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MSDS 7596 7596: Sikaflex 221 Gray [24]7596-1: Sikaflex 221 Gray [1] 7643: Sikaflex 221 White Cartridge [24] 7643-1: Sikaflex 221 White [1] MSDS Last updated: 03/10/2010
IMPERIAL SUPPLIES LLC MSDS SHEET FOR 75961, 7643 & 7643-1
Sika Sikaflex 221
Section 1 Product and Company Identification
Product Name: Sikaflex 221
Supplier Sika Corporation, Industry
30800 Stephenson Highway
Madison Heights, MI 48071
www.sikaindustry.com
Telephone number: (888) 832-7452
Fax No. (248) 577-0810
In case of Emergency: Chemtrec :800-424-9300
International: 703-527-3887
Manufacturer: Sika Corporation, Operations
201 Polito Avenue
Lyndhurst, NJ 07071
www.sikacorp.com
Telephone No. (201) 933-8800
Validation Date: 2. July 2009
Print Date: 2. July 2009
Product Type: Solid
Section 2. Composition/Information on ingredients
Name CAS Number %
Xylene (Mixed Isomers) 1330-20-7 < 4
Polyisocyanate Prepolymer TRADE SECRET
There are no additional ingredients present which, within the current
knowledge of the supplier and in the concentrations applicable, are classified
as hazardous to health or the environment and hence require reporting in this
section.
Section 3 Hazards Identification
OSHA/HCS Status: This material is considered
hazardous by the OSHA Hazard
Communication Standard (29 CFR
1910.1200)
Potential acute health effects:
Inhalation: Toxic by inhalation. Irritating
to respiratory system. May cause
sensitization by inhalation.
Exposure to decomposition
products may cause a health
hazard. Serious effects may be
delayed following exposure.
Ingestion: Toxic if swallowed
Skin: Irritating to skin. May cause
sensitization by skin contact.
Eyes: Irritating to eyes.
See Toxicological Information (see section 11)
Section 4 First Aid Measures
Eye contact: Check for and remove any contact
lenses. Get medical attention.
Immediately flush eyes with
plenty of water for at least 15
minutes.
Skin Contact: Get medical attention
immediately. Flush contaminated
skin with plenty of water.
Remove contaminated clothing and
shoes. Wash contaminated
clothing thoroughly with water
before removing it, or wear
gloves. Continue to rinse for at
least 10 minutes. In the event
of any complaints or symptoms,
avoid further exposure. Wash
clothing before reuse.
Inhalation: Get medical attention
immediately. Move exposed person
to fresh air. If it is suspected
that fumes are still present,
the rescuer should wear an
appropriate mask or
self-contained breathing
apparatus. If not breathing, if
breathing is irregular, or if
respiratory arrest occurs,
provide artificial respiration
or oxygen by trained personnel.
If may be dangerous to the
person providing aid to give
mouth to mouth resuscitation.
Maintain an open airway. In case
of inhalation of decomposition
products in a fire, symptoms may
be delayed. The exposed person
may need to be kept under
medical surveillance for 48
hours. In the event of any
complaints or symptoms, avoid
further exposure.
Ingestion: Get medical attention
immediately. Wash out mouth with
water. Move exposed person to
fresh air. If material has been
swallowed and the exposed person
is conscious, give small
quantities of water to drink. Do
not induce vomiting unless
directed to do so by medical
personnel. Never give anything
by mouth to an unconscious
person.
Notes to Physician: In case of inhalation of
decomposition products in a
fire, symptoms may be delayed.
The exposed person may need to
be kept under medical
surveillance for 48 hours.
Section 5 Fire Fighting Measures
Flammability of the Product: No specific fire of explosion
hazard
Extinguishing Media
Suitable: Use an extinguishing agent
suitable for surrounding fire.
Not Suitable: None Known
Special Exposure hazards: Promptly isolate the scene by
removing all persons from the
vicinity of the incident if
there is a fire. No action shall
be taken involving any personal
risk or without suitable
training.
Hazardous combustion products: Decomposition products may
include the following materials:
Carbon Dioxide
Carbon Monoxide
Nitrogen Oxides
Halogenated Compounds
Metal oxide/oxides
Special protective equipment for Fire-fighters should wear
firefighters: appropriate protective equipment
and self-contained breathing
apparatus (SCBA) with a full
face-piece operated in positive
pressure mode.
Section 6 Accidental Release Measures
Personal Precautions: No action shall be taken
involving any personal risk or
without suitable training.
Evacuate surrounding areas. Keep
unnecessary and unprotected
personnel from entering. Do not
touch or walk through spilled
material. Provide adequate
ventilation. Wear appropriate
respirator when ventilation is
inadequate. Put on appropriate
personal protective equipment
(See Section 8).
Environmental Precautions: Avoid dispersal of spilled
material and runoff and contact
with soil, waterways, drains and
sewers. Inform the relevant
authorities if the product has
caused environmental pollution
(sewers, waterways, soil, or
air).
Large Spill: Move containers from spill area.
Approach release from upwind.
Prevent entry into sewers, water
courses, basements or confined
areas. Vacuum or sweep up
material and place in a
designated; labeled waste
container. Dispose of via a
licensed waste disposal
contractor. Note: See section 1
for emergency contact
information and section 13 for
waste disposal.
Small Spill: Move containers from spill area.
Vacuum or sweep up material and
place in a designated, labeled
waste container. Dispose of via
a licensed disposal contractor.
Section 7 Handling and Storage
Handling: Put on appropriate personal
protective equipment (see
section 8). Eating, drinking and
smoking should be prohibited in
areas where this material is
handled, stored and processed.
Workers should wash hands and
face before eating, drinking and
smoking. Persons with a history
of skin sensitization problems
or asthma, allergies or chronic
recurrent respiratory disease
should not be employed in any
process which this product is
used. Do not get in eyes, or on
skin or clothing. Do not ingest.
Use only with adequate
ventilation. Wear appropriate
respirator when ventilation is
inadequate. Keep in the original
container or an approved
alternative made from a
compatible material, kept
tightly closed when not in use.
Empty containers retain product
residue and can be hazardous. Do
not reuse container.
Storage: Store in accordance with local
regulations. Store in original
container protected from direct
sunlight in a dry, cool and well
ventilated area, away from
incompatible materials (see
section 10) and food and drink.
Keep container tightly closed
and sealed until ready for use.
Containers that have been opened
must be carefully resealed and
kept upright to prevent leakage.
Do not store in unlabeled
containers. Use appropriate
containment to avoid
environmental contamination.
Section 8. Exposure Controls/Personal Protection:
Product Name Exposure Limits
Ethene, chloro-, homopolymer ACGIH TLV (United States,
1/2008)
TWA: 1 mg/m3 8 hour(s). Form:
Respirable Fraction
Xylene ACGIH TLV (United States,
1/2008)
STEL: 651 mg/m3 15 Minute(s)
STEL: 150 ppm 15 Minute(s)
TWA: 434 mg/m3 8 hour(s)
TWA 100 ppm 8 hour(s)
OSHA PEL(United States, 11/2006)
TWA: 435 mg/m3 8 hour(s)
TWA: 100 ppm 8 hour(s)
OSHA PEL 1989 (United States,
3/1989)
STEL: 655 mg/m3 15 minute(s)
STEL: 150 ppm 15 minute(s)
TWA: 435 mg/m3 8 hour(s)
TWA: 100 ppm 8 hour(s)
4,4'- methylenediphenyl diisocyanate ACGIH TLV (United States,
1/2008)
TWA: 0.005 ppm 8 hour(s)
NIOSHA REL (United States,
6/2008)
CEIL: 0.2 mg/m3 10 minute(s)
CEIL: 0.02 ppm 10 minute(s)
TWA: 0.05 mg/m3 10 hour(s)
TWA: 0.005 ppm 10 hour(s)
OSHA PEL (United States,
11/2006)
CEIL: 0.2 mg/m3
CEIL: 0.02 ppm
OSHA PEL 1989 (United States,
3/1989)
CEIL: 0.2 mg/m3
CEIL: 0.02 ppm
Engineering measures: Use only with adequate
ventilation. Use process
enclosures, local exhaust
ventilation or other engineering
controls to keep worker exposure
to airborne contaminates below
any recommended or statutory
limits.
Hygiene Measures: Wash hands, forearms, and face
thoroughly after handling
chemical products, before
eating, drinking, smoking and
using the lavatory and at the
end of the working period.
Appropriate techniques should be
used to remove potentially
contaminated clothing. Wash
contaminated clothing before
reusing. Ensure that eye wash
stations and safety showers are
close to the workstation
location.
Personal Protection:
Respiratory: Use a properly fitted, air
purifying or air fed respirator
complying with an approved
standard of risk assessment
indicates this is necessary.
Respirator selection must be
based on known or anticipated
exposure levels, the hazards of
the product and the safe working
limits of the selected
respirator.
Hands: Chemical-resistant, impervious
gloves complying with an
approved standard should be worn
at all times when handling
chemical products if a risk
assessment indicates this is
necessary.
Eyes: Safety eyewear complying with an
approved standard should be used
when a risk assessment indicates
this is necessary to avoid
exposure to liquid splashes,
mists or dusts.
Skin: Personal protective equipment
for the body should be selected
based on the task being
performed and the risks involved
and should be approved by a
specialist before handling this
product.
Section 9. Physical and Chemical Properties
Physical State: Paste.
Color: Various.
Odor: Aromatic.
Density: ~ 1.27 g/cm3.
VOC: 48 (g/l).
Section 10. Stability and Reactivity
Stability: The product is stable.
Conditions to avoid: No Specific Data.
Materials for avoid: No Specific Data.
Hazardous decomposition products: Under normal conditions of
storage and use, hazardous
decomposition products should
not be produced.
Hazardous Polymerization: Under normal conditions of
storage and use, hazardous
polymerization will not occur.
Section 11. Toxicological Information:
Potential Chronic Health Effects:
Chronic Effects: Contains material that may cause
target organ damage, based on
animal data. Once sensitized, a
severe allergic reaction may
occur when subsequently exposed
to very low levels.
Carcinogenicity: Contains material which may
cause cancer, based on animal
data. Risk of cancer depends of
duration and level of exposure.
Acute Toxicity:
Conclusion/Summary: Not Available
Carcinogenicity Classification:
Product/ingredient ACGIH IARC EPA NIOSH NTP OSHA
Name
Ethene, A4 3 - - - -
Chloro-,homopolymer
Xylene A4 3 - - - -
4,4'-methylenediphenyl 3 - - - -
diisocyanate
Section 12. Ecological Information
Environmental Effects: The generation of waste should be
avoided or minimized wherever
possible. Empty containers or
liners may retain some product
residues. This material and its
container must be disposed of in a
safe way. Dispose of surplus and
non-recyclable products via a
licensed waste disposal contractor.
Disposal of this product, solutions
and any by-products should at all
times comply with the requirements
of the environmental protection and
waste disposal legislation and any
regional local authority
requirements. Avoid dispersal of
spilled material and runoff and
contact with soil, waterways,
drains and sewers.
Disposal should be in accordance with applicable regional, national and local
laws and regulations.
Refer to Section 7: HANDLING AND STORAGE: and Section 8: EXPOSURE
CONTROLS/PERSONAL PROTECTION for additional handling information and
protection for employees.
Section 14. Transport Information
Regulatory UN Number Proper Classes PG* Additional
Information Shipping Information
Name
DOT Not - - -
Classification Regulated
TDG Not - - -
Classification Regulated
ADR/RID Class Not - - -
Regulated
IMGD Class Not - - -
Regulated
IATA-DGR Class Regulated - - -
PG*: Packing Group
Section 15. Regulatory Information
U.S. Federal Regulations: TSCA 8(a) PAIR:
4,4'-methylenediphenyl diisocyanate
United States inventory (TSCA 8b):
All Components are listed or
exempted.
TSCA 8(d) H and S data reporting:
4,4'-methylenediphenyl
diisocyanate:1990
SARA 302/304/311/312 extremely
hazardous substances: No products
were found.
SARA 302/304 emergency planning and
notification: No Products were
found.
SARA 302/304/311/312 hazardous
chemicals: Xylene; Ethene, Chloro-,
Homopolymer; calcium carbonate;
titanium dioxide.
