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MSDS 82115 82115: Electronic Solder .032 [1]MSDS Last updated: 02/01/2010
Material Safety Data Sheet
Emergency phone: US & Canada:800-424-9300
Mexico:01 800 022 1400, (55) 5559
1588
Health 2
Flammability 1
Instability 0
Special
Health 2
Flammability 1
Physical hazards 0
Personal protection
1. Product and company
identification
Product name: Solder Wire cored 60Sn/40Pb Alloy,
RA-32 Flux
Product Code: M060RA32
Manufacturer:
Cookson Electronics Cookson Electronics Mexico, S.A. de
C.V.
109 Corporate Blvd. Avenida Nafta No.800,
South Plainfield, NJ 07080 Parque Industrial Stiva Aeropuerto
Toll Free: (800) 367-5460 Apodaca, Neuvo Leon, C.P. 66600
Main Phone: (908) 791-3000 Mexico
Fax: (908) 791-3090 www.cooksonelectronics.com
www.alphametals.com Customer service: (814) 946-1611
Validation date: 2/3/2009
Supersedes Date: 6/6/2008
Prepared by T Valverde
(203)-799-4917
2. Hazards identification
Physical State: Solid
Odor: None.
OSHA/HCS status: This material is considered
hazardous by the OSHA Hazard
Communication Standard (29 CFR
1910.1200).
Emergency Overview: DANGER!
Very toxic if swallowed. Toxic by
inhalation. Irritating to eyes,
respiratory system and skin. May
cause sensitization by skin
contact. Do not ingest. Do not get
on skin or clothing. Avoid contact
with eyes. Contains material that
can cause target organ damage.
Contains material which may cause
cancer. Risk of cancer depends on
duration and level of exposure.
Contains material which may cause
heritable genetic effects, based on
animal data. Contains material
which may cause birth defects,
based on animal data. Contains
materials which can cause
developmental abnormalities. Avoid
exposure during pregnancy. Contains
material which can impair male
fertility. Contains material which
can impair female fertility. Use
only with adequate ventilation.
Keep container tightly closed and
sealed until ready for use. Wash
thoroughly after handling.
Routes of entry: Dermal contact. Eye contact.
Inhalation. Ingestion.
Potential acute health effects
Inhalation: Toxic by inhalation. Can cause
target organ damage. Irritating to
respiratory system.
Ingestion: Very toxic if swallowed. Can cause
target organ damage. Ingestion may
cause gastrointestinal irritation
and diarrhea.
Skin: Irritating to skin. May cause
sensitization by skin contact. Skin
inflammation is characterized by
itching, scaling, reddening or,
occasionally, blistering. Prolonged
or repeated contact may cause
dermatitis. Once sensitized, a
severe allergic reaction may occur
when subsequently exposed to very
low levels. In the event of any
complaints or symptoms, avoid
further exposure. Persons with a
history of skin sensitization
problems should not be employed in
any process in which this product
is used.
Eyes: Irritating to eyes. Adverse
symptoms may include the following:
redness, itching, swelling, pain.
Potential chronic health effects
Chronic effects: Adverse symptoms may include the
following:
tin: Prolonged or repeated exposure
may cause benign pneumoconiosis
(Stannosis).
lead: Poison! Other adverse
effects: abdominal cramps and pain,
nausea or vomiting, headache,
muscle weakness, metallic taste,
loss of appetite, insomnia,
dizziness/vertigo, "lead line" on
gums, high lead levels in blood and
urine, loss of consciousness or
coma and death. Chronic effects:
irritability, visual disturbances,
blood pressure elevation and
discoloration of: skin.
rosin: May cause allergic skin
reactions with repeated exposure.
Prolonged inhalation of fumes may
cause respiratory sensitization.
Target organs: Contains material which causes
damage to the following organs:
upper respiratory tract, skin, eye,
lens or cornea.
Contains material which may cause
damage to the following organs:
blood, kidneys, the reproductive
system, mucous membranes,
gastrointestinal tract, central
nervous system (CNS).
Carcinogenicity: Contains material which may cause
cancer. Risk of cancer depends on
duration and level of exposure.
Mutagenicity: Contains materiel which may cause
heritable genetic effects, based on
animal data.
Teratogenicity: Contains material which may cause
birth defects, based on animal
data.
Developmental effects: Contains material which can cause
developmental abnormalities.
Fertility effects: Contains material which can impair
male fertility. Contains material
which can impair female fertility.
California Prop. 65: WARNING: This product contains a
chemical known to the state of
California to cause cancer and
birth defects or other reproductive
harm.
Medical conditions aggravated by Pre-existing respiratory, skin and
overexposure: digestive disorders and disorders
involving any other target organs
mentioned in this MSDS as being at
risk may be aggravated by over
exposure to this product. Persons
with a history of skin
sensitization problems should not
be employed in any process in which
this product is used.
3. Composition/information on
ingredients
Name CAS number % by weight
tin 7440-31-5 50-60
lead 7439-92-1 30-40
rosin 8050-09-7 1-5
Any ingredient not listed in Section 3 is non-regulated or present in
the product in concentrations below legal disclosure limits.
4. First aid measures
Eye contact: Check for and remove any contact
lenses. Get medical attention if
irritation occurs. Immediately
flush eyes with running water for
at least 30 minutes, keeping
eyelids open .
Skin contact: Flush contaminated skin with plenty
of water. Remove contaminated
clothing and shoes. Continue to
rinse for at least 15 minutes. Get
medical attention. May cause
sensitization by skin contact. Once
sensitized, a severe allergic
reaction may occur when
subsequently exposed to very low
levels. Wash contaminated clothing
before reuse. Clean shoes
thoroughly before reuse. In case of
contact, immediately flush skin
with plenty of water for at least
15 minutes while removing
contaminated clothing and shoes.
Inhalation: Get medical attention immediately.
Move exposed person to fresh air.
If it is suspected that fumes are
still present, the rescuer should
wear an appropriate mask or
self-contained breathing apparatus.
Keep person warm and at rest. If
not breathing,if breathing is
irregular or if respiratory arrest
occurs, provide artificial
respiration or oxygen by trained
personnel. It may be dangerous to
the person providing aid to give
mouth-to-mouth resuscitation. If
unconscious, place in recovery
position and get medical attention
immediately. Maintain an open
airway. Loosen tight clothing such
as a collar, tie, belt or
waistband.
Ingestion: Get medical attention immediately.
Wash out mouth with water. Remove
dentures if any. Move exposed
person to fresh air. Keep person
warm and at rest. Do not induce
vomiting unless directed to do so
by medical personnel. If vomiting
occurs, the head should be kept low
so that vomit does not enter the
lungs. Never give anything by mouth
to an unconscious person. If
unconscious, place in recovery
position and get medical attention
immediately. Maintain an open
airway. Loosen tight clothing such
as a collar, tie, belt or
waistband. If not breathing, if
breathing is irregular or if
respiratory arrest occurs, provide
artificial respiration or oxygen by
trained personnel.
Protection of first-aiders: No action shall be taken involving
any personal risk or without
suitable training. It may be
dangerous to the person providing
aid to give mouth-to-mouth
resuscitation. Wear suitable
protective clothing, gloves and
eye/face protection. If it is
suspected that fumes are still
present, the rescuer should wear an
appropriate mask or self-contained
breathing apparatus. Wash
contaminated clothing thoroughly
with water before removing it, or
wear gloves.
5. Fire-fighting measures
flammability of the product: No specific fire or explosion
hazard.
Extinguishing media
Suitable: Use an extinguishing agent suitable
for the surrounding fire.
Not suitable: None known.
Special exposure hazards: Promptly isolate the scene by
removing all persons from the
vicinity of the incident if there
is a fire. No action shall be taken
involving any personal risk or
without suitable training.
Hazardous combustion products: metal oxide/oxides
Special protective equipment for Fire-fighters should wear
fire-fighters: appropriate protective equipment
and self-contained breathing
apparatus (SCBA) with a full
face-piece operated in positive
pressure mode.
6. Accidental release measures
Personal precautions: No action shall be taken involving
any personal risk or without
suitable training. Evacuate
surrounding areas. Keep unnecessary
and unprotected personnel from
entering. Do not touch or walk
through spilled material. Provide
adequate ventilation. Wear
appropriate respirator when
ventilation is inadequate. Put on
appropriate personal protective
equipment (see section 8).
Environmental precautions: Avoid dispersal of spilled material
and runoff and contact with soil,
waterways, drains and sewers.
Inform the relevant authorities if
the product has caused
environmental pollution (sewers,
waterways, soil or air).
Large spill: Move containers from spill area.
Approach release to upwind. Prevent
entry into sewers, water, courses,
basements or confined areas. Vacuum
or sweep up material and place in a
designated, labeled waste
container. Dispose of via a
licensed waste disposal contractor.
Note: see section 1 for emergency
contact information and section 13
for waste disposal.
Small spill: Move containers from spill area.
Vacuum or sweep up material and
place in a designated, labeled
waste container. Dispose of via a
licensed waste disposal contractor.
