MSDS Sheet 9118

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10 Columbus Blvd. Hartford, CT 06106 USA Telephone: 1-87-Permatex (877) 376-2839 Emergency: 800-255-3924 International Emergency: 813-248-0585 MATERIAL SAFETY DATA SHEET 1. PRODUCT IDENTIFICATION -------------------------------------------------------------------------------- Product Name: DR. BOND SUPER GLUE 2G Item: 81737 Product Type: Cyanoacrylate ester 2. COMPOSITION/INFORMATION ON INGREDIENTS -------------------------------------------------------------------------------- Ingredient Weight Percent ACGIH TLV OSHA PEL Ethyl Cyanoacrylate 90-100 0.2 ppm TWA Not Listed 7085-85-0 Poly (Methyl Methacrylate) 1-10 Not Listed Not Listed 9011-14-7 1,4 Dihydroxybenzene 0.1-0.5 2 mg/m3 TWA 2 mg/m3 TWA 123-31-9 3. HAZARDS IDENTIFICATION -------------------------------------------------------------------------------- Toxicity: Skin contact may cause burns. Bonds skin rapidly and strongly. causes eye irritation. Irritates mucous membranes. Primary Routes of Entry: Eye and skin contact, ingestion, inhalation. Signs and Symptoms of Exposure: Vapor is irritating to eyes and mucous membranes above TLV. Prolonged and repeated overexposure to vapors may produce symptoms of non-allergic asthma in sensitive individuals. Ingredient Weight NTP ACGIH IARC Percent Carcinogens Poly (Methyl Methacrylate) 1-10 Group 3 vol.19, pg 187: 1979 1,4-Dihydroxybenzene 0.1-0.5 male rat-some A3-Animal Group 3 Vol. 123-31-9 evidence: Carcinogen 71, pg 691: female rat-some 1999 evidence: male mice-no evidence: female mice-some evidence. Medical Conditions Recognized as None known. Being Aggravated by Exposure: 4. FIRST AID MEASURES -------------------------------------------------------------------------------- Ingestion: Ingestion is not likely. The adhesive solidifies and adheres in the mouth. If lips are accidentally stuck together, apply lots of warm water to the lips and encourage maximum wetting and pressure from saliva inside the mouth. Peel or roll lips apart. Do not try to pull the lips with direct opposing action. Saliva will lift the adhesive in one half to two days. Inhalation: Move to fresh air in case of accidental inhalation of vapors. Oxygen or artificial respiration if needed. Obtain medical attention. Skin Contact: Remove excess adhesive. Soak in warm, soapy water. The adhesive will come loose from the skin in several hours. Cured adhesive does not present a health hazard even when bonded to the skin. For skin adhesion, first immerse the bonded surfaces in warm, soapy water. Peel or roll the surfaces apart with the aid of a blunt edge, e.g. spatula or teaspoon handle: then remove adhesive from the skin with soap and water. Do not try to pull surfaces apart with a direct opposing action. Cyanoacrylates give off heat on solidification. In rare cases, a Large drop will increase in temperature enough to cause a burn. Burns should be treated normally after the lump of cyanoacrylate is released from the tissue as described above. Eye Contact: In the event that eyelids are stuck together or bonded to the eyeball, wash thoroughly with warm water and apply a gauze patch. The eye will open without further action, typically in 1-4 days. There will be no residual damage. Do not try to open the eyes by manipulation. If cyanoacrylate is introduced into the eyes, it will attach to the eye protein and will disassociate from it over intermittent periods, generally several hours. This will cause periods of weeping until clearance is achieved. During this period, double vision may be experienced together with a lachrymatory effect, and it is important to understand the cause and realize that disassociation will normally occur within a matter of hours, even with gross contamination. 5. FIRE FIGHTING MEASURES Flash Point (F/C): 185 degrees F. Method: Tag Closed Cup Recommended Extinguishing Media: Carbon Dioxide, Dry Chemicals, Foam Special Fire-Fighting Procedures: Firefighters should wear self-contained breathing apparatus. Hazardous Products of Combustion: Irritating vapors. Unusual Fire/Explosion Hazards: May polymerize exothermically. Lower Explosive Limit: Not determined. Upper Explosive Limit: Not determined. 6. ACCIDENTAL RELEASE MEASURES -------------------------------------------------------------------------------- Spill Procedures: Flood with water to polymerize. Maintain good ventilation. Take up with an inert absorbent. Store in a closed waste container until disposal. 7. HANDLING AND STORAGE -------------------------------------------------------------------------------- Storage: Store below 75 degrees F. Handling: Avoid contact with skin and eyes. Do not inhale vapors. Keep container closed when not in use. Wash hands before eating and smoking. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION -------------------------------------------------------------------------------- Eyes: Safety glasses. Skin: Neoprene or nitrile gloves recommended. Do not wear protective clothes containing cotton. Ventilation: General: local exhaust ventilation as necessary to control any air contaminants to within their exposure limits (or to the lowest feasible levels when limits have not been established) during the use of this product. Respiratory Protection: An approved respirator (i.e.NIOSH,etc.) should be worn when exposures are expected to exceed the applicable limits. 9. PHYSICAL AND CHEMICAL PROPERTIES -------------------------------------------------------------------------------- Appearance: Clear liquid. Odor: Irritating Boiling Point: >300F pH: Does not apply Solubility in Water: Polymerized Specific Gravity: 1.05 - 1.16 VOC Content(Wt.%): < 20 g/l (California SCAQMD Method 316B) Vapor Pressure: < 0.2 mm Hg @ 74 F Vapor Density (Air=1): Approximately 3 Evaporation Rate: Not Determined 10. STABILITY AND REACTIVITY -------------------------------------------------------------------------------- Chemical Stability: Stable at normal conditions. Hazardous Polymerization: MAY OCCUR. Hazardous polymerization may occur if over-catalyzed or insufficiently aerated after catalyzation. This polymerization is exothermic. Incompatibilities: Polymerized by contact with water, alcohols, amines or alkalis. Conditions to Avoid: Avoid contact with clothes, fabrics, rags or tissue. Contact with these material may cause polymerization. Hazardous Products of Combustion: Irritating vapors. 11. TOXICOLOGICAL INFORMATION -------------------------------------------------------------------------------- See Section 3 12. ECOLOGICAL INFORMATION -------------------------------------------------------------------------------- No data available. 13. DISPOSAL CONSIDERATIONS -------------------------------------------------------------------------------- Recommended Method of Disposal: Disposal should be made in accordance with federal, state and local regulations. US EPA Waste Number: NH - Not a RCRA Hazardous Waste Material. 14. TRANSPORTATION INFORMATION -------------------------------------------------------------------------------- DOT (49CFR 172) Domestic Ground Transport DOT Shipping Name: Unrestricted Hazard Class: None UN/ID Number: None Marine Pollutant: None IATA Proper Shipping Name: Not regulated Class or Division: None UN/NA Number: None IMDG Proper Shipping: Unrestricted Hazard Class: None UN Number: None 15. REGULATORY INFORMATION -------------------------------------------------------------------------------- SARA 313 Chemicals: The following component(s) is listed as a SARA Section 313 Toxic Chemical. NONE CALIFORNIA PROP 65: No California Prop 65 chemicals are known to be present. TSCA Inventory Status: Listed on Inventory: YES All components of this product are listed (or exempt) on the EPA TSCA inventory. 16. OTHER INFORMATION -------------------------------------------------------------------------------- Estimated NFPA Rating: Health 2, Flammability 2, Reactivity 1 Estimated HMIS Classification: Health 2, Flammability 2, Physical Hazard 0 NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: Denise Boyd, Health and Safety Manager Revision Date:08/03/2006 Company: Permatex. Inc. 10 Columbus Blvd. Hartford, CT USA 06106 Revision 4 Number: