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MSDS 7633 7633: Bondaflex White Caulk- 10.3 Oz [24]7634: Bondaflex Gray Caulk-10.3 Oz [24] MSDS Last updated: 02/11/2005
MATERIAL SAFETY DATA SHEET
BONDAFLEX
TECHNOLOGIES
BONDAFLEX PUR 40 FC POLYURETHANE SEALANT
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: BONDAFLEX Polyurethane Sealant
PRODUCT CODE: PUR 40 FC
ADDRESS: BONDAFLEX Technologies™
1700 Route 3 West
Clifton, New Jersey 07013
PHONE: (973) 473-3330
FAX: (973) 473-4222
EMERGENCY PHONE: (CHEMTREC) (800) 424-9300
International (CHEMTREC) (703) 527-3887
PREPARED BY: A.M. Gilman
REVISION DATE: 4/29/04 (Revision #3) SUPERSEDES: 9/5/03 (Revision #2)
SECTION 2 - COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
This product consists of a mixture/preparation.
CAS NO. INGREDIENT WT% LETHAL DOSES EXPOSURE LIMITS
TWA STEL Ceiling
ppm mg/m3 ppm mg/m3 ppm mg/m3
--------------------------------------------------------------------------------
85-68-7 Butyl Benzyl 15-40 Inhalation TCLo- OSHA
Phthalate (BBP) 789 mg/m3/6hr (rat) No exposure limit guidelines
Oral LD50- 2,330 NIOSH have been established for
mg/kg (rat) this material.
Dermal LD50-ACGIH
6,700 mg/kg (rat)
CANADA
1317-65-3 Calcium 7-13 Oral LD50 - OSHA - 15,5b - -
Carbonate 7,340 mg/kg (rat)
a (Limestone) NIOSH - 10,5b - -
ACGIH - 10 - -
CANADA - 10,5b - -
1305-78-8 Calcium Oxide a
1-5 Not established
OSHA - 5 - -
NIOSH - 2c - -
ACGIH - 2 - -
CANADA - 2 - 4
13463-67-7 Titanium dioxide a
1-5 Inhalation TCLo-
OSHA - 15d - -
250 mg/m3/6hr (rat)
Oral LD50 -
NIOSH e - - -
>24,000 mg/kg (rat)
Dermal LD50
ACGIH - 10 - -
>10,000 mg/m3
CANADA 10,5b
(rabbit)
1330-20-7 Xylene 1-5 Inhalation LC50
OSHA 100 435 - -
5,000 ppm/4hr (rat)
Oral LD50 -
NIOSH 100 435 150 655
4,300 mg/kg (rat)
Dermal LD50 -
ACGIH + 100 434 150 651
1,700 mg/kg
CANADA 100 434 150 652
(rabbit)
101-68-8 Diphenylmethane
0.5-1.5 Inhalation LC50 -
OSHA - - 0.02 0.2
diisocyanate (MDI)
0.5-1.5 178 mg.m3 (rat)
NIOSH 0.005 0.050 0.020g 0.2g
Oral LD50 -
ACGIH 0.005 0.051 - -
2,200 mg/kg (mouse)
CANADA 0.005 0.051 0.02 0.2
100-41-4 Ethyl benzene
0.1-1.0 Oral LD50 -
OSHA 100 435 - -
3,500 mg/kg (rat)
Dermal LD50 -
NIOSH 100 435 125 545
17,800
uL/kg (rabbit)
Inhalation LCLo-
ACGIH f 100 434 125 543
4,000 ppm/4hr (rat)
CANADA 100 434 125 542
14808-60-7 Silica, crystalline a
(Silica, quartz)
<0.1 Implant TDLo-
OSHA - 30,10b,h - -
900 mg/kg (rat)
NIOSH - 0.5 - -
Inhalation TCLo-
ACGIH - 0.5i - -
300 ug/m3 (human)
Intravenous LDLo-
40 mg/kg (mouse)
CANADA - 0.3, 0.1b - -
a Under normal conditions of use, no respirable particles should be released
from this product.
b Total mass: respirable mass, respectively.
c NIOSH permissible exposure limits for calcium oxide are as follows: TWA 2
mg/m3: IDLH 25 mg/m3
d OSHA - Total dust.
e NIOSH - No threshold has been determined: limit occupational exposure to
lowest feasible concentration.
f ACGIH - Biological Exposure Index (BEI)
g NIOSH - Value based on an exposure time of 10 minutes.
h OSHA PEL: Silica, Crystalline (Silica, Quartz) - respirable dust: TWA 10
mg/m3 divided by (%SIO2+2): total dust: TWA 30 mg/m3 divided by (%SIO)2+2)
(Source: NIOSH Pocket Guide to Hazardous Chemicals).
i Respirable mass.
