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MSDS 5266 5266: 9 Volt Lithium Ultra-Life Batt [1]MSDS Last updated: 01/04/2010
IMPERIAL SUPPLIES LLC MSDS SHEET FOR 5266
SECTION I - PRODUCT AND COMPANY IDENTIFICATION
Product Description 9V Lithium Manganese Dioxide Batteries (Lectro Style)
Product
Identification
Manufacturer Ultralife Corporation 24 Hour ChemTrec
Name/Address Emergency 800-424-9300 (US)
2000 Technology Contact 703-527-3887
Parkway (International)
Newark, NY 14513
Technical Contact 800-332-5000 Issue Date 03 NOV 99
Prepared By John Diggory Revision Date:
Section II - HAZARD IDENTIFICATION
Hazard This Ultralife battery product meets the definition of an
Classification article. Under the Globally Harmonized System of Classification
and Labeling of Chemicals (GHS), "Articles" as defined in the
Hazard Communication Standard (29 CFR 1910.1200) of the
Occupational Safety and Health Administration of the United
States of America, or by similar definition, are outside the
scope of the system.
[Rev. 2 (2007) Part 1.3.2.1.1]
Hazard/Cauti Do not open or disassemble.
on Do not expose to fire or open flame.
Statements Do not mix with batteries of varying sizes, chemistries or
types.
Do not puncture, deform, incinerate or heat above 85oC (194 oF).
The materials contained in this product may only represent a hazard if the
integrity of the cell or battery is compromised; physically or electrically
abused.
SECTION III - COMPOSITION - INGREDIENTS/IDENTITY INFORMATION
Under normal use conditions, cells and batteries do not emit hazardous or
regulated substances.
Component CAS Number EINECS Number % by Wt.
Manganese Dioxide, MnO2 1313-13-9 215-202-6 35-40
Lithium Metal, Li 7439-93-2 231-102-5 1-4
Propylene Carbonate, C4H6O3 108-32-7 203-572-1 8-10
1,3 Dioxolane, C3H6O2 646-06-0 211-463-5 5-9
Lithium Hexafluoroarsenate, 29935-35-1 249-963-0 1-4
LiAsF6
Depending on product configuration, components used to assemble battery packs
(e.g. housings, electronic components and wiring) may contain additional
hazardous materials.
SECTION VI - ACCIDENTAL RELEASE MEASURES
Inhalation Avoid inhaling any vented gases.
Remove to fresh air immediately.
If breathing is difficult, seek emergency medical attention.
Ingestion Consult a physician or local poison control center immediately
Skin Contact Exposure to materials from a ruptured or otherwise damaged
cell or battery may cause skin irritation.
Flush immediately with water and wash affected area with soap
and water.
Eye Contact Exposure to materials from a ruptured or otherwise damaged
cell or battery may cause eye irritation.
Flush immediately with copious amounts of water for at least
15 minutes; consult a physician immediately.
SECTION V - FIRE FIGHTING MEASURES
Extinguishing Copious amounts of cold water or water-based foam may be
Media used to cool burning cells or batteries. Do not use warm or
hot water.
A carbon dioxide (CO2) extinguisher is also effective.
For fires involving exposed, raw lithium metal
(characterized by deep red flames), use only metal (Class
D) fire extinguishers.
Special Fire Use a positive pressure self-contained breathing apparatus
Fighting (SCBA) if cells or batteries are involved in a fire.
Procedures Full fire fighting protective clothing is necessary.
During water application, caution is advised as burning
pieces of flammable particles may be ejected from the fire.
Unusual Fire and Cells or batteries that are damaged, opened or exposed to
Explosion Hazard excessive heat/fire may flame or leak potentially hazardous
organic vapors.
SECTION IV - FIRST AID MEASURES
In the event a cell or battery is crushed; releasing its contents, rubber
gloves must be used to handle all battery components.
Avoid inhalation of any vapors that may be emitted.
