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MSDS 9118 9118: Super Glue 2 Gram [6]MSDS Last updated: 10/05/2009
Permatex, Inc.
10 Columbus Blvd.
Hartford, CT 06106 USA
Telephone; 1-87-Permatex
(877) 376-2839
Emergency: 800-255-3924
International Emergency: +01-813-248-0585
MATERIAL SAFETY DATA SHEET
1. PRODUCT IDENTIFICATION
Product Name: DR. BOND SUPER GLUE 2G
Item No: 81737
Product Type: Cyanoacrylate ester
2. COMPOSITION/INFORMATION ON INGREDIENTS
Component Weight% ACGIH; TLV-TWA OSHA PEL
ETHYL CYANOACRYLATE >70 0.2ppm Not Listed
7085-85-0
POLY (METHYL METHACRYLATE) <30 Not Listed Not Listed
9011-14-7
1,4- DIHYDROXYBENZENE 0.1-1.0 1mg/m3 2 mg/m3
123-31-9
3. HAZARDS IDENTIFICATION
Toxicity: Skin contact may cause burns. Bonds skin
rapidly and strongly. Causes eye irritation.
Irritate mucous membranes.
Primary Routes of Entry: Eye and skin contact, inhalation
Signs and Symptoms of Exposure: Vapor is irritating to eyes and mucous
membranes above TLV. Prolonged and repeated
overexposure to vapors may produce symptoms
of non-allergic asthma in sensitive
individuals.
Medical Conditions Recognized as None known.
Being Aggravated by Exposure:
Weight ACGIH
Component Percent NTP Carcinogens IARC
POLY (METHYLACRYLATE) <30 Group 3
9011-14-7 Vol.19, pg
187; 1979
1,4-DIHYDROXYBENZENE 0.1-1.0 male rat-some A3 - Animal Group 3;
123-31-9 evidence; Carcinogen Monograph 71,
female 1999;
rat-some Supplement 7,
evidence; 1987;
male mice-no Monograph 15,
evidence; 1977
female
mice-some
evidence
4. FIRST AID MEASURES
Ingestion: Ingestion is not likely. The adhesive solidifies and
adheres in the mouth. If lips are accidentally stuck
together, apply lots of warm water to the lips and
encourage maximum wetting and pressure from saliva inside
the mouth. Peel or roll lips apart. Do not try to pull
the lips with direct opposing action. Saliva will lift
the adhesive in one half to two days.
Inhalation: Move to fresh air in case of accidental inhalation of
vapours. Oxygen or artificial respiration if needed.
Obtain medical attention.
Skin Contact: Remove excess adhesive. Soak in warm, soapy water. The
adhesive will come loose from the skin in several hours.
Cured adhesive does not present a health hazard even when
bonded to the skin. For skin adhesion, first immerse the
bonded surfaces in warm, soapy water. Peel or roll the
surfaces apart with the aid of a blunt edge, e.g.,
spatula or teaspoon handle; then remove adhesive from the
skin with soap and water. Do not try to pull surfaces
apart with a direct opposing action. Cyanoacrylates give
off heat on solidification. In rare cases, a large drop
will increase in temperature enough to cause a burn.
Burns should be treated normally after the lump of
cyanoacrylate is released from the tissue as described
above.
Eye Contact: In the event that eyelids are stuck together or bonded on
to the eyeball, wash thoroughly with warm water and apply
a gauze patch. The eye will open without further action,
typically in 1-4 days. There will be no residual damage.
Do not try to open the eyes by manipulation. If
cyanoacrylate is introduced into the eyes, it will attach
to the eye protein and will disassociate from it over
intermittent periods, generally several hours. This will
cause periods of weeping until clearance is achieved.
During this period, double vision may be experienced
together with a lachrymatory effect, and it is important
to understand the cause and realize that disassociation
will normally occur within a matter of hours, even with
gross contamination.
5. FIRE FIGHTING MEASURES
Flash Point °F(C°): 185 °F TCC
Recommended Extinguishing Media: Carbon Dioxide, Dry Chemicals, Foam.
Special Fire-Fighting Procedures: Firefighters should wear self-contained
breathing apparatus.
Hazardous Products of Combustion: Oxides of carbon
Unusual Fire/Explosion Hazards: May polymerize exothermically.
Lower Explosive Limit: Not determined.
Upper Explosive Limit: Not determined.
6. ACCIDENTAL RELEASE MEASURES
Spill Procedures: Flood with water to polymerize. Maintain good ventilation.
Take up with an inert absorbent. Store in a closed waste container until
disposal.
7. HANDLING AND STORAGE
Storage: Store below 77°F (25°C).
Handling: Avoid contact with skin and eyes. Avoid contact with clothing. Do not
inhale vapors. Keep container closed when not in use. Wash hands before eating
and smoking.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Eyes: Safety glasses.
Skin: Neoprene or nitrile gloves recommended. Do not wear
protective clothing containing cotton.
Ventilation: General; local exhaust ventilation as necessary to
control any air contaminants to within their
exposure limits (or to the lowest feasible levels
when limits have not been established) during the
use of this product.
Respiratory Protection: An approved organic vapor respirator should be worn
when exposures are expected to exceed the
applicable limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Clear liquid
Odor: Irritating
Boiling Point: >300°F
pH: Does not apply
Solubility in Water: Insoluble, material hardens
Specific Gravity: 1.05
VOC Content (Wt. %): <20 g/l (California SCAQMD Method 316B)
Vapor Pressure: 1 mm Hg @ 20°C
Vapor Density (Air=1): Approximately 3
Evaporation Rate: Nil
10. STABILITY AND REACTIVITY
Chemical Stability: Stable at normal conditions
Hazardous Polymerization: Hazardous polymerization may occur if over-
catalyzed or insufficiently aerated after
catalyzation. This polymerization is exothermic
Incompatibilities: Polymerized by contact with water, alcohols,
amines or alkalies.
Conditions to Avoid: Avoid contact with clothes, fabrics, rags or
tissue. Contact with these materials may cause
polymerization.
Hazardous Products of Combustion: Oxides of carbon
11. TOXICOLOGICAL INFORMATION
See Section 3
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended Method of Disposal:
Disposal should be made in accordance with federal, state and local
regulations..
US EPA Waste Number:
NH - Not a RCRA Hazardous Waste Material
14. TRANSPORTATION INFORMATION
DOT (49CFR 172)
Ground Transport (DOT)
DOT Shipping Name: Not Regulated
Hazard Class: None
UN/ID Number: None
IATA
Proper Shipping Name: Not regulated
Class or Division: None
UN/ID Number: None
IMDG
Proper Shipping: Not regulated
Hazard Class: None
UN Number: None
Marine Pollutant: None
15. REGULATORY INFORMATION
SARA 313 Chemicals: The following component(s) is listed as a SARA Section 313
Toxic Chemical.
NONE
California Proposition 65:
No California Prop 65 chemicals are known to be present.
TSCA Inventory Status:
All components of this product are listed (or exempt) on the EPA TSCA
inventory.
16. OTHER INFORMATION
Estimated NFPA Rating: HEALTH 2, FLAMMABILITY 2, REACTIVITY 1.
Estimated HMIS Classification: HEALTH 2, FLAMMABILITY 2, PHYSICAL HAZARD 0
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
Prepared By: Denise Boyd, Manager-Environmental, Health & Safety
Company: Permatex. Inc. 10 Columbus Blvd. Hartford, CT USA 06106
Telephone No.: 1-87-Permatex (877) 376-2839
Revision Date: June 01, 2009
Revision Number 2
The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance. For more product information by email, click here Imperial Supplies LLC does not provide services and products outside the United States |