SECTION 3 - HAZARDS IDENTIFICATION
Please note that as a service to our customers, hazard warnings and information
have been included for ALL chemicals listed in this MSDS. However, not all of
these chemicals are defined as "hazardous" by ISO or OSHA standards. Only those
chemicals listed in Section 2 of this MSDS are defined by ISO and/or OSHA as
"hazardous" based upon the properties and concentrations of each chemical.
MOST IMPORTANT HAZARDS
MAIN SYMPTOMS:
EYE: Direct contact irritates moderately with redness and swelling. Calcium
carbonate, xylene, calcium oxide, and MDI may cause severe eye irritation,
especially in dust form. Butyl benzyl phthalate (BBP) may cause irritation with
symptoms of redness and itching.
SKIN: A single short exposure (less than 24 hours) may irritate. Repeated
prolonged contact (24 to 48 hours) may irritate moderately. Product contains
calcium carbonate, xylene, and calcium oxide, which are possible skin
sensitizers. Contact with BBP may cause irritation with symptoms of redness and
itching. MDI may cause irritation to the skin or mucous membranes. Ethyl benzene
may be absorbed through the skin.
IRRITATION: Vapor overexposure, and/or inhalation of silica or calcium oxide
dust may severely irritate eyes, nose, throat, upper respiratory tract, and
lungs. Vapor over exposure may cause drowsiness. Excessive inhalation of calcium
carbonate (dust form) may result in shortness of breath or reduced pulmonary
function. Inhalation of high concentrations of BBP, xylene, or ethyl benzene may
cause respiratory irritation or difficulties and central nervous system effects
characterized by headache, nausea, dizziness, and/or drowsiness. MDI vapors or
mist can cause irritation of upper respiratory tract: signs/symptoms can include
soreness of the nose and throat, coughing, and sneezing. Persons previously
sensitized to isocyanates may experience an allergic respiratory reaction:
signs/symptoms can include difficulty breathing, wheezing, tightness of chest,
and respiratory failure. Overexposure to titanium dioxide (dust form)may cause
pulmonary fibrosis (scarring of the lungs).
ORAL: Small amounts transferred to the mouth by fingers during use, etc. should
not injure. Swallowing large amounts may cause digestive discomfort and
gastrointestinal irritation. Ingestion of BBP may cause central nervous system
depression with symptoms seen in acute inhalation. Ingestion of xylene may cause
central nervous system effects. Aspiration of xylene or ethyl benzene into lungs
may cause chemical pneumonitis.
NFPA HAZARD CODES: Health: 2 Flammability: 2 Reactivity: 0
SECTION 4 - FIRST-AID PROCEDURES
INHALATION: Remove to fresh air. If ill effects persist get medical attention.
SKIN CONTACT: Remove form skin and wash thoroughly with soap and water or
waterless cleanser. Get medical attention if irritation or other
ill effects develop or persist.
EYE CONTACT: Immediately flush with water for 15 minutes. Get medical
attention.
INGESTION: Get medical attention.
COMMENTS: Treat according to person's condition and specifics of exposure.
SECTION 5 - FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA: Carbon Dioxide (CO2), water fog (or spray),
Dry chemical, foam.
UNSUITABLE EXTINGUISHING MEDIA: Water.
SPECIFIC FIRE HAZARDS: Precipitated calcium carbonate will ignite on contact
with fluorine.
FIRE FIGHTING PROCEDURES: Wear full protective clothing including helmet,
self contained, positive pressure or pressure demand
breathing apparatus, bunker coat and pants, bands
around arms, waist, and legs, face mask, and
protective covering for exposed areas of the head.
Water may not effectively extinguish fire: however, it
should be used to keep fire-exposed containers and
surfaces cool and prevent explosive rupture. If large
amount is involved, evacuate area.
FLASH POINT (SETAFLASH): Greater than 65?C (150?F)
FLAMMABILITY LIMITS IN AIR (XYLENE): LEL: 1%
UEL: 8%
HAZARDOUS DECOMPOSITION
PRODUCTS: By high heat and fire: oxides of carbon, oxides of nitrogen,
and isocyanates.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS: Observe all personal protective equipment recommendations
described in Sections 5 and 8.
ENVIRONMENTAL PRECAUTIONS: Disposal of collected product, residues, and
cleanup materials may be governmentally regulated.
Observe all applicable local, state and federal waste
management regulations.
METHODS FOR CLEANING UP: Ventilate area. Extinguish all ignition sources.
Contain spill. Evacuate unprotected personnel from hazard area. Cover with
absorbent, place in approved drum: do not seal drum for 48 hours to avoid
possible build-up. Local, state, and federal reporting requirements may apply to
spills or releases of this material into the environment. See applicable
regulatory compliance information in Section 15.
SECTION 7 - HANDLING AND STORAGE
HANDLING: Assure good ventilation
STORAGE: Eliminate sources of ignition. Store in original sealed containers
away from heat and moisture. Shelf-life 12 months at 73?F and 50%
relative humidity.
SECTION 8 - EXPOSURE CONTROL AND PERSONAL PROTECTION
ENGINEERING CONTROLS:
LOCAL EXHAUST: Recommended
GENERAL VENTILATION: Recommended
PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION: Avoid eye contact. Use proper protection - safety glasses as a
minimum.
SKIN AND BODY PROTECTION: Avoid skin contact. Protect hands with impervious
rubber gloves and wear typical full cover clothing. Gloves must be checked
before each use for signs of degradation and penetration and for proper
functioning. Wear appropriate gloves when handling this product.
RESPIRATORY PROTECTION: Avoid breathing of vapors. Wear appropriate, properly
fitted NIOSH/MSHA approved respirator when the airborne contaminant levels
exceed the exposure limits indicated on the MSDS. Follow respirator
manufacturer's directions for respirator use. Industrial hygiene personnel
can assist in judging the adequacy of existing engineering controls.
HYGIENE MEASURES (INGESTION): Wash hands after handling and before eating.
PRECAUTIONARY MEASURES: Avoid eye contact. Avoid skin contact. Avoid breathing
vapors. Keep container closed. Do not take internally.
Note: These precautions are not room temperature handling. Use at elevated
temperatures or aerosol spray applications may require added precautions.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL FORM: Solid (Paste)
COLOR: Various
ODOR: Slight odor of xylene
pH: Not Applicable
BOILING POINT (AT 760 MM HG): Not Applicable
FLASHPOINT: Greater than 65?C (150?F)
EXPLOSION PROPERTIES: Not Determined
VAPOR PRESSURE ( AT 100?F): Not Applicable
VAPOR DENSITY: 3.66 (Xylene)
DENSITY: 10.9 lb/gal
SOLUBILITY IN WATER (%): NIL
SPECIFIC GRAVITY (AT 77?F/25?C): 1.30
VISCOSITY (AT 77?F/25?C): Greater than 800,000 cps (@ 2 rpm)
FREEZING / MELTING POINT: Not Applicable
ODOR THRESHOLD: Not Determined
EVAPORATION RATE: Not Applicable
% VOLATILE BY VOLUME: Less than 5%
VOLATILE ORGANIC CONTENT (VOC): 3.30% by weight: 43 g/L (0.36 lgs/gal)
NOTE: The above information is not intended for use in preparing
product specifications.
SECTION 10 - STABILITY AND REACTIVITY
CHEMICAL STABILITY: Stable
HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur.
CONDITIONS TO AVOID: Exposure to air or moisture until ready to use. Store
away from water or moisture as this will lead to premature curing
of the material.
MATERIALS TO AVOID: Amines, alcohol, and water will react with this
material. Water reacts with this material to form carbon dioxide, which
could result in the buildup of pressure in a sealed container.
But it is highly unlikely that enough water will mix-in to form
enough carbon dioxide to present a hazardous situation. Avoid oxidizers.
INCOMPATIBILITY: Note that precipitated calcium carbonate will ignite on contact
with fluorine. It is incompatible with acids, alum, ammonia salts,
and mercury + hydrogen mixtures.
HAZARDOUS DECOMPOSITION
PRODUCTS: Oxides of carbon and oxides of nitrogen, isocyanates. Also
possible are oxides of sulfur, phenol, and hydrogen cyanide.
SECTION 11 - TOXICOLOGICAL INFORMATION
May cause respiratory sensitization, eye and skin irritation. May cause allergic
respiratory and/or allergic skin reaction. See Section 2 for exposure limits,
Section 3 for exposure effects.
