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MSDS 82107 82107: Flux Paste 2 Oz [4]MSDS Last updated: 01/12/2010
IMPERIAL SUPPLIES LLC MSDS SHEET FOR 82107
Emergency phone: US & Canada: 800-424-9300
Mexico: 01 800 022 1400, (55) 5559 1588
Health 3 Health 3
Flammability 0 Flammability 0
Instability 0 Physical 0
hazards
Special Personal
protection
1. PRODUCT AND COMPANY IDENTIFICATION
Product name: ZN Chloride
Product code: 119653
Manufacturer: Cookson Electronics Cookson Electronics Mexico, S.A. de C.
109 Corporate Blvd. V.
South Plainfield, NJ Avenida Nafta No. 800,
07080 Parque Industrial Stiva Aeropuerto
Toll Free: (800) Apodaca, Nuevo Leon, C.P. 66600
367-5460 Mexico
Main Phone: (908) www.cooksonelectronics.com
791-3000 Customer Service: (814) 946-1611
Fax: (908) 791-3090
www.alphametals.com
Validation 2/2/2009 Supersedes Date: 9/30/2008
date:
Prepared by: T. Valverde
(203)-799-4917
2. HAZARDS IDENTIFICATION
Physical state: Solid.
Odor: None.
OSHA/HCS status: This material is considered hazardous by the OSHA Hazard
Communication Standard (29 CFR 1910.1200).
Emergency overview: DANGER!
Toxic if swallowed. Corrosive to the eyes and digestive
tract. Cause burns. Severely irritating to the skin and
respiratory system. Do not ingest. Do not get in eyes or
on skin or clothing. Contains material that can cause
target organ damage. Contains material which may cause
heritable genetic effects, based on vitro data. Use only
with adequate ventilation. Keep container tightly closed
and sealed until ready for use. Wash thoroughly after
handling.
Routes of entry: Dermal contact. Inhalation. Ingestion.
Potential acute health effects
Inhalation Severely irritating to the respiratory system. May cause severe
: irritation or burns.
Ingestion: Toxic if swallowed. Corrosive to the digestive tract. May cause
burns to mouth, throat and stomach. Can cause target organ damage.
Adverse symptoms may include the following: nausea or vomiting
stomach pains. Ingestion may cause gastrointestinal irritation and
diarrhea.
Skin: Severely irritating to the skin. Adverse symptoms may include the
following: pain or irritation redness blistering.
Eyes: Corrosive to eyes. Causes burns. Direct contact with the eyes can
cause irreversible damage, including blindness.
Potential chronic health effects
Chronic effects: Adverse symptoms may include the following:
Zinc chloride: dermatitis, ulcerations, metal fume fever,
pulmonary edema, chemical pneumonitis, mental confusion or
disorientation, drowsiness/fatigue, difficulty swallowing,
blood pressure elevation, convulsions, circulatory
collapse.
Target organs: Contains material which causes damage to the following
organs: lungs, cardiovascular system, upper respiratory
tract, skin, eye, lens or cornea. Contains material which
may cause damage to the following organs: kidneys, liver,
pancreas.
Carcinogenicity: Not classified or listed by IARC, NTP, OSHA, EU and ACGIH.
Mutagenicity: Contains material which may cause heritable genetic
effects, based on vitro data.
Developmental No conclusive data is available to indicate product or any
effects: component present at greater than 0.1% may cause
developmental abnormalities.
Fertility effects: No conclusive data is available to indicate product or any
component present at greater than 0.1% may impair
fertility.
California Prop. WARNING: This product contains less than 0.1% of a chemical
65 known to the State of California to cause cancer.
WARNING: This product contains less than 1% of a chemical
known to the State of California to cause birth defects or
other reproductive harm.
Medical conditions Pre-existing digestive disorders and disorders involving
aggravated by any other target organs mentioned in this MSDS as being at
over-exposure: risk may be aggravated by over-exposure to this product.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Name CAS number % by weight
Zinc chloride 7646-85-7 20-30
Any ingredient not listed in Section 3 is non-regulated or present in the
product in concentrations below legal disclosure limits.
4. FIRST AID MEASURES
Eye contact: Get medical attention immediately. Chemical burns must be treated
promprtly by a physician. Check for and remove any contact
lenses. Immediately flush eyes with running water for at least 30
minutes, keeping eyelids open. Provide a readily-accessible
eyewash facility and quick-drench safety shower.
