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Permatex, Inc. 10 Columbus Blvd. Hartford, CT 06106 USA Telephone: 1-87-Permatex (877) 376-2839 Emergency: 800-255-3924 International Emergency: 813-248-0585 MATERIAL SAFETY DATA SHEET 1. PRODUCT IDENTIFICATION -------------------------------------------------------------------------------- Product Name: 21425 FAST CURE EPOXY PART 1 Item No: 150345E Product Type: Epoxy 2. COMPOSITION/INFORMATION ON INGREDIENTS -------------------------------------------------------------------------------- Ingredient Weight Percent ACGIH TLV OSHA PEL: Aluminum Hydroxide 40-50 10mg/m3 dust 15mg/m3 dust: 21645-51-2 5mg/m3 respir. Bisphenol A/Epichlorohydrin 30-60 Not Listed Not Listed Based Epoxy Resin 25068-38-6 Epoxy Resin 1-10 Not Listed Not Listed 28906-96-9 Carbon Black <1 3.5mg/m3 TWA 3.5mg/m3 TWA 1333-86-4 3. HAZARDS IDENTIFICATION -------------------------------------------------------------------------------- Toxicity: May cause eye and skin irritation. May cause skin sensitization. Contact at elevated temperatures can cause permanent damage to eyes including blindness. Primary Routes of Entry: Eye and skin contact, ingestion, inhalation. Signs and Symptoms Of Exposure: Eyes: Exposure to liquid or vapor causes mild eye irritation. Symptoms may include burning, tearing, redness, stinging, blurred vision and corneal injury. Repeated skin contact may cause allergic skin reactions. Ingestion may cause nausea and vomiting. Ingredient Weight NTP ACGIH Carcinogens IARC Percent Carbon Black <1 Group A4 - Not Group 2B; 1333-86-4 classifiable as a Monograph 65 human carcinogen. 1996 Medical Conditions Recognized as Preexisting eye, skin and respiratory disorders may be aggravated by overexposure to this product. Being Aggravated by Exposure: 4. FIRST AID MEASURES -------------------------------------------------------------------------------- Ingestion: Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek medical attention. Never give anything by mouth to an unconscious person. Inhalation; Move to fresh air in case of accidental inhalation of vapors. If not breathing, give artificial respiration. Obtain medical attention. Skin Contact: Immediately remove contaminated clothing and excess contaminant. Flush with water for at least 15 minutes. Wash thoroughly with soap and water. Consult a physician if irritation develops. Eye contact: Flush eyes with clean water for at least 20 minutes while gently holding eyelids open, lifting upper and lower lids. Get medical attention. 5. FIRE FIGHTING MEASURES -------------------------------------------------------------------------------- Flash Point (F/C): >400 F Method: PMCC Recommended Extinguishing Media; Carbon Dioxide, Dry Chemicals, Foam. Special Fire-Fighting Procedures: Material will not burn unless preheated. Firefighters should wear self-contained breathing apparatus and protective clothing to prevent all skin and eye contact. Hazardous Products of Combustion: When heated to decomposition it emits fumes of Cl-, carbon monoxide, other fumes and vapors varying in composition and toxicity . Unusual Fire/Explosion Hazards: Heating above 300 F in the presence of air may cause slow oxidation decomposition and above 500 F may cause polymerization. Lower Explosive Limit: Not determined Upper Explosive Limit: Not determined 6. ACCIDENTAL RELEASE MEASURES -------------------------------------------------------------------------------- Spill Procedures: Maintain good ventilation. Take up with an inert absorbent. Store in a closed waste container until disposal. Prevent from entering waterways or sewers. 7. HANDLING AND STORAGE -------------------------------------------------------------------------------- Storage: Store away from heat. Handling: Avoid contact with skin and eyes. Use only in a well ventilated area. Avoid contact with vapors from heated material. Wash hands before eating and smoking. Discard contaminated leather gloves and shoes. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION -------------------------------------------------------------------------------- Eyes: Safety glasses Skin: Rubber or plastic gloves Ventilation: General: local exhaust ventilation as necessary to control any air contaminants to with in their exposure limits (or to the lowest feasible levels when limits have not been established) during the use of this product. Respiratory Protection: An approved respirator (i.e. NIOSH, etc.) should be worn when exposures are expected to exceed the applicable limits. 9. PHYSICAL AND CHEMICAL PROPERTIES -------------------------------------------------------------------------------- Appearance: Clear viscous liquid Odor: Slight Boiling Point; >500F pH: Neutral Solubility in water: Negligible Specific Gravity; 1.53 VOC Content(Wt.%): <1% by weight Vapor Pressure: 0.03 mm Hg @ 171 F Vapor Density (Air=1): >1 Evaporation Rate: <1 (butyl acetate = 1) 10. STABILITY AND REACTIVITY -------------------------------------------------------------------------------- Chemical Stability; Stable at normal conditions Hazardous Polymerization: Will not occur Incompatibilities: Strong Lewis or mineral acids, strong oxidizing agents, Strong mineral and organic bases (esp, primary and Secondary aliphatic amines) Conditions to Avoid: Heat. Hazardous Products of Combustion: When heated to decomposition it emits fumes of Cl-. Carbon monoxide, other fumes and vapors varying in composition and toxicity. 