7. Handling and storage
Handling: Put on appropriate personal
protective equipment (see section
8). Eating, drinking and smoking
should be prohibited in areas where
this material is handled, stored
and processed. Workers should was
hands and face before eating,
drinking and smoking. Persons with
a history of skin sensitization
problems should not be employed in
any process in which this product
is used. Avoid exposure during
pregnancy. Do not get in eyes or on
skin or clothing. Do not ingest.
Use only with adequate ventilation.
Wear appropriate respirator when
ventilation is inadequate. Keep in
the original container or approved
alternative container. Containers
should be kept closed when not in
use. Empty containers retain
product residue and can be
hazardous. Do not reuse container.
Storage: Store in accordance with local
regulations. Store in original
container protected from direct
sunlight in a dry, cool and
well-ventilated area, away from
incompatible materials (see section
10) and food and drink. Keep
container tightly closed and sealed
until ready for use. Containers
that have been opened must be
carefully resealed and kept upright
to prevent leakage. Do not store in
unlabeled containers. Use
appropriate containment to avoid
environmental contamination.
Keep container in a cool,
well-ventilated area. Keep
container tightly closed and sealed
until ready for use. Avoid all
possible sources of ignition
(sparks or flame).
8. Exposure controls/personal
protection
Product name CAS number Exposure limits
Tin 7440-31-5 OSHA PEL (united
States, 9/2005).
TWA: 2 mg/m3 8 hour(s).
ACGIH TLV (United
States, 1/2008).
TWA: 2 mg/m3 8 hour(s).
NIOSH REL (United
States, 6/2008). Notes:
Note: The REL and PEL
also apply to other
inorganic tin compounds
(as (Sn) except tin
oxides.
TWA: 2 mg/m3 10
hour(s).
Lead 7439-92-1 OSHA PEL (United
States, 5/2005).
TWA: 0.05 mg/m3 8
hour(s).
ACGIH TLV (United States, 1/2008).
Notes: as Pb
TWA: 0.05 mg/m3, (as PB) 8 hour(s).
OSHA PEL (United States, 11/2006).
Notes: as Pb
TWA: 50 ug/m3, (as Pb) 8 hour(s).
NIOSH REL (United States, 6/2008).
Notes: See Appendix C-Supplemental
Exposure Limits Note: The REL and
PEL also apply to other lead
compounds (as Pb).
TWA: 0.05 mg/m3 10 hour(s).
Rosin 8050 - 09- 7 NIOSH REL (United
States, 6/2008). Notes:
as formaldehyde
TWA: 0.1 mg/m3, (as
formaldehyde) 10
hour(s).
OSHA PEL 1989 (United
States, 3/1989). Notes:
measures as
formaldehyde
TWA: 0.1 mg/m3,
(measured as
formaldehyde) 8
hour(s).
TWA: 0.1 mg/m3,
(measured as
formaldehyde) 8
hour(s).
Consult local authorities for acceptable exposure limits.
Recommended monitoring procedures: If this product contains
ingredients with exposure limits,
personal, workplace atmosphere or
biological monitoring may be
required to determine the
effectiveness of the ventilation or
other control measures and/or the
necessity to use respiratory
protective equipment.
Engineering measures: Use only with adequate ventilation.
Use process enclosures, local
exhaust ventilation or other
engineering controls to keep worker
exposure to airborne contaminants
below any recommended or statutory
limits. Processes should be
designed to minimize airborne and
skin exposure to hazardous
substances.
Hygiene measures: Wash hands, forearms and face
thoroughly after handling chemical
products, before eating, smoking
and using the lavatory and at the
end of the working period.
Appropriate techniques should be
used to remove potentially
contaminated clothing. Wash
contaminated clothing before
reusing. Ensure that eyewash
stations and safety showers are
close to the workstation location.
Eating, drinking and smoking should
be prohibited in areas this
material is handled, stored and
processed. Remove/Take off
immediately all contaminated
clothing. Contaminated work
clothing should not be allowed out
of the workplace.
Personal protection
Respiratory: Use a properly fitted,
air-purifying or air-fed respirator
complying with an approved standard
if a risk assessment indicated this
is necessary. Respiratory selection
must be based on known or
anticipated exposure levels, the
hazards of the product and the safe
working limits of the selected
respirator.
Hands: Chemical-resistant, impervious
gloves complying with an approved
standard should be worn at all
times when handling chemical
products if a risk assessment
indicates this is necessary. The
user must check that the final
choice of type of glove selected
for handling this product is the
most appropriate and takes into
account the particular conditions
of use, as included in the user's
risk assessment.
