure controls/personal protection
Product name CAS number Exposure limits
Tin 7440-31-5 OSHA PEL (United States, 9/2005).
TWA: 2 mg/m3 8 hour(s).
ACGIH TLV (United States, 1/2008).
TWA: 2 mg/m3 8 hour(s).
NIOSH REL (United States, 6/2008). Notes: Note: The
REL and PEL also apply also apply to other inorganic
tin compounds (as Sn) except tin oxides.
TWA: 2 mg/m3 10 hour(s).
Copper 7440-50-8 OSHA Final Rule (United States, 1989). Notes: As
copper
TWA: 1 mg/m3 8 hour(s). Form:
TWA: 0.1 mg/m3 8 hour(s). Form:
NIOSH REL (United States, 6/2008). Notes: Note: The
REL and PEL also apply also apply to other copper
compounds (as Cu) except copper fumes.
TWA: 1 mg/m3 10 hour(s). Form: Dusts and Mists.
OSHA PEL (United States, 11/2006).
TWA: 1 mg/m3 8 hour(s). form: Dusts and Mists
TWA: 0.1 mg/m3 8 hour(s). Form: Fume
OSHA PEL 1989 (United States, 3/1989). Notes: as Cu
TWA: 1 mg/m3 (as Cu) 8 hour(s). Form: Dusts and
Mists
TWA: 0.1 mg/m3 (as Cu) 8 hour(s). Form: Fume
ACGIH TLV (United States, 1/2008). Notes: As Cu
TWA: 1 mg/m3 (as Cu) 8 hour(s).
ACGIH TLV (United States, 1/2008). Notes: Substances
for which the TLV is higher than the OSHA
Permissible Exposure Limit (PEL) and/or the NIOSH
Recommended Exposure Limit (REL). See CFR 58 (124)
:36338-33351, June 30, 1993, for revised OSHA PEL.
Adopted Values enclosed are those for which changes
are proposed. Consul the Notice of Intended Changes
for current proposal. See Notice of Intended
changes.
TWA: 0.2 mg/m3 8 hour(s). Form: Fume
Rosin 8050-09-7 NIOSH REL (United States, 6/2008). Notes: As
formaldehyde
TWA: 0.1 mg/m3 (as formaldehyde) 10 hour(s).
OSHA PEL 1989 (United States, 3/1989). Notes:
measured as formaldehyde
TWA: 0.1 mg/m3 (measured as formaldehyde) 8 hour(s).
Consult local authorities for acceptable exposure limits.
Recommended monitoring If this product contains ingredients with exposure
procedures: limits, personal, workplace atmosphere or biological
monitoring may be required to determine the
effectiveness of the ventilation or other control
measures and/or the necessity to use respiratory
protective equipment.
Engineering measures: Use only with adequate ventilation. If user operations
generate dust, fumes, gas, vapor or mist, use process
enclosures, local exhaust ventilation or other
engineering controls to keep worker exposure to
airborne contaminants below any recommended or
statutory limits. Processes should be designed to
minimize airborne and skin exposure to hazardous
substances.
Hygiene measures: Wash hands, forearms and face thoroughly after handling
chemical products, before eating, smoking and using the
lavatory and at the end of the working period.
Appropriate techniques should be used to remove
potentially contaminated clothing. Wash contaminated
clothing before reusing. Ensure that eyewash stations
and safety showers are close to the workstation
location. Eating, drinking and smoking should be
prohibited in areas where this material is handled,
stored and processed. Remove/Take off immediately all
contaminated clothing. Contaminated work clothing
should not be allowed out of the workplace.
Personal protection
Respiratory: Use properly fitted, air-purifying or air-fed
respirator complying with an approved standard if a
risk assessment indicates this is necessary.
Respirator selection must be based on known or
anticipated exposure levels, the hazards of the product
and the safe working limits of the selected respirator.
Hands: Chemical-resistant, impervious gloves complying with an
approved standard should be worn at all times when
handling chemical products if a risk assessment
indicates this is necessary. The user must check that
the final choice of type of glove selected for handling
this product is the most appropriate and takes into
account the particular conditions of use, as included
in the user's risk assessment.
Eyes: Avoid contact with eyes. Safety eyewear should be used
when there is a likelihood of exposure.
Skin: Avoid contact with skin and clothing. Wear protective
clothing. Body garments used should be based upon the
task being performed (e.g., lab coat, chemical
resistant protective suit, slevelets, synthetic apron,
gauntlets) to avoid exposed skin surfaces. Wash
contaminated clothing thoroughly with water before
removing it, or wear gloves.
Environmental exposure Emissions from ventilation or work process equipment
controls: should be checked to ensure they comply with the
requirements of environmental protection legislation.
