MSDS 7597

                            MATERIAL SAFETY DATA SHEET
                               POLAROID CORPORATION
                OFFICE OF HEALTH, SAFETY, & ENVIRONMENTAL AFFAIRS
                       1265 MAIN STREET - WALTHAM, MA 02254
                                  (781) 386-0879

 
Data Sheet No.  M-0628           Revision XI             NFPA FIRE HAZARD SYMBOL
 
Compiled by: E. Karger          Issue Date: 17-NOV-2004   4- Extreme
                                                                 3- High
                                                                 2- Moderate
 
                                                        1- 1- Slight
                                                        0- 0- Insignificant
 

                  SECTION I - PRODUCT AND COMPANY IDENTIFICATION

 
COMMON NAMES:   DEVELOPER FLUID CONTAINED IN POD OF FILM TYPES
         600, 708, 778, 779, 339, 600++, 309, 909, 600+, SPECTRA,
         IMAGE, 6000, 7000, 330, 990, CAPTIVA 95, VISION 95, 
         JOYCAM 95, POCKET FILM, I-ZONE, EXTREME GLOSS
         FILM: ALTER IMAGE, MATTE,: MAT-T-E
 

               SECTION II - COMPOSITION/INFORMATION ON INGREDIENTS

 
CHEMICAL FAMILY:  MIXTURE
 
INGREDIENTS
Please note that chemicals present in the mixture in concentrations below 1% 
which are considered not to be a hazard may not be included in the list of 
ingredients. 
 
Material                     %          MSDS#      CAS#            PL#/Comments
--------------------------------------------------------------------------------
POTASSIUM HYDROXIDE         5-10                    001310-58-3
TITANIUM DIOXIDE           30-60                  013463-67-7
P-TOLUENESULFINIC ACID,    0.10-1                  000824-79-3
SODIUM SALT-HYDRATE
2-ETHYLIMIDAZOLE           1-5                    001072-62-4
HYPOXANTHINE                0.50-1.50             000068-94-0
SNP22E: SNP22K              1-3
6-METHYLURACIL              0.10-1                  000626-48-2
WATER                         40-70                  007732-18-5
CARBOPOL ISX 1893 RESIN: 1-5                    000000-00-0
CARBOPOL ISX 1993 RESIN
ETHYL DIOXANE - .ALPHA.- 0.10-0.50
PIC BROMIDE
TRANEXAMIC ACID             0.10-0.50             001197-18-8


                       SECTION III - HAZARDS IDENTIFICATION

 
Hazard Signal Word         WARNING
 
Hazards
  CONTAINS ALKALI
  Eye Contact May Cause Permanent Eye Damage.
  Skin and Mouth Contact May Cause Irritation or Burns.
 
Precautionary Measures
  Do not get in eyes, on skin, mouth or clothing.
  Wash thoroughly after handling
 
INGREDIENT EXPOSURE LIMITS
 
POTASSIUM HYDROXIDE
 
OSHA Permissible Exposure Limit:   PEL/TWA  2  mg/m3  (ceiling)
ACGIH            TLV/TWA  2 mg/m3   (ceiling)
 
TITANIUM DIOXIDE
 
OSHA Permissible Exposure Limit:   PEL/TWA  15  mg/m3  (total dust) 
                                   5 mg/m3  (respirable fraction)
ACGIH            TLV/TWA  10 mg/m3  (total dust)
 
P-TOLUENESULFINIC ACID, SODIUM SALT-HYDRATE
 
OSHA Permissible Exposure Limit:   PEL/TWA  None established
ACGIH            TLV/TWA Not listed
 
2-ETHYLIMIDAZOLE
 
OSHA Permissible Exposure Limit: PEL/TWA   None established
ACGIH                   TLV/TWA   Not listed
 
HYPOXANTHINE
 
OSHA Permissible Exposure Limit:  PEL/TWA  None established
ACGIH                    TLV/TWA  Not listed
 
SNP22E: SNP22K
 
OSHA Permissible Exposure Limit:   PEL/TWA   None established 
ACGIH   TLV/TWA  Not listed   
 
6-METHYLURACIL
 
OSHA Permissible Exposure Limit:   PEL/TWA   None established
ACGIH   TLV/TWA  Not listed
 
