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MSDS 82105 82105: Solder Acid [1]MSDS Last updated: 08/28/2009
Alpha
MATERIAL SAFETY DATA SHEET
Emergency phone: US & Canada: 800-424-9300
Mexico: 01 800 022 1400, (55) 5559 1588
Health 2
Flammability 1
Instability 0
Special
Health 2
Flammability 1
Physical hazards 0
Personal Protection
1. Product and company identification
Product name: Solder Wire Cored 40Sn/60Pb Alloy, AC94 Flux
Product code: M040AC94
Manufacturer: Cookson Electronics
109 Corporate Blvd
South Plainfield, NJ 07080
Toll Free: (800) 367-5460
Main Phone: (908) 791-3000
Fax: (908) 791-3090
www.alphametals.com
Cookson Electronics Mexico, S.A.de C.V
Avenida nafta NO. 800,
Parque Industrial Stiva Aeropuerto
Apodaca, Nuevo Leon, C.P. 66600
Mexico
www.cooksonelectronics.com
Customer Service: (814) 946-1611
Validation date: 2/3/2009. Supersedes Date: 6/6/2008
Prepared by: T. Valverde
(203)-799-4917
2. Hazards identification
Physical state: Solid.
Odor: None.
OSHA/HCS status: This material is considered hazardous by the OSHA
Hazard Communication Standard (29 CFR 1910.1200).
Emergency overview: WARNING!
Toxic by inhalation and if swallowed. Irritating to
eyes, respiratory system and skin. Do not ingest.
Avoid contact with eyes, skin and clothing. Contains
material that can cause target organ damage. Contains
material which may cause cancer. Risk of cancer
depends on duration and level of exposure. Contains
material which may cause heritable genetic effects,
based on animal data. Contains material which may
cause birth defects, based on animal data. Contains
material which can cause developmental abnormalities.
Avoid exposure during pregnancy. Contains material
which can impair male fertility. Contains material
which can impair female fertility. Use only with
adequate ventilation. Keep container tightly closed
and sealed until ready for use. Wash thoroughly after
handling.
Routes of entry: Dermal contact. Eye contact. Inhalation. Ingestion.
Potential acute health effects
Inhalation: Toxic by inhalation. Can cause target organ damage.
Irritating to respiratory system. Exposure to
decomposition products may cause a health hazard.
Serious effects may be delayed following exposure. The
exposed person may need to be kept under medical
surveillance for 48 hours.
Ingestion: Toxic if swallowed. Can cause target organ damage.
Ingestion may cause gastrointestinal irritation and
diarrhea.
Skin: Irritating to skin. Skin inflammation is characterized
by itching, scaling, reddening or, occasionally,
blistering.
Eyes: Irritating to eyes. Adverse symptoms may include the
following: redness, itching, swelling, pain
Potential chronic health effects
Chronic effects: Adverse symptoms may include the following:
Lead: Poison! Other adverse effects: abdominal cramps
and pain, nausea or vomiting, headache, muscle
weakness, metallic taste, loss of appetite, insomnia,
dizziness/vertigo, "lead line" on gums, high lead
levels in blood and urine, loss of consciousness or
coma and death. Chronic effects: irritability, visual
disturbances, blood pressure elevation and
discoloration of: skin.
Tin: Prolonged or repeated exposure may cause benign
pneumoconiosis (Stannosis).
urea: mental confusion or disorientation, headache.
Chronic effects: proteinuria, weight loss.
Target organs: Contains material which causes damage to the following
organs: upper respiratory tract, skin, eye, lens or
cornea.
Contains material which may cause damage to the
following organs: blood, kidneys, the reproductive
system, mucous membranes, gastrointestinal tract,
cardiovascular system, central nervous system (CNS).
Carcinogenicity: Contains material which may cause cancer. Risk of
cancer depends on duration and level of exposure.
Mutagenicity: Contains material which may cause heritable genetic
effects.
Teratogenicity: Contains material which may cause birth defects, based
on animal data.
Developmental effects: Contains material which can cause developmental
abnormalities.
Fertility effects: Contains material which can impair male fertility.
Contains material which can impair female fertility.
California Prop. 65 WARNING: This product contains a chemical known to the
State of California to cause cancer and birth defects
or other reproductive harm.
Medical conditions Pre-existing respiratory, skin and digestive disorders
aggravated by and disorders involving any other target organs
over-exposure: mentioned in this MSDS as being at risk may be
aggravated by overexposure to this product
3. Composition/information on ingredients
Name CAS number % by weight
Lead 7439-92-1 50-60
Tin 7440-31-5 30-40
Urea 57-13-6 1-5
Any ingredient not listed in Section 3 is non-regulated or present in the
product in concentrations below legal disclosure limits.
