MSDS 82114

MATERIAL SAFETY DATAT SHEET 3M Weld-Thru II Coating, PN 05917 05/09/2007 | |

3M                                                                      
Material Safety Data Sheet                                              
Copyright, 2007, 3M Company. All rights reserved. Copying and/or        
downloading of this information for the purpose of properly utilizing 3M
products is allowed provided that: (1) the information is copied in full
with no changes unless prior written agreement is obtained from 3M, and 
(2) neither the copy nor the original is resold or otherwise distributed
with the intention of earning a profit thereon.                         

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION                           

PRODUCT NAME:                       3M Weld-Thru II Coating, PN 05917  
MANUFACTURER:                       3M                                 
DIVISION:                           Automotive Aftermarket             
ADDRESS:                            3M CENTER                          
                                    St. Paul, MN 55144-1000            
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)            

Issue Date:                         05/09/2007                         
Supercedes Date:                    11/22/2005                         
Document Group:                     18-7877-6                          
Product Use:                                                           
Intended Use:                       Automotive                         
Specific Use:                       Weldable Corrosion Resistant       
                                    Coating                            

SECTION 2: INGREDIENTS                                                  

Ingredient                  C.A.S. No.            % by Wt              
ACETONE                     67-64-1               30-60                
LIQUEFIED PETROLEUM GASES   68476-86-8            10-30                
ZINC                        7440-66-6             7-13                 
XYLENE                      1330-20-7             3-7                  
ZINC RICH PRIMER            Mixture               1-5                  
ETHYL BENZENE               100-41-4              1-5                  
ALUMINUM                    7429-90-5             1-5                  
STODDARD SOLVENT            8052-41-3             <2                   
TOLUENE                     108-88-3              <0.1                 

SECTION 3: HAZARDS IDENTIFICATION                                       

3.1 EMERGENCY OVERVIEW                                                  
Specific Physical Form:             Aerosol                            
Odor, Color, Grade:                 Gray/Metallic appearance with      
                                    solvent odor.                      
General Physical Form:              Liquid                             
 Aerosol container contains flammable material under pressure. Closed   
containers exposed to heat from fire may build pressure and explode.    
Extremely flammable liquid and vapor. Vapors may travel long distances  
along the ground or floor to an ignition source and flash back.  Aerosol
container contains a flammable material under pressure. May cause target
organ effects.                                                          
3.2 POTENTIAL HEALTH EFFECTS                                            
Eye Contact:                                                            
Moderate Eye Irritation: Signs/symptoms may include redness,swelling,pain,
tearing,and blurred or hazy vision.                                             
Skin Contact:                                                           
Delayed Dermal Irritation: Signs/symptoms may include localized redness,
swelling, itching and pain. These effects may not appear immediately    
following exposure.                                                     
Inhalation:                                                             
Upper Respiratory Tract Irritation: Signs/symptoms may include cough,   
sneezing, nasal discharge, headache, hoarseness, and nose and throat    
pain.                                                                   
Intentional concentration and inhalation may be harmful or fatal.       
May be absorbed following inhalation and cause target organ effects.    
Ingestion:                                                              
May be harmful if swallowed.                                            
Ingestion may cause:                                                    
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, 
nausea, vomiting and diarrhea.                                          
Target Organ Effects:                                                   
Central Nervous System (CNS) Depression: Signs/symptoms may include     
headache, dizziness, drowsiness, incorrdination, nausea, slowed reaction
time, slurred speech, giddiness, and unconsciousness.                   
Prolonged or repeated exposure, above recommended guidelines, may cause:       
Liver Effects: Signs/symptoms may include loss of appetite, weight loss,
fatigue, weakness, abdominal tenderness and jaundice.                   
Kidney Effects: Signs/symptoms may include reduced or absent urine      
production, increase serum creatinine, lower back pain, increased       
protein in urine, and increased blood urea nitrogen (BUN).              
Carcinogenicity:                                                        
Contains a chemical or chemicals which can cause cancer.                
Ingredient        C.A.S. No.        Class Description Regulation       
ETHYLBENZENE      100-41-4          Group 2B          International    
                                                      Agency for       
                                                      Research on      
                                                      Cancer           

SECTION 4: FIRST AID MEASURES                                           

4.1 FIRST AID PROCEDURES                                                
The following first aid recommendations are based on an assumption that 
appropriate personal and industrial hygiene practices are followed.     
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms  
persist get medical attention.                                          
Skin Contact: Wash affected area with soap and water. If signs/symptoms 
develop get medical attention.                                          
Inhalation: Remove person to fresh air. If signs/symptoms develop, get  
medical attention.                                                      
If Swallowed: Do not induce vomiting. Give victim two glasses of water. 
Never give anything by mouth to an unconscious person.  Get immediate   
medical attention.                                                      

SECTION 5: FIRE FIGHTING MEASRES                                        

5.1 FLAMMABLE PROPERTIES                                                
Auto ignition temperature           No Data Available                  
Flash Point                         -156 F [Test Method: Pensky-Martens
                                    Closed Cup]                        
Flammable Limits-LEL                0.7%                               
Flammable Limits-UEL                12.8%                              
         
5.2 EXTINGUISHING MEDIA                                                 
Use fire extinguishers with class B extinguishing agents (e.g., dry     
chemical, carbon dioxide).                                              
5.3 PROTECTION OF FIRE FIGHTERS                                         
Special Fire Fighting Procedures: Water may not effectively extinguish  
fire; however, it should be used to keep fire exposed containers and    
surfaces cool and prevent explosive rupture.  Wear full protective      
equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA).
Unusual Fire and Explosion Hazards: flammable liquefied gas.  Closed    
containers exposed to heat from fire may build pressure and explode.    
Extremely flammable liquid and vapor. Vapors may travel long distances  
along the ground or floor to an ignition source and flash back. Aerosol 
container contains flammable material under pressure.                   
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion
and thermal decomposition information.                                  

SECTION 6: ACCIDENTAL RELEASE MEASURES                                  

Accidental Release Measures: Not applicable.                            
Refer to other sections of this MSDS for information regarding physical 
and health hazards, respiratory protection, ventilation, and personal   
protective equipment. Call 3M-HELPS line (1-800-364-3577) for more      
information on handling and managing the spill. Evacuate unprotected and
untrained personnel from hazard area. The spill should be cleaned up by 
qualified personnel. Remove all ignition sources such as flames, smoking
materials, and electrical spark sources. Use only non sparking tools.   
Ventilate the area with fresh air. For large spill, or spills in        
confined spaces, provide mechanical ventilation to disperse or exhaust  
vapors, in accordance with good industrial hygiene practice. Warning! A 
motor could be an ignition source and could cause flammable gases or    
vapors in the spill area to burn or explode. Contain spill. If possible,
seal leaking container. Place leaking containers in a well ventilated   
area, preferably an operating exhaust hood, or if necessary outdoors on 
an impermeable surface until appropriate packaging for the leaking      
container or its contents is available. Working from around the edges of
the spill inward, cover with bentonite, vermiculite, or commercially    
available inorganic absorbent material. Mix in sufficient absorbent     
until it appears dry. Collect as much of the spilled material as        
possible using non-sparking tools. Clean up residue with an appropriate 
solvent selected by a qualified and authorized person. Ventilate the    
area with fresh air. Read and follow safety precautions on the solvent  
label and MSDS. Collect the resulting residue container solution. Place 
in a metal container approved for transportation by appropriate         
authorities. Seal the container. Dispose of collected material as soon  
as possible.                                                            
In the event of a release of this material, the user should determine if
the release qualifies as reportable according to local, state, and      
federal regulations.                                                    

SECTION 7: HANDLING AND STORAGE                                         

7.1 HANDLING                                                            
Vapors may ignite explosively. May cause flash fire. Prevent build-up of
vapors - open all windows and doors. Maintain vapor concentrations below
recommended exposure limits. Use only cross ventilation. Without        
adequate ventilation, vapors may settle in low-lying areas. Keep away   
from heat, sparks, and open flame. Do not smoke or ignite matches,      
lighters, etc. For industrial or professional use only. Extinguish pilot
lights and turn off stoves, ovens and other gas and electric appliances 
(space and water heaters, furnaces, etc), electric motors, and other    
sources of ignition during adhesive use and until all vapors are gone;  
i.e., until the odor of vapors at the floor level has disappeared. Do   
not use electric light switches. Do not generate static sparks (such as 
by walking on carpet, etc). Use the same precaution in the work area   
and all connected areas. Aerosol container contains flammable gas under 
pressure. Do not pierce or burn container, even after use. Keep out of  
the reach of children. Avoid eye contact with vapors, mists, or spray.  
Avoid breathing of vapors, mists, or spray. Avoid breathing of dust     
created by cutting, sanding, grinding, or machining. Do not eat, drink  
or smoke when using this product. Wash exposed areas thoroughly with    
soap and water. Avoid contact with oxidizing agents. Keep away from     
strong bases and amines. (When welding on3M Weldable Primer, adhere to  
the standard precautions normally taken for welding. Avoid breathing    
fumes during welding operations. The use of local exhaust ventilation is
recommended to control welding fumes. When local exhaust ventilation is 
not used, a NIOSH/MSHA-approved respirator is recommended.)             
7.2 STORAGE                                                             
Store away from areas where product may come into contact with food or  
pharmaceuticals. Do not store containers on their sides. Keep containers
tightly closed. Keep container in well-ventilated area. Store away from 
heat. Store out of direct sunlight. Store away from acids. Store away   
from oxidizing agents. Store at temperatures below 120 degrees          
Fahrenheit (49 degrees C).                                              

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                        

8.1 ENGINEERING CONTROLS                                                
Do not use in a confined area or areas with little or no air movement.  
Use with functioning spray booth or local exhaust. Use with appropriate 
local exhaust ventilation. Provide appropriate local exhaust for        
cutting, grinding, sanding or machining.                                
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)                                 
8.2.1 Eye/Face Protection                                               
Avoid eye contact with vapors, mists, or spray.                         
The following eye protection(s) are recommended: Safety Glasses with    
side shields, Indirect Vented Goggles                                   
8.2.2 Skin Protection                                                   
Avoid skin contact.                                                     
Select and use gloves and/or protective clothing to prevent skin contact
based on the results of an exposure assessment. Consult with your glove 
and/or protective clothing manufacturer for selection of appropriate    
compatible materials. Gloves made from the following material(s) are    
recommended: Polyethylene/Ethylene Vinyl Alcohol.                       
8.2.3 Respiratory Protection                                            
Avoid breathing of vapors, mists or spray. Avoid breathing of dust      
created by cutting, sanding, grinding or machining.  Select one of the  
following NIOSH approved respirators based on airborne concentration of 
contaminants and in accordance with OSHA regulations: Half face piece or
full-face air-purifying respirator with N95 particulate filters. Consult
the current 3M Respiratory Selection Guide for additional information or
call 1-800-243-4630 for 3M technical assistance. When welding through   
this coating, use appropriate respiratory protection against hazardous  
decomposition products.                                                 
8.2.4 Prevention of Swallowing                                          
Do not eat, drink or smoke when using this product. Wash exposed areas  
thoroughly with soap and water.                                         
8.3 EXPOSURE GUIDELINES                                                 
Ingredient            Authority    Type         Limit       Additional  
                                                            Information 
ACETONE               AIHA         TWA          500 ppm     Table A4    
ACETONE               ACGIH        STEL         750 ppm     Table A4    
ACETONE               OSHA         TWA, Vacated 750 ppm                 
ACETONE               OSHA         TWA          1000 ppm    Table Z-1   
ACETONE               OSHA         STEL,        1000 ppm                
                                   Vacated                              
ALUMINUM              ACGIH        TWA          10 mg/m3                
ALUMINUM              OSHA         TWA,         5mg/m3      Table Z-1   
                                   respirable                           
ALUMINUM              OSHA         TWA, as      15 mg/m3    Table Z-1   
                                   total dust                           
ALUMINUM PYRO POWDERS ACGIH        TWA, as A1   5 mg/m3                 
ALUMINUM PYRO POWDERS OSHA         TWA, as A1   5 mg/m3     Table Z-1A  
ETHYLBENZENE          ACGIH        TWA          100 ppm     Table A3    
ETHYLBENZENE          ACGIH        STEL         125 ppm     Table A3    
ETYLBENZENE           OSHA         TWA          100 ppm     Table Z-1A  
ETHYLBENZENE          OSHA         STEL         125 ppm     Table Z-1A  
STODDARD SOLVENT      ACGIH        TWA          100 ppm                 
STODDARD SOLVENT      OSHA         TWA, Vacated 100 ppm     Table Z-1A  
STODDARD SOLVENT      OSHA         TWA          500 ppm     Table Z-1   
TOLUENE               ACGIH        TWA          50 ppm      Skin        
                                                            Notation*,  
                                                            Table A4    
TOLUENE               CMRG         STEL         75 ppm      Skin        
                                                            Notation*   
TOLUENE               OSHA         TWA, Vacated 100 ppm                 
TOLUENE               OSHA         STEL,        150 ppm                 
                                   Vacated                              
TOLUENE               OSHA         TWA          200 ppm     Table Z-2   
TOLUENE               OSHA         CEIL         300 ppm     Table Z-2   
XYLENE                ACGIH        TWA          100 ppm     Table A4    
XYLENE                ACGIH        STEL         150 ppm     Table A4    
XYLENE                OSHA         TWA          100 ppm     Table Z-1A  
XYLENE                OSHA         STEL         150 ppm     Table Z-1A  
                                                                        
*Substance(s) refer to the potential contribution to the overall        
exposure by the cutaneious route including mucous membrane and eye,     
either by airborne, or more particularly, by direct contact with the    
substance. Vehicles can alter skin absorption.                          
VAC Vacated PEL: Vacated Permissible Exposure Limits [PEL] are enforced 
as the OSHA PEL in some states. Check with your local regulatory agency.

SOURCE OF EXPOSURE LIMIT DATA                                           
ACGIH:                              American Conference of Governmental
                                    Industrial Hygienists              
CMRG:                               chemical Manufacturer Recommended  
                                    Guideline                          
OSHA:                               Occupational Safety and Health     
                                    Administration                     
AIHA:                               American Industrial Hygiene        
                                    Association Workplace Environmental
                                    Exposure Level (WEEL)              

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                             

Specific Physical Form:             Aerosol                            
Odor, Color, Grade:                 Gray/Metallic appearance with       
                                    solvent odor.                       
General Physical Form:              Liquid                              
auto ignition temperature:          No Data Available                   
Flash Point:                        - 156 F [Test method: Pensky-Martens
                                    Closed Cup]                         
Flammable Limits-LEL                0.7%                                
Flammable Limits-UEL                12.8%                               
Boiling point                       [Details: Aerosol]                  
Vapor Density                       [Details: Heavier than air]         
Vapor Pressure                      80-90 mmHg                          
Specific Gravity                    0.796                               
pH                                  Not Applicable                      
Melting point                       Not Applicable                      
Hazardous Air Pollutants            0.53 lb HAPS/gal
Solubility in Water                 Appreciable                         
Volatile Organic Compounds          2.37 lb/gal [Test Method: calculated
                                    SCAQMD rule 443.1][Details:         
                                    excluding exempt compounds]         
Percent volatile                    35.64%                              
VOC Less H2O & Exempt Solvents      557.58 g/l [Test Method: calculated 
                                    SCAQMD rule 443.1]                  
Viscosity                           4.4 lb/gl                           
                                                                        
SECTION 10: STABILITY AND REACTIVITY                                    
Stability: Stable                              
Materials and Conditions to Avoid: Strong acids; Strong bases; Strong   
oxidizing agents; Amines; Heat Additional Information: All sources of   
ignition, welding arcs, and open flame:                                 
Hazardous Polymerization: Hazardous Polymerization will not occur.      
Hazardous Decomposition or by-Products                                  
Substance                           Condition                           
Hydrocarbons                        Not Specified                       
Chlorine                            Not Specified                       
Carbon Monoxide                     Not Specified                       
Carbon Dioxide                      Not Specified                       
Hydrogen Chloride                   Not Specified                       
Oxides of Nitrogen                  Not Specified                       
Phosgene                            Not Specified                       
Toxic Vapor, Gas, Particulate       Not Specified                       
Oxides of Zinc                      Not Specified                       

SECTION 11: TOXICOLOGICAL INFORMATION                                   

Please contact the address listed on the first page of the MSDS for     
Toxicological information on this material and/or its components.       

