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3M MATERIAL SAFETY DATA SHEET 3M Strip-Calk (Black) PN 08578 02/09/2006 3M Material Safety Data Sheet Copyright, 2006, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: 1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or other wise distributed with the intention of earning a profit there on. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 3M Strip-Calk (Black) PN 08578 MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-800-364-3577 OR (651) 737-6501 (24 hours) Issue Date: 02/09/2006 Supercedes Date: 10/12/2005 Document Group: 05-9750-0 Product Use: Specific Use: Caulk for use in seams, joints, and openings. SECTION 2: INGREDIENTS Ingredient C.A.S. No. % by Wt Kaolin 1332-58-7 15-40 Slag Wool None 15-40 Poly Butylene 9003-29-6 10-30 Aluminum Silicate 1327-36-2 3-7 Silica 7631-86-9 1-5 Aluminum Stearate 637-12-7 1-5 Carbon Black 1333-86-4 1-5 Heavy Paraffinic Distillate 64741-51-1 1-5 Rheological Additive Trade Secret 1-5 4,4'-Thiobis(6-Tert-Butyl-M-Cresol) 96-69-5 <=0.27 SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW Specific Physical Form: Viscous putty Odor, Color, Grade: Black, soft putty General Physical Form: Solid Immediate health, physical, and environmental hazards: 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing. Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching. Inhalation: No health effects are expected. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Wash affected area with soap and water. If signs/symptoms develop, get medical attention. Inhalation: No need for first aid is anticipated. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Auto ignition temperature No Data Available Flash Point Not Applicable Flammable Limits - LEL Not Applicable Flammable Limits - UEL Not Applicable 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents (e.g. dry chemical, carbon dioxide). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Not applicable. No unusual fire or explosion hazards are anticipated. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Observe precautions from other sections. Call 3M - HELPS line (1-800-364-3577) for more information on handling and managing the spill. Contain spill. Collect as much of the spilled material as possible. Clean up residue with detergent and water. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Avoid eye contact. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Avoid prolonged or repeated skin contact. Keep out of the reach of children. Avoid breathing of dust created by cutting, sanding, grinding or machining. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposures Limits. If ventilation is not adequate, use respiratory protection equipment. 7.2 STORAGE Store product at 60 F to 80 F. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Not applicable. Provide appropriate local exhaust for cutting, grinding, sanding or machining. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control dust, fume, or airborne particles. If ventilation is not adequate, use respiratory protection equipment. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection The following eye protection(s) are recommended: Safety Glasses with side shields, Indirect Vented Goggles. 8.2.2 Skin Protection Avoid prolonged or repeated skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Neoprene, Nitrile Rubber. 8.2.3 Respiratory Protection Avoid breathing of dust created by cutting, sanding, grinding or machining. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half face piece air-purifying respirator with P95 particulate filters. Consult the current 3M Respiratory Selection Guide for additional information or call 1-800- 243-4630 for 3M technical assistance. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed area thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit Additional Information 4,4'-Thiobis(6-Tert-Butyl-M-Cresol) ACGIH TWA 10 mg/m3 Table A4 4,4-Thiobis(6-Tert-Butyl-M-Cresol) OSHA TWA, 5 mg/m3 Table Z-1 (Resp.) 4,4-Thiobis(6-Tert-Butyl-M-Cresol) OSHA TWA, 10 mg/m3 Vacated, As dust. 4,4-Thiobis(6-Tert-Butyl-M-Cresol) OSHA TWA, 15 mg/m3 Table Z-1 as total dust Carbon Black ACGIH TWA 3.5 mg/m3 Table A4 Carbon Black CMRG TWA 0.5 mg/m3 Carbon Black OSHA TWA 3.5 mg/m3 Table Z-1 Ceramic Fibers (Airborne ACGIH TWA, 0.2fiber/cc Table A2 Particles of Respirable Size) as fibers >=5 um Kaolin ACGIH TWA, 2 mg/m3 Table A4 (Resp) Kaolin OSHA TWA, 5 mg/m3 Table Z-1 (Resp) Kaolin OSHA TWA, 10 mg/m3 Vacated, as dust Kaolin OSHA TWA, 15 mg/m3 Table Z-1 as total dust Silica CMRG TWA, 3 mg/m3 as resp. dust Stearates ACGIH TWA, 10 mg/m3 Table A4 as total dust VAC Vacated PEL: Vacated Permissible Exposure Limits {PEL} are enforced as the OSHA PEL in some states. Check with your local regulatory agency. SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Specific Physical Form: Viscous putty Odor, Color, Grade: Black, soft putty General Physical Form: Solid Auto ignition temperature: No Data Available Flash Point: Not Applicable Flammable Limits - LEL Not Applicable Flammable Limits - UEL Not Applicable Boiling Point: Not Applicable Density: 14.6 lb/gal Vapor Density: Not Applicable Vapor Pressure: Not Applicable Specific Gravity: 1.920 {Ref Std: WATER=1} pH: Not Applicable Melting Point: No Data Available Solubility in Water: Slight (less than 10%) Evaporation rate: Not Applicable Volatile Organic Compounds: Not Applicable Percent volatile: 00 % weight VOC Less H2O & Exempt Solvents: Not Applicable SECTION 10: STABILITY AND REACTIVITY Stability: Stable Materials and Conditions to Avoid: Sparks and/or flames Hazardous Polymerization: Hazardous polymerization will not occur. HAZARDOUS DECOMPOSITION OR BY-PRODUCTS Substance Condition Carbon monoxide Not Specified Carbon dioxide Not Specified SECTION 11: TOXICOLOGICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. SECTION 12: ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Incinerate in an industrial or commercial facility in the presence of a combustible material. As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste. EPA Hazardous Waste Number (RCRA): Not regulated Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14: TRANSPORT INFORMATION ID Number(s): 60-9800-1955-2 Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No STATE REGULATIONS Contact 3M for more information CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information. This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: OTHER INFORMATION NFPA Hazard Classification Health: 1 Flammability: 1 Reactivity: 0 Special Hazards: None National Fire protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Reason for Reissue: The MSDS has been revised because 3M has adopted the 16- section ANSI/ISO format. The potential hazards of the product have not changed. We encourage you to reread the MSDS and review the information. Revision Changes: Copyright was modified. Section 5: Unusual fire and explosion hazard information was modified. Section 8: Engineering controls information was modified. Section 2: Ingredient table was modified. Section 8: Exposure guidelines ingredient information was modified. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a data base may not be as current as the information in the MSDS available directly from 3M. 3M MSDSs are available at www.3M.com