SARA 311/312 MSDS distribution-
chemical inventory-hazard
identification: Xylene: Fire
hazard, Immediate (acute) health
hazard, Delayed (chronic) health
hazard; Ethene,
chloro-,homopolymer: Delayed
(chronic) health hazard; Calcium
carbonate: Immediate (acute) health
hazard; titanium dioxide: Immediate
(acute) health hazard.
Clean Water Act (CWA) 307: Vinyl
chloride; ethylbenzene.
Clean Water Act(CWA) 311: Xylene;
ethylbenzene
Clean Air Act (CAA) 112 accidental
release prevention: Vinyl chloride
Clean Air Act (CAA) 112 regulated
flammable substances: Vinyl
chloride
Clean Air Act (CAA) 112 regulated
toxic substances: No products were
found.
SARA 313
Product Name CAS Number Concentration
Xylene 1330-20-7 1-5
Ethylbenzene 100-41-4 <1
Form R- Reporting requirements:
SARA 313 notifications must not be detached from the MSDS and any copying and
redistribution of the MSDS shall include copying and redistribution of the
notice attached to copies of the MSDS subsequently redistributed.
State Regulations: Massachusetts Substances: The
following components are listed:
XYLENE; TITANIUM DIOXIDE
New Jersey Hazardous Substances:
The following components are
listed: XYLENES; ETHYL BENZENE;
TITANIUM DIOXIDE.
New York Acutely Hazardous
Substances: The following
components are listed: Xylene
(mixed); Ethylbenzene
Pennsylvania RTK Hazardous
Substances: The following
components are listed: BENZENE,
DIMETHYL-; BENZENE, ETHYL-;
TITANIUM OXIDE (TI02)
California Prop. 65
WARNING: This product contains a chemical known to the state of California to
cause cancer, and birth defects or other reproductive harm.
Ingredient Name Cancer Reproductive No Maximum
significant acceptable
risk level dosage level
1,2-Benzenedicarbox No Yes No No
ylic acid,
di-C9-11-branched
alkyl esters,
C10-rich
Ethylbenzene Yes No No No
Quartz (Si02) Yes No No No
Vinyl Chloride Yes No Yes No
United States Inventory (TSCA 8b): All components are listed or exempted
Section 16. Other Information
Hazardous Material Information System (U.S.A.):
Health * 2 Flammability 1 Physical Hazards 0 Personal Protection
Equipment C
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing
minimal hazards or risks, and 4 representing significant hazards or risks
Although HMIS ratings are not required on MSDSs under 29 CFR 1910.1200, the
preparer may choose to provide them. HMIS ratings are to be used with a fully
implemented HMIS program. HMIS is a registered mark of the National Paint &
Coatings Association (NPCA). HMIS materials may be purchased exclusively from
J.J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Date of Printing: 02.07.2009.
Date of Issue: 02.07.2009.
Date of previous Issue: 01.07.2009
Version: 1.03
Notice to reader:
The information contained in this Material Data Safety Sheet applies only to
the actual Sika Corporation ("Sika") product identified and described herein.
This information is not intended to address, nor does it address to the use of
application of the identified sika product in combination with any other
material, product or process. All of the information set forth herein in based
on technical data regarding the identified product that sika believes to be
reliable as the date hereof. Prior to each use of any Sika product, the user
must always read and follow the warnings and instructions on the product's
current Technical Data Sheet, product label and Material Safety Data Sheet for
each sika product, which are available at web site and/or telephone number
listed in Section 1 of this MSDS
SIKA MAKES NO WARRANTIES EXPRESS OR IMPLIED AND ASSUMES NO LIABILITY ARISING
FROM THIS INFORMATION OR ITS USE. SIKA SHALL NOT BE LIABLE UNDER ANY LEGAL
THEORY FOR SPECIAL OR CONSEQUENTIAL DAMAGES AND SHALL NOT BE RESONSIBLE FOR
THE USE OF THIS PRODUCT IN A MANNER TO INFRINGE ON ANY PATENT OR ANY
INTELLECTUAL PROPERTY RIGHTS HELD BY OTHERS.
All sales of sika product are subject to its current terms and conditions of
sale available at www.sikacorp.com or 201-933-8800.
The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance. For more product information by email, click here Imperial Supplies LLC does not provide services and products outside the United States |
