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MSDS 5268 5268: Battery Panasonic Batt [1]MSDS Last updated: 02/01/2010
IMPERIAL SUPPLIES LLC MSDS SHEET FOR 5268
Panasonic Batteries
Panasonic Industrial Company
A Division of Panasonic Corporation of North America
5201 Tollview Drive, 1F-3
Rolling Meadows, IL 60008
Toll Free: 877-726-2228
Fax: 847-637-4660
Internet: www.panasonic.com/batteries
Email: oembatteries@panasonic.com
Product: Poly-carbonmonofluoride (BR Type) Lithium Batteries
Applicable models/sizes: All BR type cylindrical and coin batteries, except
our BR-C.
Revision: H January 2009
MSDS
Material Safety Data Sheets (MSDS) are a sub-requirement of the Occupational
Safety and Health Administration (OSHA) Hazard Communication Standard, 29 CFR
Subpart 1910.1200. This Hazard Communication Standard does not apply to
various subcategories including anything defined by OSHA as an "article". OSHA
has defined "article" as a manufactured item other than a fluid or particle;
(i) which is formed to a specific shape or design during manufacture; (ii)
which has end use function(s) dependent in whole or in part upon its shape or
design during end use; and (iii) which under normal conditions of use does not
release more than very small quantities, e.g. minute or trace amounts of a
hazardous chemical, and does not pose a physical hazard or health risk to
employees.
Because all of our batteries are defined as "articles", they are exempt from
the requirements of the Hazard Communication Standard; Hence a MSDS is not
required.
The following components are found in a Panasonic Poly-carbonmonofluoride (BR)
Lithium battery:
Cylindrical Cell Material Formula
Components
Positive Electrode Poly-carbonmonofluoride (CF)n
Negative Electrode Lithium Li
Electrolyte y-Butyrolactone-Solvent C4H6O2
1,2 C4H10O2
Dimethoxyethane-Solvent
Lithium LiBF4
Tetrafluroborate-Salt
Coin Cell Components Material Formula
Positive Electrode Poly-carbonmonofluoride (CF)n
Negative Electrode Lithium Li
Electrolyte y-Butyrolactone-Solvent C4H6O2
1,2 C4H10O2
Dimethoxyethane-Solvent
Lithium LiBF4
Tetrafluroborate-Salt
DISPOSAL
The batteries referenced herein are exempt articles and are not subject to the
OSHA Hazard Communication Standard requirement. This sheet is provided as a
service to our customers.
Lithium batteries are neither specifically listed nor exempted from the
Federal Environmental Protection Agency (EPA) hazardous waste regulations as
promulgated by the Resource Conservation and Recovery Act (RCRA). The only
metal of possible concern in a lithium battery is lithium that is not a listed
or characteristic toxic hazardous waste. Waste lithium batteries can be
considered a reactive hazardous waste if there is a significant amount of
unreacted, or unconsumed lithium remaining in the spent battery. The key to
disposing of a lithium battery as non-hazardous waste. You can dispose of a
fully charged or partially discharged lithium battery as a hazardous waste
after they are first neutralized through an approved secondary treatment. The
need for a secondary treatment prior to disposal is a requirement of the U.S.
Land Ban Restrictions of the hazardous and Solid Waste Amendments of 1984. A
secondary treatment center can only receive these batteries as manifested
hazardous waste. The waste code for charged lithium batteries is D003,
reactive. In either case, button cell batteries contain so little lithium that
they never qualify as a reactive hazardous waste. These batteries are safe for
disposal in the normal municipal waste stream. Disposal of large quantities of
undischarged lithium batteries should be performed by permitted, professional
disposal firms knowledgeable in Federal, State and local hazardous material
and hazardous waste transportation and disposal requirements. As always,
households are exempt from the RCRA hazardous waste guidelines. In California,
packages that contain CR lithium coin cells and the Owners/Operating
Instructions of products that contain CR lithium coin cells must include the
following statement: "Perchlorate Material - special handling may apply. See
www.dtsc.ca.gov/hazardouswaste/perhorate". The effective date for this
Perchlorate label was July 1, 2006 for non-consumer products and January 1,
2007 for consumer products.
TRANSPORTATION
Effective October 1, 2008 all Panasonic lithium batteries, except for our
BR-C, are not subject to the requirements of the Department of Transportation
(DOT) subchapter C, Hazardous Materials Regulations if shipped in compliance
with 49 CFR 173.185 and Special Provision 188.
Effective January 1, 2009 all Panasonic lithium batteries can be shipped by
air in accordance with International Civil Aviation Organization (ICAO),
Section II or International Air Transport Association (IATA), part 1 Packing
Instructions (PI) 968 (Batteries), PI 969 (Batteries, packed with equipment)
and PI 970 (Batteries, contained in equipment) as appropriate.
Currently all Panasonic lithium batteries are regulated by the International
Maritime Organization (IMO) under Special Provisions 188 and 230. These
regulations will stay in effect until January 1, 2010 when Special provisions
188 and 230 will be updated.
If you build any of our lithium cells into a battery pack, you must also
assure that they are tested in accordance with the UN Model Regulations,
Manual of Test and Criteria. Part III, subsection 38.3
Effective December 29, 2004, the DOT requires that the outside of each package
that contains primary lithium batteries, regardless of size or number of
batteries, be labeled with the following statement: "PRIMARY LITHIUM
BATTERIES-FORBIDDEN FOR TRANSPORT ABOARD PASSENGER AIRCRAFT". The labeling
requirement covers shipments via highway, rail, vessel or cargo-only aircraft
and covers all shipments inside, into or out of the US. The label must be in
contrasting color and the letters must be 12 mm (0.5 in) in height for
packages weighing more than 30 Kg and 6 mm (0.25 in) in height for packages
weighing less than 30 Kg.
If you plan on transporting any untested prototype battery packs contact your
Panasonic Sales Representative for regulatory information.
First Aid
If you get electrolyte in your eyes, flush with water for 15 minutes without
rubbing and immediately contact a physician. If you get electrolyte on your
skin wash the area immediately with soap and water. If irritation continues,
contact a physician. If a battery is ingested, call the National Capital
Poison Center (NCPC) at 202-625-3333 (Collect) or your local poison center
immediately.
General Recommendations
CAUTION: Risk of fire, explosion and burns. Do not recharge, crush, heat above
212F (100C) or incinerate.
Fire Safety
In case of fire, you can use a Class "D" fire extinguisher or other smothering
agent such as Lith-X, copper powder or dry sand. If you use water, use enough
to smother the fire. Using an insufficient amount of water will only make the
fire worse. Cooling the exterior of the batteries will help prevent rupturing.
Burning of these batteries will generate toxic and corrosive lithium hydroxide
fumes. Fire fighters should use self-contained breathing apparatus.
Notice: The information and recommendations set forth are made in good faith
and are believed to be accurate at the date of preparation. Panasonic
Industrial Company makes no warranty expressed or implied.
The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance. For more product information by email, click here Imperial Supplies LLC does not provide services and products outside the United States |