Eyes: Avoid contact with eyes. Safety eye
wear should be used when there is a
likelihood of exposure.
Skin: Avoid contact with skin and
clothing. Wear protective clothing.
Body garments used should be based
upon the task being performed
(e.g., lab coat, chemical resistant
protective suit, sleeveless,
synthetic apron, gauntlets) to
avoid exposed skin surfaces. Wash
contaminated clothing thoroughly
with water before removing it, or
wear gloves.
Environmental exposure controls: Emissions from ventilation or work
process equipment should be checked
to ensure they comply with the
requirements of environmental
protection legislation. IN some
cases, fume scrubbers, filters or
engineering modifications to the
process equipment will be necessary
to reduce emissions to acceptable
levels.
9. Physical and chemical properties
Physical state: Solid.
Flash point: Not available.
Auto-ignition temperature: Not available.
Flammable limits: Not available.
Color: Gray.
Odor: None.
PH: Not available.
Boiling/condensation point: Not available.
Melting freezing point: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Odor threshold: Not available.
Evaporation rate: Not available.
VOC: 1.8 g/l
Solubility: Insoluble in the following
materials: cold water and hot
water.
10. Stability and reactivity
Stability: The product is stable.
Conditions to avoid: No specific data.
Incompatibility with various Reactive with oxidizing agents,
substances: reducing agents, acids, alkalies.
Chlorine, peroxides
Hazardous decomposition products: Under normal conditions of storage
and use, hazardous decomposition
products should not be produced.
Other Hazardous decomposition Metal oxides, toxic, fumes
products:
Hazardous polymerization: Under normal conditions of storage
and use, hazardous polymerization
will not occur.
11. Toxicological information
Acute toxicity
Product/ Result Species Dose Exposure
ingredient
name
Lead LDLo Rat 1 g/kg -
intraperitonea
l Rat 0.2mg/kg -
TD Lo Oral Rat 3 g/kg -
Ld50 Oral
Rosin LD50 Oral Mouse 2.2 g/kg -
LD50 Oral Rat 3 mg/kg -
Carcinogenicit
y
Classification
Product/ ACGIH IARC EPA NIOSH NTP OSHA
ingredien
t name
Lead A3 2B - - Possible -
Rosin - - - + - -
Mutagenicity
Product/ Test Experiment Result
ingredient name
Lead - Mammalian-Animal Equivocal
Teratogenicity
Product/ Result Species Dose Exposure
ingredient
name
Lead Equivocal-inha 10 mg/m3 10 mg/m3 24 hours per
lation day
Equivocal-Oral 2118 mg/kg 2118 mg/kg -
Reproductive
toxicity
Product/ Maternal Fertility Developme Species Dose Exposure
ingredien toxicity nt toxin
t name
Lead - Equivocal - Mouse Oral: -
4099.2
mg/kg
Equivocal - - Mouse-Fem Oral: 300 -
ale mg/kg
- - Equivocal Rat-Femal Inhalatio 24 hours
e n: 3 per day
- - Equivocal Rat- Oral: 520 -
Female mg/kg
Alpha has not conducted specific studies on the toxicity of this
product.
12. Ecological information
Aquatic ecotoxicity
Lead Test Result Species Exposure
- Acute LC50 Fish-Rainbow 96 hours
1.17 mg/L trout,
Fresh water donaldson
trout-
Oncorhynchus
mykiss-145 mm
- Acute LC50 Fish-Inland 96 hours
38829 to 71806 silverside-Men
ppb Marine idia berylina
water
- Acute LC50 Fish-Inland 96 hours
26150 to 44761 silverside-Men
ppb Marine idia berylina
water
- Acute LC50 Fish-Cyprinus 96 hours
1.33 ppm Fresh carpio-Juvenil
water e (Fledgling,
Hatchling,
Weanling)-6.5
cm
- Acute LC50 0.8 Fish-Cyprinus 96 hours
ppm Fresh carpio-Juvenil
water e (Fledgling,
Hatchling,
Weanling)-6.5
cm
- Acute LC50 Fish-Cyprinus 96 hours
0.44 ppm Fresh carpio-Juvenil
water e (Fledgling,
Hatchling,
Weanling)- 3.5
cm
- Acute LC50 Crustaceans-Wa 48 hours
4500 to 5500 ter flea-
ug/L Fresh Simocephalus
water vetulus-<24
hours
- Acute LC50 Crustaceans-In 48 hours
4460 ug/L dian
Marine water prawn-Penaeus
indicus- 6 to
9 cm
- Acute LC50 Daphnia-Water 48 hours
4400 to 5300 flea-Daphnia
ug/L Fresh magna-<24
water hours
- Acute LC50 Fish- 96 hours
2800 ug/L Smallmouth
Fresh water bass-Micropter
us
dolomieui-Swim
-up
- Acute LC50 Fish- 96 hours
2200 ug/L Smallmouth
Fresh water bass-Micropter
us
dolomieui-Swim
-up
- Acute LC50 933 Crustaceans-Fl 48 hours
to 1200 ug/L eshy
Marine water prawn-Penaeus
chinensis
- Acute LC50 530 Daphnia-Water 48 hours
ug/L Fresh flea-Ceriodaph
water nia
reticulata-<4h