In some cases, fume scrubbers, filters or engineering
modifications to the process equipment will be
necessary to reduce emissions to acceptable levels.
9. Physical and chemical properties
Physical state: Solid
Flash point: Not available.
Auto-ignition Not available.
temperature:
Flammable limits: Not available.
Color: Gray.
Odor: None.
pH: Not available.
Boiling/condensation Not available.
point:
Melting/freezing Not available.
point:
Vapor pressure: Not available.
Vapor density: Not available.
Odor threshold: Not available.
Evaporation rate: Not available.
VOC: 1.5 g/l
Solubility: Insoluble in the following materials: cold water and
hot water.
10. Stability and reactivity
Stability: The product is stable
Conditions to avoid: No specific data.
Incompatibility with Reactive with oxidizing agents, reducing agents, acids,
various substances: alkalis.
Chlorine, peroxides.
Hazardous Under normal conditions of storage and use, hazardous
decomposition decomposition products should not be produced
products:
Other Hazardous Metal oxides, toxic. Fumes
decomposition
products:
Hazardous Under normal conditions of storage and use, hazardous
polymerization: polymerization will not occur.
11. Toxicological information
Acute toxicity
Product/ingredient Result Species Dose Exposure
name
Rosin LD50 Oral Rat 3 g/kg -
LD50 Oral Mouse 2.2 g/kg -
LD50 Oral Rat 3 mg/kg -
Carcinogenicity
Classification
Product ACGIH IARC EPA NIOSH NTP OSHA
ingredient name
Rosin - - - + - -
Alpha has not conducted specific studies on the toxicity of this product.
12. Ecological information
Aquatic exotoxicity
Product/ Test Result Species Exposure
ingredient name
copper - Acute EC50 Daphnia - Water 48 hours
0.017 to0.026 flea - Daphnia
mg/L Fresh obtuse - Neonate
water - <24 hours
- Acute EC50 12 Daphnia - Water 48 hours
ug/L Fresh flea -
water Ceriodaphnia
dubia - Neonate
- <24 hours
- Acute EC50 11 Daphnia - Water 48 hours
ug/L Fresh flea -
water Ceriodaphnia
dubia - Neonate
- <24 hours
- Acute EC50 9 Daphnia - Water 48 hours
ug/L Fresh flea -
water Ceriodaphnia
dubia - Neonate
- <24 hours
- Acute EC50 1.6 Daphnia - Water 48 hours
ug/L Fresh flea -
water Ceriodaphnia
dubia - Neonate
- <24 hours -
0.25 mm
- Acute EC50 161 Crustaceans - 48 hours
to 566 ug/L Shrimp - Paratya
Fresh water australiensis
- Acute EC50 120 Crustaceans - 48 hours
ug/L Marine Giant river
water prawn -
Macrobrachium
rosenbergii -
LARVAE
- Acute lC50 105 Crustaceans - 48 hours
ug/L Marine Calanoida
water
- Acute LC50 85 Crustaceans - 48 hours
to 138 ug/L Fleshy prawn -
Marine water Penaeus
chinensis
- Acute LC50 57 Crustaceans - 48 hours
to 64 ug/L Water flea -
Fresh water Simocephalus
vetulus - <24
hours
- Acute LC50 30 Fish - chonook 96 hours
ug/L Fresh salmon -
water Oncorhynchus
tshawytscha - 3
months - 1.35 g
- Acute LC50 Fish - Fathead 96 hours
27.8 to 42 minnow -
ug/L Fresh Pimephales
water promelas -
Juvenile
(Fledgling,
Hatchling,
Weanling) - <1
months
- Acute LC50 24 Fish - Striped 96 hours
ug/L Fresh bass - Morone
water saxatilis -
LARVAE - 16 days
- Acute LC50 >20 Fish - Chinook 96 hours
ug/L salmon -
Oncorhynchus
tshawytscha -
1.35 g
- Acute LC50 20 Fish-chinook 96 hours
ug/L Fresh salmon -
water Oncorhynchus
tshawytscha - 3
months 1.35
- Acute LC50 17 Daphnia - Water 48 hours
to 21 ug/L flea -
Fresh water Ceriodaphnia
reticulate - <4
hours
Acute LC50 17 Daphnia - Water 48 hours
to 23 ug/L flea -
Fresh water Ceriodaphnia
dubia - Neonate
- <12 hours
Acute LC50 14 Daphnia - Water 48 hours
to 17 ug/L flea -
Fresh water Ceriodaphnia
dubia - Neonate
Acute LC50 12 Daphnia - Water 48 hours
ug/L Fresh flea -
water Ceriodaphnia
dubia - Neonate
- < 24 hours
Acute LC50 Crustaceans - 48 hours
10.3 to 15.6 Giant river
ug/L Fresh prawn -
water Macrobrachium
rosenbergii -
LARVAE
Acute LC50 Fish - Fathead 96 hours
10.3 to 15.6 minnow -
ug/L Fresh Pimephales
water promelas -
Juvenile
(Fledgling,
Hatchling,
Weanling) - <1
months
Acute LC50 >10 Fish - Chinook 96 hours
ug/L salmon -
Oncorhynchus
tshawytscha -
1.35 g
Acute LC50 9.4 Fish - Fathead 96 hours
to 11.5 ug/L minnow -
Fresh water Pimephales
promelas -
Juvenile
(Fledling,
Hatchling,
Weanling) - <1
months
Acute LC50 195 Crustaceans - 48 hours
ug/L Marine Giant river