CARBOPOL ISX 1893 RESIN: CARBOPOL ISX 1993 RESIN
 
OSHA Permissible Exposure Limits   PEL/TWA  None established
ACGIH   TLV/TWA  Not listed
 
ETHYL DIOXANE-.ALPHA.-PIC BROMIDE
 
OSHA Permissible Exposure Limit:   PEL/TWA  None established
ACGIH   TLV/TWA  Not listed
 
TRANEXAMIC ACID
 
OSHA Permissible Exposure Limit:   PEL/TWA  None established
ACGIH   TLV/TWA  Not listed
 
SECTION IV - FIRST AID MEASURES
 
EYE CONTACT:
In case of eye contact, immediately flush eyes with plenty of water for at least 
fifteen 
fifteen minutes. Remove contact lenses if worn. Seek Medical attention 
immediately. 
 
SKIN CONTACT:
In case of skin contact, flush affected area with plenty of water. 
 
ORAL CONTACT;
In case of oral contact rinse mouth immediately with plenty of water. Drink 
water or 
citrus juices to dilute or neutralize any alkali that may have been swallowed. 
Do NOT
induce vomiting. Seek Medical attention immediately. 
 
INGESTION:
Get Medical attention immediately. If swallowed, do NOT induce vomiting unless 
directed to do so by Medical personnel. Never give anything by mouth to an 
unconscious person. 
 
NOTES TO PHYSICIAN
Prolonged contact with skin may produce alkali burns. 
 

                        SECTION V - FIRE FIGHTING MEASURES

 
Flash Point:      (Tag Closed Cup):   Mixture will not burn. 
 

                     SECTION VI - ACCIDENTAL RELEASE MEASURES

 
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
Handle film so as not to break developer pods prior to film development. 
Small quantities of developer fluid may be wiped up with a damp paper towel 
using care
to avoid any skin or eye contact.
 

                       SECTION VII -  HANDLING AND STORAGE

 
Not Available
 

               SECTION VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION

 
RECOMMENDED VENTILATION:
Not normally required. 
 
RESPIRATORY PROTECTION;
Not normally required.
 
EYE PROTECTION;
Not normally required.
 
SKIN PROTECTION;
Not normally required.
 

                  SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES

 
Appearance and Odor: Cream, white, tan, gray or pink viscous fluid. 
 
Melting Point:         ND
Boiling Point:         @ 760 mm Hg: 100 ºC (212ºF)  (Water)
Specific Gravity(H2O=1):     1.1
% Solubility in Water:   @ 20ºC:  dilutable
Vapor Density (Air=1):   ND
% Volatiles by volume;   85 (approximate)
Vapor Pressure:      ND
Evaporation Rate:      (BUTYL ACETATE=1):  <1
pH:             > 13 - Drops rapidly after processing
Pour Point;         ND
Softening Point:      ND
Viscosity;         ND
Bulk Density:         ND
Surface Tension:      ND
Log Kow:         ND
 

                       SECTION X - STABILITY AND REACTIVITY

 
Hazardous Reactivity:
Mixture is considered stable.
 

                      SECTION XI - TOXICOLOGICAL INFORMATION

 
INHALATION:
May be an irritant
 
SKIN CONTACT:   
Corrosive
 
EYE:
Corrosive
 
INGESTION:
Corrosive
 
Effects of Acute Overexposure: 
Eye contact with developer may cause permanent eye damage. May cause burns to 
skin and mouth. 
 
Effects of Chronic Overexposure:
None currently known.
 

                       SECTION XII - ECOLOGICAL INFORMATION

 
Not Available
 

                      SECTION XIII - DISPOSAL CONSIDERATIONS

 
Product (film pack, picture) is not classified or regulated under U.S. federal 
law as "RCRA Hazardous"  before or after processing. 
 

                       SECTION XIV - TRANSPORT INFORMATION

 
OTHER D.O.T. INFORMATION
Film product not regulated
 

                       SECTION XV - REGULATORY INFORMATION

 
All ingredients are listed on the TSCA inventory.
This product has been classified in accordance with the hazard criteria of the 
Canadian Controlled Product Regulations (CPR) and the MSDS contains all the 
information required by the CPR. 
 

                         SECTION XVI - OTHER INFORMATION

 
NOTE:  Film conforms to ASTM D-4236
 
ND = No Data
NA = Not Applicable

The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance.

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