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MSDS 7598 7598: Sikaflex 227 White [24]7599: Sikaflex 227 Gray [24] 7602: Sikaflex 227-202 Gray [20] (DISCONTINUED) 7606: Sikaflex 227-201 White [20] (DISCONTINUED) MSDS Last updated: 12/29/2009
IMPERIAL SUPPLIES LLC MSDS SHEET FOR 7599
Material Safety Data Sheet Sikaflex 227
1. PRODUCT AND COMPANY IDENTIFICATION
Product Name Sikaflex 227
Supplier Sika Corporation, Industry
30800 Stephenson Highway
Madison Heights, MI 48071
www.sikaindustry.com
Telephone no. (888) 832-7452
Fax no. (248) 577-0810
In case of emergency CHEMTREC: 800-424-9300
INTERNATIONAL: 703-527-3887
Manufacturer Sika Corporation, Operations
201 Polito Avenue
Lyndhurst, NJ 07071
www.sikacorp.com
Telephone no. (201) 933-8800
Validation date 1. June 2009
Print date 1. June 2009
Product type Solid
2. COMPOSITION/INFORMATION ON INGREDIENTS
Name CAS number %
OLYISOCYANATE PREPOLYMER TRADE SECRET
XYLENE (MIXED ISOMERS) 1330-20-7 <4
There are no additional ingredients present which, within the current
knowledge of the supplier and in the concentrations applicable, are classified
as hazardous to health or the environment and hence require reporting in this
section.
3. HAZARDS IDENTIFICATION
OSHA/HCS status This material is considered hazardous by the OSHA
Hazard communication Standard (29 CFR 1910.1200).
Potential acute health effects
Inhalation Toxic by inhalation. Irritating to respiratory system. May
cause sensitization by inhalation. Exposure to
decomposition products may cause a health hazard. Serious
effects may be delayed following exposure.
Ingestion Toxic if swallowed.
Skin Irritating to skin. May cause sensitization by skin
contact.
Eyes Irritating to eyes.
See toxicological information (section 11)
4. FIRST AID MEASURES
Note to physician In case of inhalation of decomposition products in a
fire, symptoms may be delayed. The exposed person may
need to be kept under medical surveillance for 48
hours.
5. FIRE-FIGHTING MEASURES
Flammability of the product: No specific fire or explosion hazard.
Extinguishing media
Suitable: Use an extinguishing agent suitable for the
surrounding fire.
Not suitable: None known.
Special exposure hazards Promptly isolate the scene by removing all
persons from the vicinity of the incident if
there is a fire. No action shall be taken
involving any personal risk or without suitable
training.
Hazardous combustion products Decomposition products may include the following
materials:
Carbon dioxide
Carbon monoxide
Nitrogen oxides
Halogenated compounds
Metal oxide/oxides
Special protective equipment Fire-fighters should wear appropriate protective
for the fire-fighters: equipment and self-contained breathing apparatus
(SCBA) with a full face-piece operated in a
positive pressure mode.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions: No action shall be taken involving any personal risk
or without suitable training. Evacuate surrounding
areas. Keep unnecessary and unprotected personnel
from entering. Do not touch or walk through spilled
material. Provide adequate ventilation. Wear
appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective
equipment (see section 8).
Environmental Avoid dispersal of spilled material and runoff and
precautions: contact with soil, waterways, drains and sewers.
Inform the relevant authorities if the product has
caused environmental pollution (sewers, waterways,
soil or air).
Large spill: Move containers from spill area. Approach release
from upwind. Prevent entry into sewers, water
courses, basements or confined areas. Vacuum or sweep
up material and place in a designated, labeled waste
container. Dispose of via a licensed waste disposal
contractor. Note: see section 1 for emergency contact
information and section 13 for waste disposal.
Small spill: Move containers from spill area. Vacuum or sweep up
material and place in a designated, labeled waste
container. Dispose of via a licensed waste disposal
contractor.
7. HANDLING AND STORAGE
Handling: Put on appropriate personal protective equipment (see section
8). Eating, drinking and smoking should be prohibited in
areas where this material is handled, stored and processed.
Workers should wash hands and face before eating, drinking
and smoking. Persons with a history of skin sensitization
problems or asthma, allergies or chronic or recurrent
respiratory disease should not be employed in any process in
which this product is used. Do not get in eyes or on skin or
clothing. Do not ingest. Use only with adequate ventilation.
Wear appropriate respirator when ventilation is inadequate.
Keep in the original container or an approved alternative
made from a compatible material, kept tightly closed when not
in use. Empty containers retain product residue and can be
hazardous. Do not reuse container.
Storage: Store in accordance with local regulations. Store in original
container protected from direct sunlight in a dry, cool and
well-ventilated area, away from incompatible materials (see
section 10) and food and drink. Keep container tightly closed
and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent
leakage. Do not store in unlabeled containers. Use
appropriate containment to avoid environmental contamination.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ethene, chloro-,homopolymer ACGIH TLV (United States, 1/2008).