ACUTE TOXICITY:
FOR BUTYL BENZYL PHTHALATE: Inhalation TCLo- 789 mg/m3/6hr (rat)
Oral LD50 - 2,330 mg/kg (rat)
Dermal LD50 - 6,700 mg/kg (rat)
FOR CALCIUM CARBONATE: Oral LD50 - 7,340 mg/kg (rat)
FOR CALCIUM OXIDE: Not established.
FOR TITANIUM DIOXIDE: Inhalation TCLo - 250 mg/m3/6hr (rat)
Oral LD50 - >24,000 mg/kg (rat)
Dermal LD50 - >10,000 mg/m3 (rabbit)
FOR XYLENE: Inhalation LC50 - 5,000 ppm/4hr (rat)
Oral LD50 - 4,300 mg/kg (rat)
Dermal LD50 - >1,700 mg/kg (rabbit)
FOR MDI: Inhalation LC50 - 178 mg/m3 (rat)
Oral LD50 - 2,200 mg/kg (mouse)
FOR ETHYL BENZENE: Oral LD50 - 3,500 mg/kg (rat)
Dermal LD50 - 17,800 uL/kg (rabbit)
Inhalation LCLo - 4,000 ppm/4hr (rat)
FOR SILICA, QUARTZ: Implant TDLo - 900 mg/kg (rat)
Inhalation TCLo - 300 ug/m3 (human)
Intravenous LDLo - 40 mg/kg (mouse)
CHRONIC TOXICITY:
SKIN: Repeat contact with skin may cause severe irritation, sensitization,
or allergic reaction. Prolonged skin contact with xylene or ethyl
benzene may cause skin irritation or dermatitis. Chronic exposure
to calcium oxide may cause severe corrosive damage.
INHALATION; Vapor overexposure may cause drowsiness, irritate eyes, nose, and
throat, or injure blood, liver, or central nervous system. Prolonged inhalation
of dust (including calcium carbonate, titanium dioxide, and silica in dust form)
may cause respiratory effects including shortness of breath, reduced pulmonary
function, and pulmonary fibrosis (scarring of the lungs). Chronic exposure to
BBP by inhalation may cause sleepiness, withdrawal and weight loss or decreased
weight gain. Chronic exposure to xylene may cause damage to the eyes, central
nervous system, bone marrow, liver, or kidneys. Chronic inhalation of
calcium oxide may cause inflammation and ulcers in the respiratory system.
Chronic overexposure to isocyanates (found in MDI) may cause lung damage and
isocyanate sensitization (chemical asthma), which may be temporary or permanent.
Chronic inhalation of ethyl benzene may have central nervous effects.
ORAL: Small amounts transferred to the mouth by fingers during use, etc.
should not injure. Swallowing larger quantities may have adverse effects
depending on quantity ingested. Repeated ingestion of BBP may cause
sleepiness, withdrawal, and weight loss or decreased weight gain.
Ingestion of xylene may cause central nervous system effects.
SPECIFIC EFFECTS: This material contains the following components with the
special hazards listed below.
Carcinogens: See below.
Teratogens: Xylene and ethyl benzene may cause teratogenic
effects.
Titanium dioxide has caused teratogenic effects
in laboratory animals.
Mutagens: Positive and negative results have been observed
"in vitro" for MDI and ethyl benzene. For ethyl
benzene, mutation in mammalian somatic cells
(rodent, mouse) Lymophocyte = 80 mg/L.
Reproductive toxins: BBP, xylene, and ethyl benzene may cause
reproductive effects.
CARCINOGENICITY:
BUTYL BENZYL
PHTHALATE: The IARC has evaluated this chemical and listed it as Group 3, not
classifiable as to its carcinogenicity to humans.
TITANIUM DIOXIDE: The IARC has evaluated this chemical and listed it as Group
3, not classifiable as to its carcinogenicity to humans.
XYLENE: The IARC has evaluated this chemical and listed it as Group 3, not
classifiable as to its carcinogenicity to humans.
MDI: The IARC has evaluated this chemical and listed it as Group 3, not
classifiable as to its carcinogenicity to humans.
ETHYL BENZENE: The IARC has evaluated this chemical and listed it as Group
2B, possibly carcinogenic to humans.
SILICA, QUARTZ; The IARC has evaluated this chemical and listed it as Group 1,
carcinogenic.