Skin In case of contact, immediately flush skin with plenty of water
contact: for at least 30 minutes while removing contaminated clothing and
shoes. Provide a readily-accessible eyewash facility and
quick-drench safety shower. Get medical attention. Wash
contaminated clothing before reuse. Clean shoes thoroughly before
reuse.
Inhalation: Get medical attention immediately. Chemical burns must be treated
promptly by a physician. Move exposed person to fresh air. If it
is suspected that fumes are still present, the rescuer should
wear an appropriate mask or self-contained breathing apparatus.
Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide the artificial
respiration or oxygen by trained personnel. It may be dangerous
to the person providing aid to give mouth-to-mouth resuscitation.
If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight
clothing such as a collar, tie, belt or waistband.
Ingestion: Get medical attention immediately. Chemical burns must be treated
promptly by a physician. Wash out mouth with water. Remove
dentures if any. Move exposed person to fresh air. Keep person
warm and at rest. Do not induce vomiting unless directed to do so
by medical personnel. If vomiting occurs, the head should be kept
low so that vomit does not enter the lungs. Never give anything
by mouth to an unconscious person. If unconscious, place in
recovery position and get medical attention immediately. Maintain
an open airway. Loosen tight clothing such as collar, tie, belt
or waistband. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or
oxygen by trained personnel.
Protection No action shall be taken involving any personal risk or without
of first- suitable training. It may be dangerous to the person providing
aiders: aid to give mouth-to-mouth resuscitation. Wear suitable
protective clothing, gloves and eye/face protection. If it is
suspected that fumes are still present, the rescuer should wear
an appropriate mask or self-contained breathing apparatus. Wash
contaminated clothing thoroughly with water before removing it,
or wear gloves.
5. FIRE-FIGHTING MEASURES
Flammability of the No specific fire or explosion hazard.
product:
Extinguishing media
Suitable: Use an extinguishing agent suitable for the surrounding fire.
Not suitable: None known.
Special exposure Promptly isolate the scene by removing all persons from
hazards: the vicinity of the incident if there is a fire. No
action shall be taken involving any personal risk or
without suitable training.
Hazardous combustion Halogenated compounds
products: Metal oxide/oxides
Special remarks on Slightly flammable in the presence of the following
fire hazards: materials or conditions: open flames, sparks and static
discharge and heat.
Special protective Fire-fighters should wear appropriate protective
equipment for equipment and self-contained breathing apparatus (SCBA)
fire-fighters: with a full face-piece operated in positive pressure
mode.
6. ACCIDENTAL RELEASE MEASURES
Personal No action shall be taken involving any personal risk or
precautions: without suitable training. Evacuate surrounding areas. Keep
unnecessary and unprotected personnel from entering. Do not
touch or walk through spilled material. Provide adequate
ventilation. Wear appropriate respirator when ventilation
is inadequate. Put on appropriate personal protective
equipment (see section 8).
Environmental Avoid dispersal of spilled material and runoff and contact
precautions: with soil, waterways, drains and sewers. Inform the
relevant authorities if the product has caused
environmental pollution (sewers, waterways, soil or air).
Large spill: Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements
or confined areas. Vacuum or sweep up material and place in
a designated, labeled waste container. Dispose of via a
licensed waste disposal contractor. Note: see section 1 for
emergency contact information and section 13 for waste
disposal.
Small spill: Move containers from spill area. Vacuum or sweep up
material and place in a designated, labeled waste
container. Dispose of via a licensed waste disposal
contractor.
7. HANDLING AND STORAGE
Handling: Put on appropriate personal protective equipment (see section 8).
Eating, drinking and smoking should be prohibited in areas where
this material is handled, stored and processed. Workers should wash
hands and face before eating, drinking and smoking. Do not get in
eyes or on skin or clothing. Provide a readily-accessible eyewash
facility and quick-drench safety shower. Do not ingest. Use only
with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Keep in the original container or
approved alternative container. Containers should be kept closed
when not in use. Empty containers retain product residue and can be
hazardous. Do not reuse container.
Storage: Store in accordance with local regulations. Store in original
container protected from direct sunlight in a dry, cool and
well-ventilated area, away from incompatible materials (see section
10) and food and drink. Keep container tightly closed and sealed
until ready for use. Containers that have been opened must be
carefully resealed and kept upright to prevent leakage. Do not store
in unlabeled containers. Use appropriate containment to avoid
environmental contamination. Provide a readily-accessible eyewash
facility and quick-drench safety shower.
Keep container tightly closed. Keep container in a cool,
well-ventilated area.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Product name CAS number Exposure limits
Zinc 7646-85-7 ACGIH TLV(United States, 1/2008),
chloride STEL: 2 mg/m3 15 minute(s). Form: Fume
TWA: 1 mg/m3 8 hour(s). Form: Fume
NIOSH REL (United States, 6/2008),
STEL: 2 mg/m3 15 minute(s). Form: Fume
TWA: 1 mg/m3 10 hour(s). Form: Fume
OSHA PEL (United States, 11/2006),
TWA: 1 mg/m3 8 hour(s). Form: Fume
OSHA PEL 1989 (United States, 3/1989),
STEL: 2 mg/m3 15 minute(s). Form: Fume
TWA: 1 mg/m3 8 hour(s). Form: Fume
Consult local authorities for acceptable exposure limits
Recommended If this product contains ingredients with exposure limits,
monitoring personal, workplace atmosphere or biological monitoring may
procedures: be required to determine the effectiveness of the
ventilation or other control measures and/or the necessity
to use respiratory protective equipment.
Engineering Use only with adequate ventilation. If user operations
measures: generate dust, fumes, gas, vapor or mist, use process
enclosures, local exhaust ventilation or other engineering
controls to keep worker exposure to airborne contaminants
below any recommended or statutory limits. Provide a
readily-accessible eyewash facility and quick-drench safety
shower. Processes should be designed to minimize airborne
and skin exposure to hazardous substances.
Hygiene measures: Wash hands, forearms and face thoroughly after handling
chemical products, before eating, smoking and using the
lavatory and at the end of the working period. Appropriate
techniques should be used to remove potentially
contaminated clothing. Wash contaminated clothing before
reusing. Ensure that eyewash stations and safety showers
are close to the workstation location. Eating, drinking and
smoking should be prohibited in areas where this material
is handled, stored and processed. Remove/Take off
immediately all contaminated clothing. Contaminated work
clothing should not be allowed out of the workplace.
Personal protection
Respiratory: Use a properly fitted, air-purifying or air-fed respirator
complying with an approved standard if a risk assessment
indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of
the product and the safe working limits of the selected
respirator.
Hands: Chemical-resistant, impervious gloves complying with an
approved standard should be worn at all times when handling
chemical products if a risk assessment indicates this is
necessary. The user must check that the final choice of type
of glove selected for handling this product is the most
appropriate and takes into account the particular conditions
of use, as included in the user's risk assessment.
Eyes: Avoid contact with eyes. Safety eyewear should be used when
there is a likelihood of exposure. Direct contact with the
eyes can cause irreversible damage, including blindness.
Skin: Avoid contact with skin and clothing. Wear protective
clothing. Body garments used should be based upon the task
being performed (e.g., lab coat, chemical resistant protective
suit, sleevelets, synthetic apron, gauntlets) to avoid exposed
skin surfaces. Wash contaminated clothing thoroughly with
water before removing it, or wear gloves.
Environmental Emissions from ventilation or work process equipment should be
exposure checked to ensure they comply with the requirements of an
controls: environmental protection legislation. In some cases, fume
scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable
levels.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Solid
Flash point: Not available
Auto Ignition Not available
temperature:
Flammable limits: Not available
Color: Gray
Odor: None
pH: Not available
Boiling/condensation Not available
point:
Melting/freezing Not available
point:
Vapor pressure: Not available
Vapor density: Not available
Odor threshold: Not available
Evaporation rate: Not available
VOC: 0.02 g/l
Solubility: Easily soluble in the following materials: cold water
and hot water
10. STABILITY AND REACTIVITY
Stability: The product is stable
Conditions to avoid: No specific data
Incompatibility with Reactive with oxidizing agents, reducing agents, metals,
various substances: acids, alkalis.
Chlorine, peroxides.
Hazardous Under normal conditions of storage and use, hazardous
decomposition decomposition products should not be produced.
products:
Other Hazardous Toxic fumes
decomposition
products:
Hazardous Under normal conditions of storage and use, hazardous
polymerization: polymerization will not occur.
11. TOXICOLOGICAL INFORMATION
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Zinc chloride LD50 Rat 3690 ug/kg -
Intravenous
LD50 Mouse 9090 ug/kg -
Intravenous
TDLo Rat 9.3 mg/kg -
Intraperitoneal
Mutagenicity
Product/ingredient name Test Experiment Result
Zinc chloride - Mammalian-Animal Positive
- Bacteria Positive
Alpha has not conducted specific studies on the toxicity of this product
12. ECOLOGICAL INFORMATION
Aquatic ecotoxicity
Product/ingredient Test Result Species Exposure
name
Zinc chloride - Acute EC50 280 Daphnia-Water 48 hours
ug/L Fresh water flea-Daphnia magna-12
hours
- Acute EC50 164 to Crustacenas-Calanoid 48 hours
170 ug/L Fresh copepod-Skistodiaptomus
water oregonesis-Juvenile
(Fledgling, hatchling,
Weanling)
- Acute EC50 100 Daphnia-Water 48 hours
ug/L Fresh water flea-Daphnia magna-12
hours
- Acute EC50 81 to Crustaceans-Calanoid 48 hours
94 ug/L Fresh copepod-Diaptomus
water leptopus
- Acute EC50 73 to Crustacenas-Calanoid 48 hours
82 ug/L Fresh copepod-Diaptomus
water leptopus
- Acute EC50 52 to Crustaceans-Cyclopoid 48 hours
949 ug/L Fresh copepod-Tropocyclops
water prasinus mexicanus-0.54
mm
- Acute LC50 210 Daphnia-Water 48 hours
ug/L Fresh water flea-Daphnia
magna-Neonate-<24 hours
- Acute LC50 205.31 Crustaceans-Water 48 hours
ug/L Fresh water flea-Moina
irrasa-Neonate-< 24
hours
- Acute LC50 525 to Daphnia-Water 48 hours
620 ug/L Fresh flea-Daphnia magna-<1
water days
- Acute LC50 163 Daphnia-Water 48 hours
ug/L Fresh water flea-Ceriodaphnia
dubia-<4 hours
- Acute LC50 152.51 Crustaceans-Water 48 hours
ug/L Fresh water flea-Moina
irrasa-Neonate-<24
hours
- Acute LC50 127.7 Daphnia-Water 48 hours
to 151.9 ug/L flea-Ceriodaphnia dubia
Fresh water - <24 hours
- Acute LC50 107 to Fish-Rainbow trout, 96 hours
139 ug/L Fresh Donaldson
water trout-Oncorhynchus
mykiss-Juvenile
(Fledgling, Hatchling,
Weanling)-7 months-8.6
cm - 4.95 g
- Acute LC50 380 to Daphnia-Water 48 hours
430 ug/L Fresh flea-Daphnia pulex -
water >=6 days
- Acute LC50 100 Fish-Striped 96 hours
ug/L Fresh water bass-Morone
saxatilis-LARVAE
- Acute LC50 97 to Fish-Rainbow trout, 96 hours
112 ug/L Fresh Donaldson
water trout-Oncorhynchus
mykiss-FRY 2.36 to 3.01
g
- Acute LC50 97 to Fish-Chinook 96 hours
108 ug/L Fresh salmon-Oncorhynchus
water tshawytscha-Swim-up-0.2
3 g
- Acute LC50 95 to Fish-Rainbow trout, 96 hours
159 ug/L Fresh Donaldson
water trout-Oncorhynchus
mykiss-Juvenile
(Fledgling, Hatchling,
Weanling)-7 months-8.6
cm-4.95g
- Acute LC50 93 to Fish-Rainbow trout, 96 hours
107 ug/L Fresh Donaldson
water trout-Oncorhynchus
mykiss-Swim-up-0.17g
- Acute LC50 92.88 Crustaceans-Water 48 hours
ug/L Fresh water flea-Moina
irrasa-Neonate-<24
hours
- Acute LC50 334 to Daphnia-Water 48 hours
540 ug/L fresh flea-Daphnia magna-<1
water days
- Acute LC50 77.46 Crustaceans-Water 48 hours
ug/L Fresh water flea-Moina
irrasa-Neonate-<24
hours
- Acute LC50 66 to Fish-Rainbown trout, 96 hours
79 ug/L Fresh Donaldson
water trout-Oncorhynchus
mykiss-FRY-2.36 to 3.01
g
- Acute LC50 59.24 Crustaceans-Water 48 hours
ug/L Fresh water flea-Moina
irrasa-Neonate-<24
hours
- Acute LC50 260 to Daphnia-Water 48 hours
350 ug/L Fresh flea-Daphnia Pulex->=6
water days
- Acute LC50 49.99 Crustaceans-Water 48 hours
ug/L Fresh water flea-Moina
irrasa-Neonate-<24
hours
- Acute LC50 30 Fish-Inland 96 hours
ug/L Marine water silverside-Menidia
beryllina-14 days
- Acute LC50 Daphnia-Water flea - 48 hours
232.488 to Daphnia pulex - Adult
251.478 ug/L
Fresh water
- Chronic NOEC 0.1 Fish-Nile 96 hours
mg/L Fresh water tilapia-Tilapia
nilotica-14.7 cm
13. DISPOSAL CONSIDERATIONS
Waste The generation of waste should be avoided or minimized wherever
disposal: possible. Empty containers or liners may retain some product
residues. This material and its container must be disposed of in
a safe way. Dispose of surplus and non-recyclable products via a
licensed waste disposal contractor. Disposal of this product,
solutions and any by-products should at all times comply with
the requirements of environmental protection and waste disposal
legislation and any regional local authority requirements. Avoid
dispersal of spilled material and runoff and contact with soil,
waterways, drains and sewers.
Disposal should be in accordance with applicable regional, national and local
laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE
CONTROLS/PERSONAL PROTECTION for additional handling information and
protection of employees.
14. TRANSPORT INFORMATION
Regulatory UN number Proper shipping Classes PG* Label Additional
information name informatio
n
DOT Classification Not - - -
regulated
*PG: Packing Group
15. REGULATORY INFORMATION
United States
HCS Toxic material
Classification: Corrosive material
Target organ effects
U.S. Federal All ingredients comply with applicable rules or orders under
regulations: United States TSCA.
All components are listed or exempted.
TSCA 5(a)2 proposed significant rules: No products were
found.
TSCA 5(a)2 final significant rules: No products were found.
TSCA 12(b) one-time export: No products were found.
SARA 313
Product name
Form R - Reporting Zinc chloride
requirements:
Supplier Zinc chloride
notification:
California Prop. 65
WARNING: This product contains less than 0.1% of a chemical known to the
State of California to cause cancer.
WARNING: This product contains less than 1% of a chemical known to the State
of California to cause birth defects or other reproductive harm.
Canada
WHMIS (Canada): Class D-1B: Material causing immediate and serious
toxic effects (Toxic).
Class E: Corrosive material
Canada Inventory: All components are listed or exempted.
International lists
China inventory All components are listed or exempted.
(IECSC):
Europe inventory: Not determined.
Australia inventory All components are listed or exempted.
(AICS):
Japan inventory Not determined.
(ENCS):
Korea inventory All components are listed or exempted
(KECI):
Philippines inventory All components are listed or exempted.
(PICCS):
16. OTHER INFORMATION
Definition of Terms
ACGIH American Conference of Governmental Industrial
Hygienists
Ceiling Maximum exposure limit defined by OSHA
CAS Chemical Abstract Service
IARC International Agency for Research on Cancer
NIOSH National Institute for Occupational Safety and Health
NTP National Toxicology Program
OSHA Occupational Safety and Health Administration
PEL Permissible Exposure Limit
REL Recommended Exposure Limit
RTK Right to Know
SARA Superfund Amendments and Reauthorization Act
STEL Short Term Exposure Limit
TLV ACGIH Threshold Limit Value
TLV-C ACGIH Threshold Limit Value, Ceiling
TRADE SECRET Claimed as allowed under 29CFRS1910-1200
TSCA Toxic Substances Control Act
PPE Personal Protection Equipment
CEPA Canadian Environmental Protection Act
DSL Domestic Substance List
NDSL Non-domestic Substance List
NSN New Substance Notification Rules
Disclaimer
The information contained herein is based on data considered accurate.
However, no warranty is expressed of implied regarding the accuracy of these
data or the results to be obtained from the use thereof. Additionally, Cookson
Electronics assumes no responsibility for injury to the vendee or third
persons proximately caused by the material even if reasonable safety
procedures are followed. Furthermore, vendee assumes the risk in his use of
the material.
The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance. For more product information by email, click here Imperial Supplies LLC does not provide services and products outside the United States |