water prawn -
Macrobrachium
rosenbergii -
LARVAE
Acute LC50 183 Crustaceans - 48 hours
to 477 ug/L Shrimp - paratya
Fresh water australiensis
Acute LC50 255 Crustaceans - 48 hours
ug/L Marine Giant river
water prawn -
Macrobrachium
rosenbergii -
LARVAE
Acute LC50 Crustaceans - 48 hours
248 to 2340 Shrimp - Paratya
ug/L Fresh australiensis
water Daphnia - Water 48 hours
Chronic NEL flea - Daphnia
0.01 mg/L magna - 24 hours
Fresh water
Chronic NOEC Fish - Chinook 96 hours
11.7 ug/L salmon -
Fresh water Oncorhynchus
tshawytscha
13. Disposal considerations
Waste The generation of waste should be avoided or minimized whenever
Disposal: possible. Empty containers or liners may retain some product
residues. This material and its container must be disposed of
in a safe way. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Disposal of this
product, solutions and any by-products should at all times
comply with the requirements of environmental protection and
waste disposal legislation and any regional local authority
requirements. Avoid dispersal of spilled material and runoff
and contact with soil, waterways, drains and sewers.
Disposal should be in accordance with applicable regional, national and local
laws and regulations.
Refer to Section 7: HANDLING AND STORE and Section 8: EXPOSURE
CONTROLS/PERSONAL PROTECTION for additional handling information and protection
of employees.
14. Transport information
Regulatory UN number Proper Classes PG* Label Additional
information shipping Information
name
DOT Not - - -
Classification regulated.
PG*: Packing group
15. Regulatory information
United States
HCS Classification: Highly toxic material
Irritating material
Sensitizing material
Target organ effects
U.S. Federal All ingredients comply with applicable rules or orders
regulations: under United States TSCA.
All components are listed or exempted.
TSCA 5(a)2 proposed significant rules: No products were
found.
TSCA 5(a)2 final significant rules: No products were
found.
TSCA 12(b) one-time export: No products were found.
SARA 313
Product name
Form R - Reporting requirements Copper
Supplier notification Copper
Canada
WHMIS (Canada): Class D-2B: Material causing other toxic effects (toxic).
Canada Inventory: All components are listed or exempted.
International lists
China inventory All components are listed or exempted.
(IECSC):
Europe inventory: All components are listed or exempted.
Australia inventory All components are listed or exempted.
(AICS):
Japan inventory Not determined.
(ENCS) Not determined.
Korea inventory All components are listed or exempted.
(KECI)
Philippines All components are listed or exempted.
inventory (PICCS)
16. Other information
Definition of Terms
ACGIH American Conference of Governmental Industrial Hygienists
Ceiling Maximum exposure limit defined by OSHA
CAS Chemical Abstract Service
IARC International Agency for Research on Cancer
NIOSH National Institute for Occupational Safety and Health
NTP National Toxicology Program
OSHA Occupational Safety and Health Administration
PEL Permissible Exposure Limit
REL Recommended Exposure Limit
RTK Right to Know
SARA Superfund Amendments and Reauthorization Act
STEL Short Term Exposure Limit
TLV ACGIH Threshold Limit Value
TLV-C ACGIH Threshold Limit Value, Ceiling
TRADE SECRET Claimed as allowed under 29CFRS1910.1200
TSCA Toxic Substances Control Act
PPE Personal Protection Equipment
CEPA Canadian Environmental Protection Act
DSL Domestic Substance List
NDSL Non-Domestic Substance List
NSN New Substance Notification Rules
Disclaimer
The information contained herein is based on data considered accurate.
However, no warranty is expressed of implied regarding the accuracy of these
data or the results to be obtained from the use thereof. Additionally, Cookson
Electronics assumes no responsibility for injury to the vendee or third persons
proximately caused by the material even if reasonable safety procedures are
followed. Furthermore, vendee assumes the risk in his use of the material.
The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance. For more product information by email, click here Imperial Supplies LLC does not provide services and products outside the United States |