11. TOXICOLOGICAL INFORMATION -------------------------------------------------------------------------------- Oral LD50 (rat) = 11.4 g/kg Dermal LD50 (rabbit) = >20 ml/kg Eye irritation: Draize = 2 (rabbit) 12. ECOLOGICAL INFORMATION -------------------------------------------------------------------------------- No data available 13. DISPOSAL CONSIDERATIONS -------------------------------------------------------------------------------- Recommended Method of Disposal: Disposal should be made in accordance with federal, state and local regulations. US EPA Waste Number: NH - Not a RCRA Hazardous Waste Material 14. TRANSPORTATION INFORMATION -------------------------------------------------------------------------------- DOT (49 CFR 172) Domestic Ground Transport DOT Shipping Name: Unrestricted Hazard Class: None UN/ID Number: None Marine Pollutant: None IATA Proper Shipping Name; Not regulated Class or Division: None UN/NA Number: None IMDG Proper Shipping: Unrestricted Hazard Class: None UN Number: None 15. REGULATORY INFORMATION -------------------------------------------------------------------------------- SARA 313 Chemicals: The following component(s) is listed as a SARA Section 313 Toxic Chemical. NONE CALIFORNIA PROP 65: WARNING: This product contains a chemical known to the State of California to cause cancer. TSCA Inventory Status: Listed on Inventory: YES All components of this product are listed (or exempt) on the EPA TSCA inventory. 16. OTHER INFORMATION -------------------------------------------------------------------------------- Estimated NFPA Rating: Health 2, Flammability 1, Reactivity 1 Estimated HMIS Classification: Health 2, Flammability 1, Physical Hazard 0 NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By:Denise Boyd, Health and Safety Manager Revision Date; 06/01/2006 Company: Permatex. Inc. 10 Columbus Blvd. Hartford, CT USA 06106 Revision 2 Number: Permatex. Inc. 10 Columbus Blvd. Hartford, CT 06106 USA Telephone: 1-87-Permatex (877) 376-2839 Emergency: 800-255-3924 International Emergency: 813-248-0585 MATERIAL SAFETY DATA SHEET 1. PRODUCT IDENTIFICATION -------------------------------------------------------------------------------- Product Name: 21425 FAST CURE EPOXY PART 2 Item No: 150445E Product Type: Epoxy 2. COMPOSITION/INFORMATION ON INGREDIENTS -------------------------------------------------------------------------------- Ingredient Weight Percent ACGIH TLV: OSHA PEL: Aluminum Hydroxide 40-50 10mg/m3 dust 15mg/m3 dust: 21645-51-2 5mg/m3 respir. Polymercaptan Curing 20-40 Not Listed Not Listed Agent Mixture 2,4,6- 5-10 Not Listed Not Listed Tris(Dimethylaminomethyl)P Henol 90-72-2 Benzyl Alcohol 1-10 Not Listed Not Listed 100-51-6 Styrene 3-7 20 ppm TWA 100 ppm TWA 100-42-5 3. HAZARDS IDENTIFICATION -------------------------------------------------------------------------------- Toxicity: Corrosive Severe irritation or burns, necrosis, blistering and Permanent injury Product can be absorbed through the skin and may cause nausea, headache and general discomfort May cause lacrimation, conjunctivitis, corneal damage and may cause permanent injury (i.e. blindness) if the hardener is poorly ventilated, strongly heated or atomized, the vapor or mist can cause severe irritation of the respiratory tract, damage contacted tissue and produce scarring. Coughing and chest pain may result, nausea and vomiting in severe cases causes severe damage to mucous membranes if swallowed May cause malaise, headache, discomfort, bleeding and vomiting of blood. Primary Routes of Entry: Eye and skin contact, ingestion, inhalation. Signs and Symptoms of Exposure: Overexposure may cause eye and skin redness, difficulty breathing and vomiting. Contact with product at elevated temperatures can result in thermal burns. Ingredient Weight NTP ACGIH Carcinogens IARC Percent Benzyl Alcohol 1-10 male rat-no evidence: 100-51-6 female rat-no evidence; male mice-no evidence: female mice-no evidence. Styrene 3-7 male rat-negative: A4-Not Classifiable Group 2B: 100-42-5 female rat-negative as a Human Vol. 60, Male mice-equivocal: Carcinogen Page 233 Female mice- negative 1994: Monograph 82, 2002 Medical Conditions Recognized as Preexisting eye, skin and respiratory disorders Being Aggravated by Exposure: may be aggravated by overexposure to this product. 4. FIRST AID MEASURES -------------------------------------------------------------------------------- Ingestion: Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek medical attention. Never give anything by mouth to an unconscious person. Inhalation: Move to fresh air in case of accidental inhalation of vapors. Oxygen or artificial respiration if needed. Obtain medical attention. Skin Contact: Immediately remove contaminated clothing and excess contaminant. Flush with water for at least 15 minutes. Wash thoroughly with soap and water. Consult a physician if irritation develops. Eye Contact: Flush eyes with clean water for at least 20 minutes while gently holding eyelids open, lifting upper and lower lids. Get medical attention. 