TWA: 1 mg/m³ 8 hour(s). Form: Respirable
fraction
Xylene ACGIH TLV (United States, 1/2008).
STEL: 651 mg/m³ 15 minute(s).
STEL: 150 ppm 15 minute(s).
TWA: 434 mg/m³ 8 hour(s).
TWA: 100 ppm 8 hour(s).
OSHA PEL (United States, 11/2006).
TWA: 435 mg/m³ 8 hour(s).
TWA: 100 ppm 8 hour(s).
OSHA PEL 1989 (United States, 3/1989).
STEL: 655 mg/m³ 15 minute(s).
STEL: 150 ppm 15 minute(s).
TWA: 435 mg/m³ 8 hour(s).
TWA: 100 ppm 8 hour(s).
4.4'-methylenediphenyl ACGIH TLV (United States, 1/2008).
diisocyanate TWA: 0.005 ppm 8 hour(s).
NIOSH REL (United States, 6/2008).
CEIL: 0.2 mg/m³ 10 minute(s).
CEIL: 0.02 ppm 10 minute(s).
TWA: 0.05 mg/m³ 10 hour(s).
TWA: 0.005 ppm 10 hour(s).
OSHA PEL (United States, 11/2006).
CEIL: 0.2 mg/m³
CEIL: 0.02 ppm
OSHA PEL 1989 (United States, 3/1989).
CEIL: 0.2 mg/m³
CEIL: 0.02 ppm
Engineering measures: Use only with adequate ventilation. Use process
enclosures, local exhaust ventilation or other
engineering controls to keep worker exposure to
airborne contaminants below any recommended or
statutory limits.
Hygiene measures: Wash hands, forearms and face thoroughly after
handling chemical products, before eating, smoking
and using the lavatory and at the end of the working
period. Appropriate techniques should be used to
remove potentially contaminated clothing. Wash
contaminated clothing before reusing. Ensure that
eyewash stations and safety showers are close to the
workstation location.
Personal protection
Respiratory: Use a properly fitted, air-purifying or air-fed respirator
complying with an approved standard if a risk assessment
indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards
of the product and the safe working limits of the selected
respirator.
Hands: Chemical-resistant, impervious gloves complying with an
approved standard should be worn at all times when handling
chemical products if a risk assessment indicates this is
necessary.
Eyes: Safety eyewear complying with an approved standard should
be used when a risk assessment indicates this is necessary
to avoid exposure to liquid splashes, mists or dusts.
Skin: Personal protective equipment for the body should be
selected based on the task being performed and the risks
involved and should be approved by a specialist before
handling this product.
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash point: Closed cup: 61.6oC (142.9oF)
Color: Various
Odor: Aromatic.
Density: ~1.27 g/cm3
VOC: 48.9 (g/l).
10. STABILITY AND REACTIVITY
Stability: The product is stable.
Conditions to avoid: No specific data.
Materials to avoid: No specific data.
Hazardous decomposition Under normal conditions of storage and use,
products: hazardous decomposition products should not be
produced.
Hazardous polymerization: Under normal conditions of storage and use,
hazardous polymerization will not occur.
11. TOXICOLOGICAL INFORMATION
Potential chronic health effects
Chronic effects: Contains material that may cause target organ damage,
based on animal data. Once sensitized, a severe allergic
reaction may occur when subsequently exposed to very low
levels.
Carcinogenicity: Contains material which may cause cancer, based on animal
data. Risk of cancer depends on duration and level of
exposure
Acute toxicity
Conclution/Summary: Not available.
Carcinogenicity
Classification
Product/ingredient name ACGIH IARC EPA NIOSH NTP OSHA
Ethene, chloro-, homopolymer A4 3 - - - -
Xylene A4 3 - - - -
4,4'-methylenediphenyl - 3 - - - -
diisocyanate
12. ECOLOGICAL INFORMATION
Environmental effects: No known significant effects or critical hazards.
13. DISPOSAL CONSIDERATIONS
Waste disposal The generation of waste should be avoided or minimized
wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be
disposed of in a safe way. Dispose of surplus and
non-recyclable products via a licensed waste disposal
contractor. Disposal of this product, solutions and any
byproducts should at all times comply with the requirements
of environmental protection and waste disposal legislation
and any regional local authority requirements. Avoid
dispersal of spilled material and runoff and contact with
soil, waterways, drains and sewers.
Disposal should be in accordance with applicable regional, national and local
laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE
CONTROLS/PERSONAL PROTECTION for additional handling information and
protection of employees.
14. TRANSPORT INFORMATION
Regulatory UN number Proper shipping Classes PG* Additional
information name information
DOT Classification Not regulated - - -
TDG Classification Not regulated - - -
ADR/RID Class Not regulated - - -
IMDG Class Not regulated - - -
IATA-DGR class Not regulated - - -
PG* : Packing group
15. REGULATORY INFORMATION
U.S. Federal TSCA 8(a) PAIR: 4,4'-methylenediphenyl diisocyanate
Regulations: United States inventory (TSCA 8b): All components are listed or
exempted.
