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MSDS 82104 82104: Solder Rosin [1]MSDS Last updated: 08/26/2009
Alpha
MATERIAL SAFETY DATA SHEET
Emergency phone: US & Canada: 800-424-9300
Mexico: 01 800 022 1400, (55) 5559 1588
Health 2
Flammability 1
Instability 0
Special
Health 2
Flammability 1
Physical hazards 0
Personal Protection
1. Product and company identification
Product name: Solder Wire Cored 40Sn/60Pb Alloy, RA-32 Flux
Product code: M040RA32
Manufacturer: Cookson Electronics
109 Corporate Blvd
South Plainfield, NJ 07080
Toll Free: (800) 367-5460
Main Phone: (908) 791-3000
Fax: (908) 791-3090
www.alphametals.com
Cookson Electronics Mexico, S.A.de C.V
Avenida nafta NO. 800,
Parque Industrial Stiva Aeropuerto
Apodaca, Nuevo Leon, C.P. 66600
Mexico
www.cooksonelectronics.com
Customer Service: (814) 946-1611
Validation date: 2/3/2009. Supersedes Date : 6/6/2008
Prepared by: T. Valverde
(203)-799-4917
2. Hazards identification
Physical state: Solid.
Odor: None.
OSHA/HCS status: This material is considered hazardous by the OSHA
Hazard Communication Standard (29 CFR 1910.1200).
Emergency overview: DANGER!
Very toxic if swallowed. Toxic by inhalation.
Irritating to eyes, respiratory system and skin. May
cause sensitization by skin contact. Do not ingest.
Do not get on skin or clothing. Avoid contact with
eyes. Contains material that can cause target organ
damage. Contains material which may cause cancer.
Risk of cancer depends on duration and level of
exposure. Contains material which may cause heritable
genetic effects, based on animal data. Contains
material which may cause birth defects, based on animal
data. Contains material which can cause developmental
abnormalities. Avoid exposure during pregnancy.
Contains material which can impair male fertility.
Contains material which can impair female fertility.
Use only with adequate ventilation. Keep container
tightly closed and sealed until ready for use. Wash
thoroughly after handling.
Routes of entry: Dermal contact. Eye contact. Inhalation. Ingestion.
Potential acute health effects
Inhalation: Toxic by inhalation. Can cause target organ damage.
Irritating to respiratory system.
Ingestion: Very toxic if swallowed. Can cause target organ
damage. Ingestion may cause gastrointestinal
irritation and diarrhea.
Skin: Irritating to skin. May cause sensitization by skin
contact. Skin inflammation is characterized by
itching, scaling, reddening or, occasionally,
blistering. Prolonged or repeated contact may cause
dermatitis. Once sensitized a severe allergic reaction
may occur when subsequently exposed to very low levels.
In the event of any complaints or symptoms, avoid
further exposure. Persons with a history of skin
sensitization problems should not be employed in any
process in which this product is used.
Eyes: Irritating to eyes. Adverse symptoms may include the
following: redness, itching, swelling, pain
Potential chronic health effects
Chronic effects: Adverse symptoms may include the following:
Lead: Poison! Other adverse effects: abdominal cramps
and pain, nausea or vomiting, headache, muscle
weakness, metallic taste, loss of appetite, insomnia,
dizziness/vertigo, "lead line" on gums, high lead
levels in blood and urine, loss of consciousness or
coma and death. Chronic effects: irritability, visual
disturbances, blood pressure elevation and
discoloration of: skin.
Tin: Prolonged or repeated exposure may cause benign
pneumoconiosis (Stannosis).
Rosin: May cause allergic skin reactions with repeated
exposure. Prolonged inhalation of fumes may cause
respiratory sensitization.
Target organs: Contains material which causes damage to the following
organs: upper respiratory tract, skin, eye, lens or
cornea.
Contains material which may cause damage to the
following organs: blood, kidneys, the reproductive
system, mucous membranes, gastrointestinal tract,
central nervous system (CNS).
Carcinogenicity: Contains material which may cause cancer. Risk of
cancer depends on duration and level of exposure.
Mutagenicity: Contains material which may cause heritable genetic
effects, based on animal data.
Teratogenicity: Contains material which may cause birth defects, base
don animal data.
Developmental effects: Contains material which can cause developmental
abnormalities.
Fertility effects: Contains material which can impair male fertility.