SECTION 12: ECOLOGICAL INFORMATION                                      

ECOTOXICOLOGICAL INFORMATION                                            
Not determined.                                                         
CHEMCAL FATE INFORMATION                                                
Not determined.                                                         

SECTION 13: DISPOSAL CONSIDERATIONS                                     

Waste Disposal Method: Do not puncture or burn cans in a household      
incinerator.  Incinerate in a permitted hazardous waste incinerator. As 
a disposal alternative, dispose of waste product in a permitted         
hazardous waste facility. Facility must be capable of handling aerosol  
cans. Combustion products will include HCI. Facility must be capable of 
handling halogenated materials. Dispose of empty product container in a 
sanitary landfill.                                                      
EPA Hazardous Waste Number (RCRA): D001 (Ignitable)                     
Since regulations vary, consult applicable regulations or authorities   
before disposal.                                                        

SECTION 14: TRANSPORT INFORMATION                                       
ID Number(s):                                                           
LB-K100-0341-3, 60-9801-0777-9                                          
Please contact the emergency numbers listed on the first page of the    
MSDS for Transportation Information for this material.                  

SECTION 15: REGULATORY INFORMATION                                      

US FEDERAL REGULATIONS                                                  
Contact 3M for more information.                                        
311/312 Hazard Categories:                                              
Fire Hazard-Yes  Pressure Hazard-Yes Reactivity Hazard-No  Immediate    
Hazard-Yes  Delayed Hazard-Yes                                          
Section 313 Toxic Chemical subject to the reporting requirements of that
section and 40 CFR part372 (EPCRA):                                     
Ingredient              C.A.S. No.              % by Wt                
XYLENE                  1330-20-7               3-7                    
ETHYLBENZENE            100-41-4                1-5                    
ALUMINUM                7429-90-5               1-5                    
ZINC                    7440-66-6               7-13                   
ZINC (ZINC COMPOUNDS)   7440-66-6               7-13                   
This material contains a chemical which requires export notification    
under TSCA Section 12[b]:                                               
Ingredient        C.A.S. No         Regulation        Status           
(Category if                                                           
applicable)                                                            
ACETONE           67-64-1           Toxic Substances  Applicable       
                                    Control Act                        
                                    (TSCA) 4 Test                      
                                    Rule Chemicals                     
STATE REGULATIONS                                                       
Contact 3M for more information.                                        
CALIFORNIA PROPOSITION 65                                               
Ingredient              C.A.S. No.              Classification         
TOLUENE                 108-88-3                *Developmental Toxin   
*WARNING: contains a chemical or chemicals which can cause birth defects or
other reproductive harm.
CHEMICAL INVENTORIES                                                    
The components of this product are in compliance with the chemical      
notification requirements of TSCA.                                      
Contact 3M for more information.                                        
INTERNATIONAL REGULATIONS                                               
Contact 3M for more information.                                        
WHMIS: Hazardous                                                        

This MSDS has been prepared to meet the U.S. OSHA Hazard Communication  
Standard, 29 CFR 1910.1200.                                             

SECTION 16: OTHER INFORMATION                                           

NFPA Hazard Classification                                              
Health:2Flammability: 4Reactivity: 0 Special Hazards: None              
National Fire Protection Association (NFPA) hazard ratings are designed 
for use by emergency response personnel to address the hazards that are 
presented by short-term, acute exposure to a material under conditions  
of fire, spill or similar emergencies. Hazard ratings are primarily     
based on the inherent physical and toxic properties of the material but 
also include the toxic properties of combustion or decomposition        
products that are know to be generated in significant quantities.       
Revision Changes:                                                       
Section 1: Product use information was modified.                        
Copyright was modified.                                                 
Section 14: ID Number(s) was modified.                                  
Section 9: Property description for optional properties was modified.   

DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is
believed to be correct as of the date issued. 3M MAKES NO WARRANTIES,   
EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED        
WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR      
COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for        
determining whether the 3M product is fit for a particular purpose and  
suitable for user's method of use or application. Given the variety of  
factors that can affect the use and application of a 3M product, some of
which are uniquely within the user's knowledge and control, it is       
essential that the user evaluate the 3M product to determine whether it 
is fit for a particular purpose and suitable for user's method of use or
application.                                                            
3M provides information in electronic form as a service to its          
customers. Due to the remote possibility that electronic transfer may   
have resulted in errors, omissions or alterations in this information,  
3M makes no representations as to its completeness or accuracy. In      
addition, information obtained from a database may not be as current as 
the information in the MSDS available directly from 3M.                 
3M MSDS are available at www.3M.com                                     

The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance.

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