TSCA 8(d) H and S data reporting: 4,4'-methylenediphenyl
diisocyanate: 1990
SARA 302/304/311/312 extremely hazardous substances: No products
were found.
SARA 302/304 emergency planning and notification: No products
were found.
SARA 302/304/311/312 hazardous chemicals: xylene; Ethene,
chloro-, homopolymer;
calcium carbonate; titanium dioxide
SARA 311/312 MSDS distribution - chemical inventory - hazard
identification:
xylene: Fire hazard, Immediate (acute) health hazard, Delayed
(chronic) health hazard;
Ethene, chloro-, homopolymer: Delayed (chronic) health hazard;
calcium carbonate:
Immediate (acute) health hazard; titanium dioxide: Immediate
(acute) health hazard
Clean Water Act (CWA) 307: vinyl chloride; ethylbenzene
Clean Water Act (CWA) 311: xylene; ethylbenzene
Clean Air Act (CAA) 112 accidental release prevention: vinyl
chloride
Clean Air Act (CAA) 112 regulated flammable substances: vinyl
chloride
Clean Air Act (CAA) 112 regulated toxic substances: No products
were found.
SARA 313
Form R- Reporting Product name CAS number Concentration
requirements
Xylene 1330-20-7 1 - 5
Ethylbenzene 100-41-4 <1
SARA 313 notifications must not be detached from the MSDS and any copying and
redistribution of the MSDS shall include copying and redistribution of the
notice attached to copies of the MSDS subsequently redistributed.
State regulations Massachusetts Substances: The following components are
listed:
XYLENE; TITANIUM DIOXIDE
New Jersey Hazardous The following components are
Substances: listed:
XYLENE; ETHYL BENZENE;
TITANIUM DIOXIDE
New York Acutely Hazardous The following components are
Substances: listed:
Xylene (mixed); Ethylbenzene
Pennsylvania RTK Hazardous The following components are
Substances: listed:
BENZENE, DIMETHYL-; BENZENE,
ETHYL-; TITANIUM OXIDE (TIO2)
California Prop. 65
WARNING: This product contains a chemical known to the state of California to
cause cancer and birth defects or other reproductive harm.
Ingredient name Cancer Reproductiv No Maximum
e significant acceptable
risk level dosage
level
1,2-Benzenedicarboxylic acid, No. Yes. No. No.
di-C9-11-branches alkyl esters,
C10-rich
ethylbenzene Yes No. No. No.
Quartz (SiO2) Yes. No. No. No.
Vinyl chloride Yes. No. Yes. No.
United States inventory (TSCA 8b) : All components are listed or exempted.
16. OTHER INFORMATION
Hazardous Material Health * 2
Information System
(U.S.A):
Flammability 2
Physical hazards 0
Personal Protection C
Equipment
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing
minimal hazards or risks, and 4 representing significant hazards or risks
Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.1200, the
preparer may choose to provide them. HMIS® ratings are to be used with a fully
implemented HMIS® program. HMIS® is a registered mark of the National Paint &
Coatings Association (NPCA). HMIS® materials may be purchased exclusively from
J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Date of printing: 01.06.2009.
Date of issue: 01.06.2009.
Date of previous issue: 29.05.2009
Version: 1.01
Indicates information that has changed from previously issued version.
Notice to reader
The information contained in this Material Safety Data Sheet applies only to
the actual Sika Corporation ("Sika") product identified and described herein.
This information is not intended to address, nor does it address the use or
application of the identified Sika product in combination with any other
material, product or process. All of the information set forth herein is based
on technical data regarding the identified product that Sika believes to be
reliable as of the date hereof. Prior to each use of any Sika product, the
user must always read and follow the warnings and instructions on the
product's current Technical Data Sheet, product label and Material Safety Data
Sheet for each Sika product, which are available at web site and/or telephone
number listed in Section 1 of this MSDS.
SIKA MAKES NO WARRANTIES EXPRESS OR IMPLIED AND ASSUMES NO LIABILITY ARISING
FROM THIS INFORMATION OR ITS USE. SIKA SHALL NOT BE LIABLE UNDER ANY LEGAL
THEORY FOR SPECIAL OR
CONSEQUENTIAL DAMAGES AND SHALL NOT BE RESPONSIBLE FOR THE USE OF THIS PRODUCT
IN A
MANNER TO INFRINGE ON ANY PATENT OR ANY OTHER INTELLECTUAL PROPERTY RIGHTS
HELD BY OTHERS.
All sales of Sika products are subject to its current terms and conditions of
sale available at www.sikacorp.com or 201-933-8800.
The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance. For more product information by email, click here Imperial Supplies LLC does not provide services and products outside the United States |