SECTION 12 - ECOLOGICAL INFORMATION
FOR BUTYL BENZYL PTHALATE:
Environmental Fate: Biodegradability is 50 - 100% after 28 days.
Environmental Toxicity: LC50 (Pimephales promelas): 1.5-2.25 mg/L (96hr): LC50
(Rainbow trout): 1.1 mg/L (96hr): EC50 (Daphnia magna): 1.7 mg/L (48hr): EC50
(Green algae): 1.5 mg/L (72hr)
FOR CALCIUM CARBONATE:
Environmental fate: This chemical is not expected to have a significant
impact when released into the environment.
Environmental Toxicity: TLm (Mosquito Fish): 240 ppm/24hr: 220 ppm/48hr: 160
ppm/96hr at 70-73.5 degrees F (21-23 degrees C)
FOR CALCIUM OXIDE:
Environmental Fate: Not available.
Environmental Toxicity: This chemical is expected to be toxic to aquatic life.
TLm (Mosquito Fish): 240 ppm/24hr - toxic
TLm (Sunfish): 100 ppm/3hr - toxic
TLm (Vector snail): 300 ppm/24hr - lethal
FOR TITANIUM DIOXIDE:
Environmental Fate: Not available.
Environmental Toxicity: Not available.
FOR XYLENE:
Environmental Fate: When released into the soil, this material may
evaporate to a moderate extent. When released into the soil, this material is
expected to leach into ground water. When released into the soil, this material
may biodegrade to a moderate extent. When released into water, this material may
evaporate to a moderate extent. When released into water, this material
may biodegrade to a moderate extent. When released into the air, this
material may be moderately degraded by reaction with photo chemically
produced hydroxyl radicals. When released into the air, this material is
expected to have a half-life of less than 1 day. This material is not expected
to significantly bio accumulate. {Mixed xylenes: octanol /water partition
coefficient 3.1 - 3.2: bio concentration factor = 1.3 (eels).}
Environmental Toxicity: This material is expected to be slightly toxic to
acquatic life.
LC50 - Range 10-100 mg/L/96hr (fish)
FOR MDI:
Environmental Fate: Aquatic: Rapidly hydrolyzes to form an insoluble crust.
Terrestrial: Will bind with moist soil. No leaching will occur.
Atmospheric: Remains in the vapor phase and is degraded by
photo chemically produced hydroxyl radicals (half-life
in 32 hours).
Will not bio concentrate or biodegrade.
Environmental Toxicity: This material may be toxic to some types of
aquatic life.
LC50 - >500 mg/L/24hr static (Daphnia magna,
Limnea Stagnalis, and Zebra fish).
FOR ETHYL BENZENE:
Environmental Fate: No information available.
Environmental Toxicity: This chemical is expected to be toxic to aquatic life.
Fish: Rainbow Trout: LC50 - 14.0 mg/L/96hr
Static Bioassay Fish: Fathead Minnow: LC50 - 12.1 mg/L/96hr
Flow-through Bioassay Fish: Bluegill/Sunfish: LC50 - 150.0 mg/L/96hr
Static Bioassay, pH 6.5-7.9, 21-23 degrees C, Water flea:
EC50 - 2.1 mg/L/48hr
Static Bioassay Water Flea: EC50 - 75.0 mg/L/48hr
Static Bioassay Shrimp (mysidoposis bahia): LC50 - 87.6 mg/L/96hr
Sheepshead Minnow: LC50 - 275mg/L/96hr
Fathead Minnow: LC50 - 42.3 mg/L/96hr in hard water,
48.5mg/L/96hr in soft water.
FOR SILICA, QUARTZ;
Environmental Fate: Not available.
Environmental Toxicity: Not available.
SECTION 13 - DISPOSAL INFORMATION
PRODUCT DISPOSAL: RCRA Hazard Class (40 CFR 261)
When a decision is made to discard this material, as received,is it classified
as a hazardous waste?
No Federal Hazardous Waste Code: Not Applicable
Characteristic Waste; Ignitable: Not Applicable
Corrosive: Not Applicable
Reactive: Not Applicable
TCLP: Not Applicable
WASTE FROM RESIDUES
CONTAMINATED PACKAGING: Residues of hazardous waste in empty containers should
be managed according to 40 CFR 261.7
State or local laws may impose additional regulatory requirements regarding
disposal.
SECTION 14 - TRANSPORT INFORMATION
DOT Information (49CFR 172.101)
PROPER SHIPPING NAME: Not Applicable
HAZARD CLASS: Not Applicable
UN/NA NUMBER: None
PACKING GROUP; Not Applicable
QUANTITY LIMITATIONS: Not Applicable
VESSEL STORAGE REQUIREMENTS: Not Applicable
SECTION 15 - REGULATORY INFORMATION
US FEDERAL REGULATIONS:
Occupational Health and Safety Administration (OSHA)
Ingredients listed on National Toxicology Program (NTP) Annual Report on
Carcinogens
The following ingredients are known to be human carcinogens.
* Silica, quartz (Silica, crystalline) 14808-60-7
* Vinyl chloride 75-01-4
The following ingredients are reasonable anticipated to be human carcinogens.
* Furan 110-00-9
* Propylene oxide 75-56-9
* Acetaldehyde 75-07-0
Ingredients listed on International Agency for Research on Cancer (IARC)
Monographs The following ingredient is listed as Group 1.
Group 1 is defined as: The agent (mixture) is carcinogenic to humans.
* Silica, quartz 14808-60-7
* Vinyl chloride 75-01-4
The following ingredients are listed as Group 2B.
Group 2B is defined as: The agent is possibly carcinogenic to humans.
* Ethyl benzene 100-41-4
* Furan 110-00-9
* Propylene oxide 75-56-9
* Acetaldehyde 75-07-0
The following ingredients are listed as Group 3.
Group 3 is defined as: The agent (mixture or exposure circumstances) is not
classifiable as to its carcinogenicity to humans.
* Butyl benzyl phthalate 85-68-7
* Polyvinyl chloride (PVC) 9002-86-2
* Titanium dioxide 13463-67-7
* Xylene 1330-20-7
* Diphenylmethane diisocyanate (MDI) 101-68-8
Toxic Substance Control Act (TSCA)
TSCA Status: All chemical substances found in this product comply with the Toxic
Substances Control Act inventory reporting requirements.
Superfund Amendments and Reauthorization Act (SARA) Title III - Section 302-304
These sections require emergency planning based on Threshold Planning
Quantities (TPQs) and release reporting based on Reportable Quantities
(RQs) of "Extremely Hazardous Substances" (EHS) listed in Appendix A
of 40 CFR 355.
Chemical CAS No. Wt% RQ (lbs) TPQ (lbs)
Furan 110-00-9 <0.0006 100 500
Propylene oxide 75-56-9 <0.0002 100 10,000
- Section 311/312
These sections require Tier I/Tier II - Emergency and hazardous chemical
Inventory form.
Minimum thresholds have been established for Tier One/Tier Two reporting
Under Title III, Section 312. These thresholds are as follows:
For Extremely Hazardous Substances (EHSs) designated under Section 302
of Title III, the reporting threshold is 500 pounds (or 227 kg.) or the
threshold planning quantity (TPQ), whichever is lower.
For all other hazardous chemicals for which facilities are required to have or
prepare an MSDS, the minimum reporting threshold is 10,000 pounds
(or 4,540 kg).
Section 312 Hazard Class:
Acute: Yes
Chronic: No
Fire: No
Pressure: No
Reactive: No
- Section 313
This product contains the following toxic chemicals subject to the reporting
Requirements of Section 313 of the Emergency Planning and Community Right
To Know Act:
Chemical CAS No. Wt% Threshold Report %
Xylene 1330-20-7 1-5 1.0
Comprehensive Environmental Response, Compensation and Liability Act (CERCLA)
Releases of CERCLA hazardous substances, in quantities equal to or greater than
their reportable quantity (RQ), are subject to reporting to the National
Response Center under CERCLA. Such releases are also subject to state and local
regulations under Section 304 of SARA Title III (EPCRA). This material contains
the following components and RQs on the CERCLA hazardous substance list.
Chemical CAS No. Wt% Reportable Quantity (RQ) in pounds
Butyl benzyl phthalate 85-68-7 15-40 100
Xylene 1330-20-7 1-5 100
MDI 101-68-8 0.5-1.5 5,000
Ethyl benzene 100-41-4 0.1-1.0 1,000
Chlorobenzene 108-90-7 <0.009 100
Vinyl chloride 75-01-4 <0.002 1
Furan 110-00-9 <0.0006 100
Propylene oxide 75-56-9 <0.0002 100
Acetaldehyde 75-07-0 <0.00005 1,000
US STATE REGULATIONS:
California
California Safe Drinking Water and Toxic Enforcement Act - Proposition 65
This product contains the following chemical currently listed under California
Proposition 65.
Chemical CAS No. Source List Designations
Vinyl chloride 75-01-4 Cancer
Furan 110-00-9 Cancer
Propylene oxide 75-56-9 Cancer
Acetaldehyde 75-07-0 Cancer
Volatile Organic Content (VOC)
Wt% g/L lbs/gal
3.30 43 0.36
This product does comply with the California Air Resources Board maximum for
VOCs in a sealant.
Per the California Air Resources Board TITLE 17 Division 3 Chapter 1 Subchapter
8.5 Article 2 2 § 94508, a VOC is a substance with a vapor pressure greater than
or equal to 0.1 mmHg at 20?C (68?F), or is a chemical compound with less than or
equal to 12 carbon atoms if the vapor pressure is not known, or is a chemical
compound with a boiling point less than or equal to 216?C (421?F).
State Right-to Know Regulations
States within the US that have promulgated State Right-to-Know regulations with
chemical listing requirements including the chemicals in this product are
provided below.
Chemical CAS No. Wt% States
Butyl benzyl phthalate 85-68-7 15-40 DE, MA, MI, NJ, NY, PA
Polyvinyl chloride 9002-86-2 10-30 NJ
Calcium carbonate 1317-65-3 7-13 MA, MN, PA, WA,
precipitated calcium carbonate
471-34-1 5-10 MN
Calcium oxide 1305-78-8 1-5 FL, MA, MN, PA, WA
Titanium dioxide 13463-67-7 1-5 MA, MN, NJ, PA, WA
Xylene 1330-20-7 1-5 DE, FL, MA, MI, MN, NJ,
NY, PA, WA
MDI 101-68-8 0.5-1.5 DE, FL, MA, MN, NJ, NY,
PA, WA
Ethyl benzene 100-41-4 0.1-1.0 DE, FL, MA, MN, NJ, NY,
PA, WA
Silica, quartz 14808-60-7 <0.1 FL, MA, MN, NJ, PA, WA
Toluenesulfonyl chloride
98-59-9 <0.01 MN
Chlorobenzene 108-90-7 <0.009 DE, FL, MA, MI, MN, NJ,
NY, PA, WA
Stannous 2-ethylhexanoate
301-10-0 <0.002 MA
Vinyl chloride 75-01-4 <0.002 DE, FL, MA, MI, MN, NJ,
NY, PA, WA
Furan 110-00-9 <0.0006 DE, FL, MA, NJ, NY, PA
Propylene oxide 75-56-9 <0.0002 DE, FL, MA, MN, NJ, NY,
PA, WA
Acetaldehyde 75-07-0 <0.00005 DE, FL, MA, MN, NJ, NY,
PA, WA
INTERNATIONAL:
Canada
This product has been classified according to the hazard criteria of the CPR and
the MSDS contains all the information required by the CPR.
Canadian DSL
All ingredients in this product are currently listed on the Canadian Domestic
Substances List (DSL) except the non-hazardous polyurethane prepolymer and
dimorpholine ethane, which are both on the NDSL. (Based upon the concentration
of the prepolymer in the formulation, it would require over 130,000 10.1 fl. oz.
cartridges of PUR 40 to reach the 10,000 kg yearly limit for an NDSL polymer
approved under Schedule VI before reporting is required. This is equal to
approximately 50 200-Gal batches of PUR 40. There is also a cumulative limit of
50,000 kg that can take many years to reach, assuming no one year exceeds the
10,000 kg limit. The dimorpholine ethane is in such small quantities that it
would require millions of cartridges to reach the yearly limit.) The substances
that are on the DSL would not be considered new for the purposes of the Canadian
Environmental Protection Act (CEPA).
Note:
The recipient of this product should be aware of the possible existence of
additional local regulations, which may be applicable to this product.
SECTION 16 - OTHER INFORMATION
These data are offered in good faith as typical values and not as a product
specification. No warranty, either expressed or implied, is hereby made. The
recommended industrial hygiene and safe handling procedures are believed to be
generally applicable. However, each user should review these recommendations in
the specific context of the intended use and determine whether they are
appropriate.
The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance. For more product information by email, click here Imperial Supplies LLC does not provide services and products outside the United States |
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