Contains material which can impair female fertility.
California Prop. 65: WARNING: This product contains a chemical known to the
State of California to cause cancer and birth defect or
other reproductive harm.
Medical conditions Pre-existing respiratory, skin and digestive disorders
aggravated by and disorders involving any other target organs
over-exposure: mentioned in this MSDS as being at risk may be
aggravated by overexposure to this product. Persons
with a history of skin sensitization problems should
not be employed in any process in which this product is
used.
3. Composition/information on ingredients
Name CAS number % by weight
Lead 7439-92-1 50-60
Tin 7440-31-5 30-40
Rosin 8050-09-7 1-5
Any ingredient not listed in Section 3 is non-regulated or present in the
product in concentrations below legal disclosure limits.
4. First aid measures
Eye contact: Check for and remove any contact lenses. Get medical
attention if irritation occurs. Immediately flush eyes
with running water for at least 30 minutes, keeping
eyelids open.
Skin contact: Flush contaminated skin with plenty of water. Remove
contaminated clothing and shoes. Continue to rinse for at
least 15 minutes. Get medical attention. May cause
sensitization by skin contact. Once sensitized, a severe
allergic reaction may occur when subsequently exposed to
very low levels. Wash contaminated clothing before reuse.
Clean shoes thoroughly before reuse. In case of contact,
immediately flush skin with plenty of water for at least
15 minutes while removing contaminated clothing and shoes.
Inhalation: Get medical attention immediately. Move exposed person to
fresh air. If it is suspected that fumes are still
present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. Keep person warm and
at rest. If not breathing, if breathing is irregular or
if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be
dangerous to the
person providing aid to give mouth to mouth resuscitation.
If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen
tight clothing such as a collar, tie, belt or waistband.
Ingestion: Get medical attention immediately. Wash out mouth with
water. Remove dentures if any. Move exposed person to
fresh air. Keep person warm and at rest. Do not induce
vomiting unless directed to do so by medical personnel.
If vomiting occurs, the head should be kept low so that
vomit does not enter the lungs. Never give anything by
mouth to an unconscious person. If unconscious, place in
recovery position and get medical attention immediately.
Maintain an
open airway. Loosen tight clothing such as a collar, tie
belt or waistband. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide
artificial respiration or oxygen by trained personnel.
Protection of No action shall be taken involving any personal risk or
first-aiders: without suitable training. It may be dangerous to the
person providing aid to give mouth to mouth resuscitation.
Wear suitable protective clothing, gloves and eye/face
protection. If it is suspected that fumes are still
present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. Wash contaminated
clothing thoroughly with water before removing it, or wear
gloves.
5. Fire-fighting measures
Flammability of the No specific fire or explosion hazard.
product:
Extinguishing media
Suitable: Use an extinguishing agent suitable for the surrounding
fire.
Not Suitable: Not known.
Special exposure Promptly isolate the scene by removing all persons from
hazards: the vicinity of the incident if there is a fire. No
action shall be taken involving any personal risk or
without suitable training.
Hazardous combustion Metal oxide/oxides
products:
Speical protective Fire-fighters should wear appropriate protective
equipment for equipment and self-contained breathing apparatus (SCBA)
fire-fighters: with a full face-piece operated in positive pressure
mode.
6. Accidental release measures
Personal precautions: No action shall be taken involving any personal risk or
without suitable training. Evacuate surrounding areas.
Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled
material. Provide adequate ventilation. Wear
appropriate respirator when ventilation is inadequate.
Put on appropriate personal protective equipment (see
section 8).
Environmental Avoid dispersal of spilled material and runoff and
precautions: contact with soil, waterways, drains and sewers.
Inform the relevant authorities if the product has
caused environmental pollution (sewers, waterways, soil
or air)
Large spill: Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses,
basements or confined areas. Vacuum or sweep up
material and place in a designated, labeled waste
container. Dispose of via a licensed waste disposal
contractor. Note: see section 1 for emergency contact
information and section 13 for waste disposal.
Small spill: Move containers from spill area. Vacuum or sweep up
material and place in a designated, labeled waste
container. Dispose of via a licensed waste disposal
contractor.
7. Handling and storage
Handling: Put on appropriate personal protective equipment (see section
8). Eating, drinking and smoking should be prohibited in areas
where this material is handled, stored and processed. Workers
should wash hands and face before eating, drinking and smoking.
Persons with a history of skin sensitization problems should not
be employed in any process in which this product is used. Avoid
exposure during pregnancy. Do not get in eyes or on skin or
clothing. Do not ingest. Use only with adequate ventilation.
Wear appropriate respirator when ventilation is inadequate.
Keep in the original container or approved alternative
container. Containers should be kept closed when not in use.
Empty containers retain product residue and can be hazardous.
Do not reuse container.
Storage: Store in accordance with local regulations. Store in original
container protected from direct sunlight in a dry, cool and
well-ventilated area away from incompatible materials (see
section 10) and food and drink. Keep container tightly closed
and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent
leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination.
Keep container in a cool, well-ventilated area. Keep container
tightly closed and sealed until ready for use. Avoid all
possible sources of ignition (spart or flame).
8. Exposure controls/personal protection
Product name CAS number Exposure limits
Lead 7439-92-1 OSHA PEL (United States, 5/2005).
TWA: 0.05 mg/m3 8 hour(s).
ACGIH TLV (United States, 1/2008). Notes: as Pb
TWA: 0.05 mg/m3 8 hour(s).
OSHA PEL (United States, 11/2006). Notes: as Pb
TWA: 50 ug/m3, (asPb) 8 hour(s).
NIOSH REL (United States, 6/2008). Notes: See
Appendix C-
Supplemental Exposure limits Note: The REL and PEL
also apply to other lead compounds (as Pb).
TWA: 0.05 mg/m3 10 hour(s).
Tin 7440-31-5 OSHA PEL (United States, 9/2005).
TWA: 2 mg/m3 8 hour(s).
ACGIH TLV (United States, 1/2008).
TWA: 2 mg/m3 8 hour(s).
NIOSH REL (United States, 6/2008). Notes: Note:
The REL and PEL also apply to other inorganic tin
compounds (as Sn) except tin oxides
TWA: 2 mg/m3 10 hour(s).
Rosin 8050-09-7 NIOSH REL (United States, 6/2008). Notes: As
formaldehyde
TWA: 0.1 mg/m3 (as formaldehyde) 10 hour(s).
OSHA PEL 1989 (United States, 3/1989). Notes:
measured as formaldehyde
TWA: 0.1 mg/m3 (measured as formaldehyde) 8
hour(s).
Consult local authorities for acceptable exposure limits.
Recommended monitoring If this product contains ingredients with exposure
procedures: limits, personal, workplace atmosphere or biological
monitoring may be required to determine the
effectiveness of the ventilation or other control
measures and/or the necessity to use respiratory
protective equipment.
Engineering measures: Use only with adequate ventilation. Use process
enclosures, local exhaust ventilation or other
engineering controls to keep worker exposure to
airborne contaminants below any recommended or
statutory limits. Processes should be designed to
minimize airborne and skin exposure to hazardous
substances.
Hygiene measures: Wash hands, forearms and face thoroughly after
handling chemical products, before eating, smoking and
using the lavatory and at the end of the working
period. Appropriate techniques should be used to
remove potentially contaminated clothing. Wash
contaminated clothing before reusing. Ensure that
eyewash stations and safety showers are close to the
workstation location. Eating, drinking and smoking
should be prohibited in areas where this material is
handled, stored and processed. Remove/Take off
immediately all contaminated clothing. Contaminated
work clothing should not be allowed out of the
workplace.
Personal protection
Respiratory: Use properly fitted, air-purifying or air-fed
respirator complying with an approved standard if a
risk assessment indicates this is necessary.
Respirator selection must be based on known or
anticipated exposure levels, the hazards of the
product and the safe working limits of the selected
respirator.
Hands: Chemical-resistant, impervious gloves complying with
an approved standard should be worn at all times when
handling chemical products if a risk assessment
indicates this is necessary. The user must check that
the final choice of type of glove selected for
handling this product is the most appropriate and
takes into account the particular conditions of use,
as included in the user's risk assessment.
Eyes: Avoid contact with eyes. Safety eyewear should be
used when there is a likelihood of exposure.
Skin: Avoid contact with skin and clothing. Wear protective
clothing. Body garments used should be based upon the
task being performed (e.g., lab coat, chemical
resistant protective suit, sleevelets, synthetic
apron, gauntlets) to avoid exposed skin surfaces. Wash
contaminated clothing thoroughly with water before
removing it, or wear gloves.
Environmental exposure Emissions from ventilation or work process equipment
controls: should be checked to ensure they comply with the
requirements of environmental protection legislation.
In some cases, fume scrubbers, filters or engineering
modifications to the process equipment will be
necessary to reduce emissions to acceptable levels.
9. Physical and chemical properties
Physical state: Solid
Flash point: Not available.
Auto-ignition temperature: Not available.
Flammable limits: Not available.
Color: Gray.
Odor: None.
pH: Not available.
Boiling/condensation point: Not available.
Melting/freezing point: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Odor threshold: Not available.
Evaporation rate: Not available.
VOC: 1.8 g/l
Solubility: Insoluble in the following materials: cold water
and hot water.
10. Stability and reactivity
Stability: The product is stable
Conditions to avoid: No specific data.
Incompatibility with various Reactive with oxidizing agents,
substances: reducing agents, acids, alkalis.
Chlorine, peroxides.
Hazardous decomposition products: Under normal conditions of storage
and use, hazardous decomposition
products should not be produced
Other Hazardous decomposition Metal oxides, toxic. Fumes
products:
Hazardous polymerization: Under normal conditions of storage
and use, hazardous polymerization
will not occur.
11. Toxicological information
Acute toxicity
Product/ingredient Result Species Dose Exposure
name
Lead LDLo Rat 1 g/kg -
Intraperitoneal
TDLo Oral Rat 0.2 mg/kg -
Rosin LD50 Oral Rat 3 g/kg -
LD50 Oral Mouse 2.2 g/kg -
LD50 Oral Rat 3 mg/kg -
Carcinogenicity
Classification
Product/ ACGIH IARC EPA NIOSH NTP OSHA
ingredient name
lead A3 2B - - Possible -
Rosin - - - + - -
Mutagenicity
Product/ Test Experiment Result
ingredient name
lead - Mammalian-Animal Equivocal
Teratogenicity
Product/ Result Species Dose Exposure
ingredient name
lead Equivocal- 10mg/m3 10mg/m3 24 hours per day
Inhalation
Equivocal 2118 mg/kg 2118 mg/kg -
-Oral
Reproductive toxicity
Product/ Maternal Fertility Development Species Dose Exposure
ingredient name toxicity toxin
lead - Equivocal - Mouse Oral: -
4099.2
mg/kg
Equivocal - - Mouse- Oral: -
Female 300 mg/kg
- - Equivocal Rat - Inhalation:24 hr
Female 3 per day
- - Equivocal Rat - Oral: 520 -
Female mg/kg
12. Ecological information
Aquatic ecotoxicity
Product/
ingredient name Test Result Species Exposure
Lead - Acute LC50 1.17 Fish - Rainbow 96 hours
mg/L Fresh water trout, Donaldson
trout -
Oncorhynchus
mykiss - 145mm
- Acute LC50 38829 Fish - Inland 96 hours
to 71806 ppb silverside-
Marine water Menidia beryllina
- Acute LC50 26150 Fish - Inland 96 hours
to 44761 ppb silverside-
Marine water Menidia beryllina
- Acute LC50 1.33 Fish - cyprinus 96 hours
ppm Fresh water carpio - Juvenile
(Fledgling,
Hatchling,
Weanling) - 6.5
cm
- Acute LC50 0.8 ppm Fish - cyprinus 96 hours
Fresh water carpio - Juvenile
(Fledgling,
Hatchling,
Weanling) - 6.5
cm
- Acute LC50 0.44 Fish - cyprinus 96 hours
ppm Fresh water carpio - Juvenile
(Fledgling,
Hatchling,
Weanling) - 3.5
cm
- Acute LC50 4500 to Crustaceans - 48 hours
5500 ug/L Fresh Water flea -
water Simocephalus
vetulus -<24
hours
- Acute LC50 4460 Crustaceans - 48 hours
ug/L Marine water Indian prawn -
Panaeus indicus -
6 to 9 cm
- Acute LC50 4400 to Daphnia - Water 48 hours
5300 ug/L Fresh flea - Daphnia
water magna - <24 hours
- Acute LC50 2800 Fish - Smallmouth 96 hours
ug/L Fresh water bass -
Micropterus
dolmieui -
Swim-up
- Acute LC50 2200 Fish - Smallmouth 96 hours
ug/L Fresh water bass -
Micropterus
dolomieui -
Swim-up
- Acute LC50 933 to Crustaceans - 48 hours
1200 ug/L Marine Fleshy prawn -
water Penaeus chinensis
- Acute LC50 530 Daphnia - Water 48 hours
ug/L Fresh water felat-
Ceriodaphnia
reticulate - <4
hours
- Acute LC50 29000 Fish-Smallmouth 96 hours
ug/L Fresh water bass -
Micropterus
dolomieui-Fingerl
ing
- Acute LC50 40000 Fish - Goldfish - 96 hours
ug/L Fresh water Carassius auratus
- Acute LC50 5100 Daphnia - Water 48 hours
ug/L Fresh water flea - Daphnia
pulex - < 24
hours
- Acute LC50 5010 Crustaceans - 48 hours
ug/L Marine water Brine shrimp -
Artemia salina
13. Disposal considerations
Waste The generation of waste should be avoided or minimized whenever
Disposal: possible. Empty containers or liners may retain some product
residues. This material and it's container must be disposed of
in a safe way. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Disposal of this
product, solutions and any by-products should at all times
comply with the requirements of environmental protection and
waste disposal legislation and any regional local authority
requirements. Avoid dispersal of spilled material and runoff
and contact with soil, waterways, drains and sewers.
Disposal should be in accordance with applicable regional, national and local
laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE
CONTROLS/PERSONAL PROTECTION for additional handling information and protection
of employees.
14. Transport information
Regulatory UN number Proper Classes PG* Label Additional
information shipping name information
DOT
Classification Not regulated - - -
PG*: Packing group
15. Regulatory information
United States
HCS Classification: Highly toxic material
Irritating material
Sensitizing material
Carcinogen
Target organ effects
U.S. Federal All ingredients comply with applicable rules or orders
regulations: under United States TSCA.
All components are listed or exempted.
TSCA 5(a)2 proposed significan rules: No products were
found.
TSCA 5(a)2 final significant rules: No products were
found.
TSCA 12(b) one-time export: No products were found.
SARA 313
Product name
Form R - Reporting requirements: lead
Supplier notification: lead
California Prop. 65
WARNING: This product contains a chemical known to the State of California to
cause cancer and birth defects or other reproductive harm.
Canada
WHMIS (Canada): Class D-2A: Material causing other toxic effects (Very
toxic).
Class D-2B: Material causing other toxic effects (Toxic)
Canada Inventory: All components are listed or exempted.
International lists
China inventory All components are listed or exempted.
(IECSC):
Europe inventory: All components are listed or exempted.
Australia inventory All components are listed or exempted.
(AICS):
Japan inventory (ENCS): Not determined.
Not determined.
Korea inventory (KECI): All components are listed or exempted.
Philippines inventory All components are listed or exempted.
(PICCS):
16. Other information
Definition of Terms
ACGIH American Conference of Governmental Industrial Hygienists
Ceiling Maximum exposure limit defined by OSHA
CAS Chemical Abstranct Service
IARC International Agency for Research on Cancer
NIOSH National Institute for Occupational Safety and Health
NTP National Toxicology Program
OSHA Occupational Safety and Health Administration
PEL Permissible Exposure Limit
REL Recommended Exposure Limit
RTK Right to Know
SARA Superfund Amendments and Reauthorization Act
STEL Short Term Exposure Limit
TLV ACGIH Threshold Limit Value
TLV-C ACGIH Threshold Limit Value, Ceiling
TRADE SECRET Claimed as allowed under 29CFRS1910.1200
TSCA Toxic Substances Control Act
PPE Personal Protection Equipment
CEPA Canadian Environmental Protection Act
DSL Domestic Substance List
NDSL Non-Domestic Substance List
NSN New Substance Notification Rules
Disclaimer:
The information contained herein is based on data considered accurate.
However, no warranty is expressed of implied regarding the accuracy of these
data or the results to be obtained from the use thereof. Additionally, Cookson
Electronics assumes no responsibility for injury to the vendee or third persons
proximately caused by the material even if reasonable safety procedures are
followed. Furthermore, vendee assumes the risk in his use of the material.
The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance. For more product information by email, click here Imperial Supplies LLC does not provide services and products outside the United States |