ours
- Acute LC50 Fish-Smallmout 96 hours
29000 ug/L h
Fresh water bass-Micropter
us
dolomieui-Fing
erling
- Acute LC50 Fish-Goldfish 96 hours
40000 ug/L Carassius
Fresh water auratus
- Acute LC50 Daphnia-Water 48 hours
5100 ug/L flea-Daphnia
Fresh water pulex-<24
hours
- Acute LC50 Crustaceans-Br 48 hours
5010 ug/L ine
Marine water shrimp-Artemia
salina
13. Disposal considerations
Waste disposal: The generation of waste should be
avoided or minimized wherever
possible. Empty containers or
liners may retain some product
residues. This material and its
container must be disposed of in a
safe way. Dispose of surplus and
non-recyclable products via a
licensed waste disposal contractor.
Disposal of this product, solutions
and any by-products should at all
times comply with the requirements
of environmental protection and
waste disposal legislation and any
regional local authority
requirements. Avoid dispersal of
spilled material and runoff and
contact with soil, waterways,
drains and sewers.
Disposal should be in accordance with applicable regional, national and
local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOUSRE
CONTROLS/PERSONAL PROTECTION for additional handling information and
protection of employees.
14. Transport information
Regulatory UN number Proper Classes PG* Label Additional
information shipping information
name
DOT Not - - -
Classificat regulated.
ion
PG*: Packing group
15. Regulatory information
United States
HCS Classification: Highly toxic material
Irritating material
Sensitizing material
Carcinogen
Target organ effects
U.S. Federal regulations: All ingredients comply with
applicable rules or orders under
United States TSCA.
All components are listed or
exempted.
TSCA 5(a)2 proposed significant
rules: NO products were found.
TSCA 5(a)2 final significant rules:
No products were found.
TSCA 12(b) one-time export: No
products were found.
SARA 313
Product name
Form R-Reporting requirements: Lead
Supplier notification: Lead
California Prop. 65
WARNING: This product contains a chemical known to the State of
California to cause cancer and birth defects or other reproductive harm.
Canada
WHMIS (Canada) Class D-2A: Material causing other
toxic effects (Very toxic).
Class D-2B: Material causing other
toxic effects (Toxic).
Canada inventory: All components are listed or
exempted.
International lists
China inventory (IECSC): All components are listed or
exempted.
Europe inventory: All components are listed or
exempted.
Australia inventory (AICS) All components are listed or
exempted.
Japan inventory (ENCS): Not determined.
Not determined.
Korea inventory (KECI): All components are listed or
exempted.
Philippines inventory (PICCS): All components are listed or
exempted.
16. Other information
Definition of Terms
ACGIH American Conference of Governmental
Industrial Hygienists
Ceiling Maximum exposure limit defined by
OSHA
CAS Chemical Abstract Service
IARC International Agency for Research
on Cancer
NIOSH National Institute for Occupational
Safety and Health
NTP National Toxicology Program
OSHA Occupational Safety and Health
Administration
PEL Permissible Exposure Limit
REL Recommended Exposure Limit
RTK Right to Know
SARA Superfund Amendments and
Re-authorization Act
STEL Short Term Exposure Limit
TLV ACGIH Threshold Limit Value
TLV-C ACGIH Threshold Limit Value,
Ceiling
TRADE SECRET Claimed as allowed under 29CFRS
1910.1200
TSCA Toxic Substances Control Act
PPE Personal Protection Equipment
CEPA Canadian Environmental Protection
Act
DSL Domestic Substance List
NSN New Substance Notification Rules
Disclaimer
The information contained herein is based on data considered accurate.
However, no warranty is expressed or implied regarding the accuracy of
these data or the results to be obtained from the use thereof.
Additionally, Cookson Electronics assumes no responsibility for injury
to the vendee or third persons proximately caused by the material even
if reasonable safety procedures are followed. Furthermore, vendee
assumes the risk in his use of the material.
The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance. For more product information by email, click here Imperial Supplies LLC does not provide services and products outside the United States |