5. FIRE FIGHTING MEASURES -------------------------------------------------------------------------------- Flash Point (F/C): >200 Method: Estimated Recommended Extinguishing Media; Carbon Dioxide, Dry Chemicals, Foam Special Fire-Fighting Procedures: Firefighters should wear self-contained breathing apparatus and protective clothing to prevent all skin and eye contact. Use water spray to cool exposed containers. Hazardous Products of Combustion: Acrid and toxic fumes with organic amines ammonia, oxides of carbon and nitrogen. Unusual Fire/Explosion Hazards: Sudden reaction and fire may result if product is mixed with an oxidizing agent. Lower Explosive Limit: Not determined Upper Explosive Limit; Not determined 6. ACCIDENTAL RELEASE MEASURES -------------------------------------------------------------------------------- Spill Procedures: Maintain good ventilation. Take up with an inert absorbent. Store in a closed waste container until disposal. Prevent from entering waterways or sewers. 7. HANDLING AND STORAGE -------------------------------------------------------------------------------- Storage: Store away from heat. Do not store in reactive metal containers. Keep away from acids and oxidizers. Avoid prolonged skin contact. Keep away from eyes. Avoid breathing vapors, if exposed to high vapor concentrations, leave area at once. Wash thoroughly with soap and water after handling. Discard contaminated leather gloves and shoes. Do not mix with sodium nitrite or other nitro sating agents as cancer-causing nitrosamines could be formed. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eyes: Safety glasses with side shields or chemical goggles. Skin: Rubber or plastic gloves. Ventilation: General: local exhaust ventilation as necessary to control any air contaminants to within their exposure limits (or to the lowest feasible levels when limits have not been established) during the use of this product. Respiratory Protection: An approved respirator (i.e. NIOSH, etc.) Should be worn when exposures are expected to exceed the applicable limits. 9. PHYSICAL AND CHEMICAL PROPERTIES -------------------------------------------------------------------------------- Appearance: Black paste Odor: Mercaptan Boiling Point: >300 F pH: Does not apply Solubility in Water: Slight Specific Gravity: 1.4 VOC Content (Wt.%): Not determined Vapor Pressure: <5 mm Hg @ 77 F Vapor Density (Air=1): >1 Evaporation Rate; <1 (butyl acetate = 1) 10. STABILITY AND REACTIVITY -------------------------------------------------------------------------------- Chemical Stability: Stable at normal conditions Hazardous Polymerization: Will not occur Incompatibilities: Strong oxidizers. Materials reactive with hydroxyl compounds. Sodium/calcium hypochlorite, Peroxides, Reactive metals (e.g. Na. Ca. zinc) . Acids. Conditions to Avoid: Heat. Corrodes base metals. Hazardous Products of Combustion: Acrid and toxic fumes with organic amines, ammonia, oxides of carbon and nitrogen. 11. TOXICOLOGICAL INFORMATION -------------------------------------------------------------------------------- See Section 3 12. ECOLOGICAL INFORMATION -------------------------------------------------------------------------------- No data available. 13. DISPOSAL CONSIDERATIONS -------------------------------------------------------------------------------- Recommended Method of Disposal: Disposal should be made in accordance with federal, state and local regulations. US EPA Waste Number: NH - Not a RCRA Hazardous Waste Material 14. TRANSPORTATION INFORMATION DOT (49CFR 172) Domestic Ground Transport DOT Shipping Name: CONSUMER COMMODITY Hazard Class: ORM-D UN/ID Number: None Marine Pollutant: None IATA Proper Shipping Name: Amines, liquid, corrosive, n.o.s. (Tris-2,4,6- (dimethylaminomethyl)phenol), Limited Quantity. Class or Division: Class 8, Packing Group III UN/NA Number: UN 2735 IMDG Proper shipping: Amines, liquid, corrosive, n.o.s. (Tris-2,4,6-(Dimethylaminomethyl Phenol), Limited Quantity. Hazard Class: Class 8 PGIII UN Number: UN 2735 15. REGULATORY INFORMATION -------------------------------------------------------------------------------- SARA 313 Chemicals: The following component(s) is listed as a SARA Section 313 Toxic Chemical. STYRENE CALIFORNIA PROP 65: WARNING: This product contains a chemical known to the State of California to cause cancer. TSCA Inventory Status: Listed on Inventory: YES All components of this product are listed (or exempt) on the EPA TSCA inventory. 16. OTHER INFORMATION -------------------------------------------------------------------------------- Estimated NFPA Rating: Health 3, Flammability 1, Reactivity 1 Estimated HMIS Classification: Health 3, Flammability 1, Physical Hazard 0 NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: Denise Boyd, Health and Safety Manager Revision Date; 06/01/2006 Company: Permatex. Inc. 10 Columbus Blvd. Hartford, CT USA 06106 Revision 2 Number: