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MSDS 9115 9115: Gel Super Glue 2 Gram Tube [2]MSDS Last updated: 01/05/2010
Permatex, Inc.
10 Columbus Blvd.
Hartford, CT 06106 USA
Telephone: 1-87-Permatex
(877) 376-2839
Emergency: 800-255-3924
International Emergency: 813-248-0585
Material Safety Data Sheet
1. PRODUCT IDENTIFICATION
Product Name: SUP-2M DR. BOND SUPER GLUE GEL 2 GR
2-PACK
Item No: 85742
Product Type: Cyanoacrylate ester
2. HAZARDS IDENTIFICATION
Component Weight% ACGIH TLV:TWA OSHA PEL:
ETHYL CYANOACRYLATE >70 0.2 ppm TWA Not Listed
7085-85-0
POLY (METHYL <25 Not Listed Not Listed
METHACRYLATE)
9011-14-7
SILICON DIOXIDE, <5 10 mg/m3 TWA 6 mg/m3 TWA
AMORPHOUS
112945-52-5
1,4-DIHYDROXYBENZENE <1 2 mg/m3 TWA 2 mg/m3 TWA
123-31-9
3. HAZARDS IDENTIFICATION
Toxicity: Skin contact may cause burns.
Bonds skin rapidly and strongly.
Causes eye irritation. Irritates
mucous membranes. Note: This
product does not contain
microcrystalline silica.
Primary Routes of Entry: Eye and skin contact, ingestion,
inhalation
Signs and Symptoms of Exposure: Vapor is irritating to eyes and
mucous membranes above TLV.
Prolonged and repeated exposure to
vapors may product symptoms of
non-allergic in sensitive
individuals. Repeated skin contact
may cause allergic skin reactions.
Component Weight% NTP ACGIH IARC
Carcinogens
POLY (METHYL <25 Group 3 Vol.
METHACRYLATE) 19 pg 187;
9011-14-7 1979
SILICON DIOXIDE, <5 Amorphous
AMORPHOUS Silica, Group
112945-52-5 3: Vol. 68:
1997
1,4-DIHYDROXYBEN <1 male rat-some A3- Animal Group3;
ZENE 123-31-9 evidence; Carcinogen Monograph 71,
female 1999;
rat-some Supplemement7,
evidence; 1987;
male mice-no Monograph 15,
evidence; 1977
female
mice-some
evidence
Medical Conditions Recognized as None known.
Being Aggravated by Exposure:
4. FIRST AID MEASURES
Ingestion: Ingestion is not likely. The
adhesive solidifies and adheres in
the mouth. If lips are accidentally
stuck together, apply lots of warm
water to the lips and encourage
maximum wetting and pressure from
saliva inside the mouth. Peel or
roll lips apart. Do not try to pull
the lips with direct opposing
action. Saliva will lift the
adhesive in one half to two days.
Inhalation: Move to fresh air in case of
accidental inhalation of vapours.
Oxygen or artificial respiration if
needed. Obtain medical attention.
Skin Contact: Remove excess adhesive. Soak in
warm, soapy water. The adhesive
will come loose from the skin in
several hours. Cured adhesive does
not present a health hazard even
when bonded to the skin. For skin
adhesion, first immerse the bonded
surfaces in warm, soapy water. Peel
or roll the surfaces apart with the
aid of a blunt edge, e.g., spatula
or teaspoon handle; then remove
adhesive from the skin with soap
and water. Do not try to pull
surfaces apart with a direct
opposing action. Cyanoacrylates
give off heat on solidification. In
rare, cases, a large drop with
increase in temperature enough to
cause a burn. Burns should be
treated normally after the lump of
cyanoacrylate is released from the
tissue as described above.
Eye Contact: In the even that eyelids are stuck
together or bonded to the eyeball,
wash thoroughly with warm water and
apply a gauze patch. The eye will
open without further action,
typically in 1-4 days. There will
be no residual damage. Do not try
to open the eyes by manipulation.
If cyanoacrylate is introduced into
the eyes, it will attach to the eye
protein and will disassociate from
it over intermittent periods,
generally several hours. This will
cause periods of weeping until
clearance is achieved. During this
period, double vision may be
experienced together with a
lachrymatory effect, and it is
important to understand the cause
and realize that disassociation
will normally occur within a matter
of hours, even with gross
contamination.
5. FIRE FIGHTING MEASURES
Flash Point (F/C): 185F TCC
Recommended Extinguishing Media: Carbon Dioxide, Dry Chemicals,
Foam.
Special Fire-Fighting Procedures: Firefighters should wear
self-contained breathing apparatus.
Hazardous Products of Combustion: Oxides of carbon, Irritating vapors
Unusual Fire/Explosion Hazards: May polymerize exothermically
Lower Explosive Limit: Not determined.
Upper Explosive Limit: Not determined.
6. ACCIDENTAL RELEASE MEASURES
Spill Procedures: Flood with water to polymerize.
Maintain good ventilation. Take up
with an inert absorbent. Store in a
closed waste container until
disposal.
7. HANDLING AND STORAGE
Storage: Store away from water or moisture
Store at temperatures not exceeding
25 C
Handling: Avoid contact with skin and eyes.
Avoid contact with clothing. Do not
inhale vapors. Keep container
closed when not in use. Wash hands
before eating and smoking.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Eyes: Safety glasses
Skin: rubber or plastic gloves. Do not
wear protective clothing containing
cotton.
Ventilation: General; local exhaust ventilation
as necessary to control any air
contaminants to within their
exposure limits (or to the lowest
feasible levels when limits have
not been established) during the
use of this product.
Respiratory Protection: An approved respirator (i.e. NIOSH,
etc.) should be worn when exposures
are expected to exceed applicable
limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Gel
Odor: Irritating
Boiling Point: 365F
pH: Does not apply
Solubility in Water: Polymerized
Specific Gravity: 1.05
VOC Content (Wt. %): <20 g/l (California SCAQMD Method
316B)
Vapor Pressure 1 mm Hg @20C
Vapor Density (Air=1): Nil
Evaporation Rate: Nil
10. STABILITY AND REACTIVITY
Chemical Stability: Stable at normal conditions
Hazardous Polymerization: May OCCUR. Hazardous polymerization
may occur if over-catalyzed or
insufficiently aerated after
catalyzation. This polymerization
is exothermic.
Incompatibilities: Polymerized by contact with water,
alcohols, amines or alkalies.
Conditions to Avoid: Avoid contact with clothes,
fabrics, rags or tissue. Contact
with these materials may cause
polymerization.
Hazardous Products of Combustion: Oxides of carbon, Irritating vapors
11. TOXICOLOGICAL INFORMATION
See Section 3
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended Method of Disposal: Disposal should be made in
accordance with federal, state and
local regulations.
US EPA Waste Number: NH-Not a RCRA Hazardous Waste
Material
14. TRANSPORTATION INFORMATION
DOT (49CFR 172)
Domestic Ground Transport
DOT Shipping Name: Unrestricted
Hazard Class: None
UN/ID Number: None
Marine Pollutant: None
IATA
Proper Shipping Name: Not regulated
Class or Division: None
UN/NA Number: None
IMDG
Proper Shipping: Unrestricted
Hazard Class: None
UN Number: None
15. REGULATORY INFORMATION
SARA 313 Chemicals: The following component(s) is listed as a SARA
Section 313 Toxic Chemical.
NONE
CALIFORNIA PROP 65:
No California Prop 65 chemicals are known to be present.
TSCA Inventory Status:
Listed on Inventory: YES All components of this product are listed (or
exempt) on the EPA TSCA inventory.
16. OTHER INFORMAITON
Estimated NFPA HEALTH 2, FLAMMABILITY 2, REACTIVITY 1
Rating:
Estimated HMIS HEALTH 2, FLAMMABILITY 2, PHYSICAL HAZARD 0
Classification:
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
Prepared By: Denise Boyd, Health and Revision Date:
Safety Manager October/01/2007
Company: Permatex. Inc. 10 Revision Number: 1
Columbus Blvd.
Hartford, CT USA 06106
The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance. For more product information by email, click here Imperial Supplies LLC does not provide services and products outside the United States |