4. First aid measures
Eye contact: Check for and remove any contact lenses. Get medical
attention if irritation occurs. Immediately flush eyes
with running water for at least 30 minutes, keeping
eyelids open.
Skin contact: Flush contaminated skin with plenty of water. Remove
contaminated clothing and shoes. Continue to rinse for
at least 15 minutes. Get medical attention. Wash
contaminated clothing before reuse. Clean shoes
thoroughly before reuse. In case of contact,
immediately flush skin with plenty of water for at least
15 minutes while removing contaminated clothing and
shoes.
Inhalation: Get medical attention immediately. Move exposed person
to fresh air. If it is suspected that fumes are still
present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. Keep person warm
and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide
artificial respiration or oxygen by trained personnel.
It may be dangerous to the person providing aid to give
mouth to mouth resuscitation. If unconscious, place in
recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as
a collar, tie, belt or waistband. In case of inhalation
of decomposition products in a fire, symptoms may be
delayed. The exposed person may need to be kept under
medical surveillance for 48 hours.
Ingestion: Get medical attention immediately. Wash out mouth with
water. Remove dentures if any. Move exposed person to
fresh air. Keep person warm and at rest. Do not induce
vomiting unless directed to do so by medical personnel.
If vomiting occurs, the head should be kept low so that
vomit does not enter the lungs. Never give anything by
mouth to an unconscious person. If unconscious, place
in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight
clothing such as a collar, tie belt or waistband. If
not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel.
Protection of No action shall be taken involving any personal risk or
first-aiders: without suitable training. It may be dangerous to the
person providing aid to give mouth to mouth
resuscitation. Wear suitable protective clothing,
gloves and eye/face protection. If it is suspected that
fumes are still present, the rescuer should wear an
appropriate mask or self-contained breathing apparatus.
Wash contaminated clothing thoroughly with water before
removing it, or wear gloves.
5. Fire-fighting measures
Flammability of the No specific fire or explosion hazard.
product:
Extinguishing media
Suitable: Use an extinguishing agent suitable for the surrounding
fire.
Not Suitable: Not known.
Special exposure Promptly isolate the scene by removing all persons from
hazards: the vicinity of the incident if there is a fire. No
action shall be taken involving any personal risk or
without suitable training.
Hazardous combustion Carbon oxides
products: Nitrogen oxides
Metal oxide/oxides
Special protective Fire-fighters should wear appropriate protective
equipment for equipment and self-contained breathing apparatus (SCBA)
fire-fighters with a full face-piece operated in positive pressure
mode.
6. Accidental release measures
Personal precautions: No action shall be taken involving any personal risk or
without suitable training. Evacuate surrounding areas.
Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled
material. Provide adequate ventilation. Wear
appropriate respirator when ventilation is inadequate.
Put on appropriate personal protective equipment (see
section 8).
Environmental Avoid dispersal of spilled material and runoff and
precautions: contact with soil, waterways, drains and sewers. Inform
the relevant authorities if the product has caused
environmental pollution (sewers, waterways, soil or air)
Large spill: Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses,
basements or confined areas. Vacuum or sweep up
material and place in a designated, labeled waste
container. Dispose of via a licensed waste disposal
contractor. Note: see section 1 for emergency contact
information and section 13 for waste disposal.
Small spill: Move containers from spill area. Vacuum or sweep up
material and place in a designated, labeled waste
container. Dispose of via a licensed waste disposal
contractor.
7. Handling and storage
Handling: Put on appropriate personal protective equipment (see section 8).
Eating, drinking and smoking should be prohibited in areas where
this material is handled, stored and processed. Workers should
wash hands and face before eating, drinking and smoking. Avoid
exposure during pregnancy. Do not get in eyes or on skin or
clothing. Do not ingest. Use only with adequate ventilation.
Wear appropriate respirator when ventilation is inadequate. Keep
in the original container or approved alternative container.
Containers should be kept closed when not in use. Empty containers
retain product residue and can be hazardous. Do not reuse
container.
Storage: Store in accordance with local regulations. Store in original
container protected from direct sunlight in a dry, cool and
well-ventilated area away from incompatible materials (see section
10) and food and drink. Keep container tightly closed and sealed
until ready for use. Containers that have been opened must be
carefully resealed and kept upright to prevent leakage. Do not
store in unlabeled containers. Use appropriate containment to
avoid environmental contamination.
Keep container in a cool, well-ventilated area. Keep container
tightly closed and sealed until ready for use. Avoid all possible
sources of ignition (spark or flame).
8. Exposure controls/personal protection
Product name CAS number Exposure limits
Lead 7439-92-1 OSHA PEL (United States, 5/2005).
TWA: 0.05 mg/m3 8 hour(s).
ACGIH TLV (United States, 1/2008). Notes: as Pb
TWA: 0.05 mg/m3 8 hour(s).
OSHA PEL (United States, 11/2006). Notes: as Pb
TWA: 50 ug/m3, (asPb) 8 hour(s).
NIOSH REL (United States, 6/2008). Notes: See
Appendix C-
Supplemental Exposure limits Note: The REL and PEL
also apply to other lead compounds (as Pb).
TWA: 0.05 mg/m3 10 hour(s).
Tin 7440-31-5 OSHA PEL (United States, 9/2005).
TWA: 2 mg/m3 8 hour(s).
ACGIH TLV (United States, 1/2008).
TWA: 2 mg/m3 8 hour(s).
NIOSH REL (United States, 6/2008). Notes: Note: The
REL and PEL also apply to other inorganic tin
compounds (as Sn) except tin oxides
TWA: 2 mg/m3 10 hour(s).
Urea 57-13-6 AIHA WEEL (United States, 1/2008).
TWA: 10 mg/m3 8 hour(s).
Consult local authorities for acceptable exposure limits.
Recommended monitoring If this product contains ingredients with exposure
procedures: limits, personal, workplace atmosphere or biological
monitoring may be required to determine the
effectiveness of the ventilation or other control
measures and/or the necessity to use respiratory
protective equipment.
Engineering measures: Use only with adequate ventilation. Use process
enclosures, local exhaust ventilation or other
engineering controls to keep worker exposure to
airborne contaminants below any recommended or
statutory limits. Processes should be designed to
minimize airborne and skin exposure to hazardous
substances.
Hygiene measures: Wash hands, forearms and face thoroughly after handling
chemical products, before eating, smoking and using the
lavatory and at the end of the working period.
Appropriate techniques should be used to remove
potentially contaminated clothing. Wash contaminated
clothing before reusing. Ensure that eyewash stations
and safety showers are close to the workstation
location. Eating, drinking and smoking should be
prohibited in areas where this material is handled,
stored and processed. Remove/Take off immediately all
contaminated clothing. Contaminated work clothing
should not be allowed out of the workplace.
Personal protection
Respiratory: Use properly fitted, air-purifying or air-fed
respirator complying with an approved standard if a
risk assessment indicates this is necessary.
Respirator selection must be based on known or
anticipated exposure levels, the hazards of the product
and the safe working limits of the selected respirator.
Hands: Chemical-resistant, impervious gloves complying with an
approved standard should be worn at all times when
handling chemical products if a risk assessment
indicates this is necessary. The user must check that
the final choice of type of glove selected for handling
this product is the most appropriate and takes into
account the particular conditions of use, as included
in the user's risk assessment.
Eyes: Avoid contact with eyes. Safety eyewear should be used
when there is a likelihood of exposure.
Skin: Avoid contact with skin and clothing. Wear protective
clothing. Body garments used should be based upon the
task being performed (e.g., lab coat, chemical
resistant protective suit, sleevelets, synthetic apron,
gauntlets) to avoid exposed skin surfaces. Wash
contaminated clothing thoroughly with water before
removing it, or wear gloves.
Environmental exposure Emissions from ventilation or work process equipment
controls: should be checked to ensure they comply with the
requirements of environmental protection legislation.
In some cases, fume scrubbers, filters or engineering
modifications to the process equipment will be
necessary to reduce emissions to acceptable levels.
9. Physical and chemical properties
Physical state: Solid
Flash point: Not available.
Auto-ignition Not available.
temperature:
Flammable limits: Not available.
Color: Gray.
Odor: None.
pH: Not available.
Boiling/condensation Not available.
point:
Melting/freezing Not available.
point:
Vapor pressure: Not available.
Vapor density: Not available.
Odor threshold: Not available.
Evaporation rate: Not available.
VOC: 25.5 g/l
Solubility: Insoluble in the following materials: cold water and
hot water.
10. Stability and reactivity
Stability: The product is stable
Conditions to avoid: No specific data.
Incompatibility with Reactive with oxidizing agents, reducing agents, acids,
various substances: alkalis.
Chlorine, peroxides.
Hazardous decomposition Under normal conditions of storage and use, hazardous
products: decomposition products should not be produced
Other Hazardous Metal oxides, toxic. Fumes
decomposition products:
Hazardous Under normal conditions of storage and use, hazardous
polymerization: polymerization will not occur.
11. Toxicological information
Acute toxicity
Product/
ingredient name Result Species Dose Exposure
Lead LDLo Rat 1 g/kg -
Intraperitoneal
TDLo Oral Rat 0.2 mg/kg -
Urea LD50 Oral Mouse 11 g/kg -
LD50 Oral Rat 8471 mg/kg -
LDLo Oral Rabbit 10 g/kg -
Carcinogenicity
Classification
Product/
ingredient name ACGIH IARC EPA NIOSH NTP OSHA
lead A3 2B - - Possible -
Mutagenicity
Product/
ingredient name Test Experiment Result
lead - Mammalian-Animal Equivocal
Urea - In vitro; Mammalian - Positive
Human; Germ
Teratogenicity
Product/
ingredient name Result Species Dose Exposure
lead Equivocal- 10mg/m3 10mg/m3 24 hours per day
Inhalation
Equivocal 2118 mg/kg 2118 -
-Oral mg/kg
Reproductive toxicity
Product/ Maternal Development
ingredient name toxicity Fertility toxin Species Dose Exposure
lead - Equivocal - Mouse Oral: -
4099.2
mg/kg
Equivocal - - Mouse- Oral: 300 -
Female mg/kg
- - Equivocal Rat - Inhalatio 24 hours
Female n: per day
3
- - Equivocal Rat - Oral: 520 -
Female mg/kg
Alpha has not conducted specific studies on the toxicity of this product.
12. Ecological information
Aquatic ecotoxicity
Product/
ingredient name Test Result Species Exposure
Lead - Acute LC50 1.17 Fish - Rainbow 96 hours
mg/L Fresh water trout, Donaldson
trout -
Oncorhynchus
mykiss - 145mm
- Acute LC50 38829 Fish - Inland 96 hours
to 71806 ppb silverside-
Marine water Menidia beryllina
- Acute LC50 26150 Fish - Inland 96 hours
to 44761 ppb silverside-
Marine water Menidia beryllina
- Acute LC50 1.33 Fish - cyprinus 96 hours
ppm Fresh water carpio - Juvenile
(Fledgling,
Hatchling,
Weanling) - 6.5
cm
- Acute LC50 0.8 Fish - cyprinus 96 hours
ppm Fresh water carpio - Juvenile
(Fledgling,
Hatchling,
Weanling) - 6.5
cm
- Acute LC50 0.44 Fish - cyprinus 96 hours
ppm Fresh water carpio - Juvenile
(Fledgling,
Hatchling,
Weanling) - 3.5
cm
- Acute LC50 4500 Crustaceans - 48 hours
to 5500 ug/L Water flea -
Fresh water Simocephalus
vetulus -<24
hours
- Acute LC50 4460 Crustaceans - 48 hours
ug/L Marine water Indian prawn -
Panaeus indicus -
6 to 9 cm
- Acute LC50 4400 Daphnia - Water 48 hours
to 5300 ug/L flea - Daphnia
Fresh water magna - <24 hours
- Acute LC50 2800 Fish - Smallmouth 96 hours
ug/L Fresh water bass -
Micropterus
dolmieui -
Swim-up
- Acute LC50 2200 Fish - Smallmouth 96 hours
ug/L Fresh water bass -
Micropterus
dolomieui -
Swim-up
- Acute LC50 933 to Crustaceans - 48 hours
1200 ug/L Marine Fleshy prawn -
water Penaeus chinensis
- Acute LC50 530 Daphnia - Water 48 hours
ug/L Fresh water felat-
Ceriodaphnia
reticulate - <4
hours
- Acute LC50 29000 Fish-Smallmouth 96 hours
ug/L Fresh water bass -
Micropterus
dolomieui-Fingerl
ing
- Acute LC50 40000 Fish - Goldfish - 96 hours
ug/L Fresh water Carassius auratus
- Acute LC50 5100 Daphnia - Water 48 hours
ug/L Fresh water flea - Daphnia
pulex - < 24
hours
- Acute LC50 5010 Crustaceans - 48 hours
ug/L Marine water Brine shrimp -
Artemia salina
urea - Acute EC50 6573.1 Daphnia - Water 48 hours
to 7061 mg/L flea -
Fresh water Ceriodaphnia
dubia - Neonate
-< 24 hours
- Acute EC50 Daphnia - Water 48 hours
3910000 ug/L flea - Daphnia
Fresh water magna - Neonate -
<24 hours
- Acute LC50 83700 Fish - Rohu - 96 hours
to 86900 ug/L Labeo rohita -
Fresh water FRY - 0.8 g
- Acute LC50 72600 Labeo rohita - 96 hours
to 75900 ug/L Egg
Fresh water
- Acute LC50 66800 Fish - Rohu - 96 hours
to 70500 ug/L Labeo rohita -
Fresh water Egg
- Acute LC50 65800 Fish - Rohu - 96 hours
to 70200 ug/L Labeo rohita -
Fresh water FRY - 0.8 g
- Acute LC50 64700 Fish - Rohu - 96 hours
to 69200 ug/L Labeo rohita -
Fresh water Egg
- Acute LC50 23400 Fish - Rohu - 96 hours
to 26500 ug/L Labeo rohita -
Fresh water Egg
- Acute LC50 22500 Fish - Mozambique 96 hours
ug/L tilapia - Tilapia
-mossambica
- Acute LC50 16700 Fish - Rohu - 96 hours
to 19600 ug/L Labeo rohita -
Fresh water Egg
- Acute LC50 90100 Fish - Rohu - 96 hours
to 93900 ug/L Labeo rohita -
Fresh water FRY - 0.8 g
- Acute LC50 5000 Fish - Giant 96 hours
ug/L Fresh water gourami - Colisa
fasciata -
Fingerling
13. Disposal considerations
Waste The generation of waste should be avoided or minimized whenever
Disposal: possible. Empty containers or liners may retain some product
residues. This material and its container must be disposed of
in a safe way. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Disposal of this
product, solutions and any by-products should at all times
comply with the requirements of environmental protection and
waste disposal legislation and any regional local authority
requirements. Avoid dispersal of spilled material and runoff
and contact with soil, waterways, drains and sewers.
Disposal should be in accordance with applicable regional, national and local
laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE
CONTROLS/PERSONAL PROTECTION for additional handling information and protection
of employees.
14. Transport information
Regulatory UN number Proper Classes PG* Label Additional
information shipping name Information
DOT Not regulated. - - -
Classification
PG*: Packing group
15. Regulatory information
United States
HCS Classification: Toxic material
Irritating material
Carcinogen
Target organ effects
U.S. Federal All ingredients comply with applicable rules or orders
regulations: under United States TSCA.
All components are listed or exempted.
TSCA 5(a)2 proposed significant rules: No products were
found.
TSCA 5(a)2 final significant rules: No products were
found.
TSCA 12(b) one-time export: No products were found.
SARA 313
Product name
Form R - Reporting requirements Lead
Supplier notification lead
California Prop. 65
WARNING: This product contains a chemical known to the State of California to
cause cancer and birth defects or other reproductive harm.
Canada
WHMIS (Canada): Class D-2A: Material causing other toxic effects (Very
toxic).
Canada Inventory: All components are listed or exempted.
International lists
China inventory All components are listed or exempted.
(IECSC):
Europe inventory: All components are listed or exempted.
Australia inventory All components are listed or exempted.
(AICS):
Japan inventory(ENCS): Not determined.
Not determined.
Korea inventory(KECI): All components are listed or exempted.
Philippines inventory All components are listed or exempted.
(PICCS):
16. Other information
Definition of Terms
ACGIH American Conference of Governmental Industrial Hygienists
Ceiling Maximum exposure limit defined by OSHA
CAS Chemical Abstract Service
IARC International Agency for Research on Cancer
NIOSH National Institute for Occupational Safety and Health
NTP National Toxicology Program
OSHA Occupational Safety and Health Administration
PEL Permissible Exposure Limit
REL Recommended Exposure Limit
RTK Right to Know
SARA Superfund Amendments and Reauthorization Act
STEL Short Term Exposure Limit
TLV ACGIH Threshold Limit Value
TLV-C ACGIH Threshold Limit Value, Ceiling
TRADE SECRET Claimed as allowed under 29CFRS1910.1200
TSCA Toxic Substances Control Act
PPE Personal Protection Equipment
CEPA Canadian Environmental Protection Act
DSL Domestic Substance List
NDSL Non-Domestic Substance List
NSN New Substance Notification Rules
Disclaimer
The information contained herein is based on data considered accurate.
However, no warranty is expressed of implied regarding the accuracy of these
data or the results to be obtained from the use thereof. Additionally, Cookson
Electronics assumes no responsibility for injury to the vendee or third persons
proximately caused by the material even if reasonable safety procedures are
followed. Furthermore, vendee assumes the risk in his use of the material.
The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance. For more product information by email, click here Imperial Supplies LLC does not provide services and products outside the United States |