Damaged batteries that are not hot or burning should be placed in a sealed
plastic bag or container.
SECTION VII - HANDLING AND STORAGE
Precautions Batteries are not designed to be recharged. Charging a primary
for Safe cell or battery may result in electrolyte leakage and/or cause
Handling the cell or battery to flame.
Never disassemble a battery or bypass any safety device.
More than a momentary short circuit will generally reduce the
battery service life. Batteries with fuses will no longer be
functional after being shorted.
Extended short-circuiting creates high temperatures in the cell.
High temperatures can cause burns in skin or cause the cell to
flame.
Avoid reversing battery polarity within the battery assembly. To
do so may cause cell to flame or to leak.
Conditions Batteries should be separated from other materials and stored in
for Safe a non-combustible, well ventilated structure with sufficient
Storage and clearance between walls and battery stacks. Do not place
Incompatibil batteries near heating equipment, nor expose to direct sunlight
ity for long periods.
Do not store batteries above 85ºC (194ºF) or below 20ºC (-4ºF).
Store batteries in a cool (below 25°C (77ºF)), dry area that is
subject to little temperature change. Elevated temperatures can
result in reduced battery service life. Battery exposure to
temperatures in excess of 130°C (266ºF) will result in the
battery venting flammable liquid and gases.
Do not store batteries in a manner that allows terminals to short
circuit.
SECTION VIII: EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering Under conditions of normal use, batteries do not emit
Controls and hazardous or regulated substances.
Work Practices No engineering controls are required for handling batteries
that have not been damaged.
Personal Personal protective equipment for damaged batteries should
Protective include chemical resistant gloves and safety glasses.
Equipment In the event of a fire, SCBA should be worn along with
thermally protective outer garments.
SECTION IX. PHYSICAL AND CHEMICAL PROPERTIES
Appearance Rectangular UEL/LEL Not Applicable
pack
Odor None Vapor Pressure Not Applicable
Odor Threshold Not Applicable Vapor Density Not Applicable
pH Not Applicable Relative Density Not Available
Melting Point Not Available Solubility Not Applicable
Boiling Point Not Available Partition Coefficient Not Applicable
Flash Point Not Applicable Auto-ignition Not Available
Temperature
Evaporation Rate Not Applicable Decomposition Not Available
Temperature
Flammability Not Applicable Viscosity Not Applicable
SECTION X. STABILITY AND REACTIVITY
Stability Stable Hazardous Polymerization Will Not Occure
Conditions to Avoid It is not recommended that this product be stored above
85C (194F).
Hazardous Carbon Monoxide (CO), Hydrogen Fluoride (HF) and other
Decomposition VOC's
SECTION XI - TOXICOLOGICAL INFORMATION
No toxicological impacts are expected under normal use conditions.
The electrolytes contained in this cell or battery can irritate eyes with any
contact.
Prolonged contact of electrolytes with lung tissue, skin or mucous membranes
may cause irritation.
The electrolytes contained in this cell or battery contain inorganic arsenic
compounds. Detailed information regarding sensitization, carcinogenicity,
mutagenicity or reproductive toxicity related to internal cell or battery
components has not been included in this document.
Carcinogen References
National Toxicology Program (NTP): No
IARC Monographs: No
OSHA: See 29 CFR 1910.1018 - Inorganic Arsenic
California Proposition 65 Warning
Electrolytes contained in this cell or battery contain inorganic arsenic
compounds, chemicals known to the State of California to cause cancer.
SECTION XII - ECOLOGICAL INFORMATION
No ecological impacts expected under normal use conditions.
The electrolytes contained in this cell or battery contain inorganic arsenic
compounds which are very toxic to aquatic organisms; may cause long-term
damage in the environment.
Detailed information regarding the ecological impact of internal cell or
battery components has not been included in this document.
SECTION XIII. DISPOSAL CONSIDERATIONS
Do not dispose in fire. Battery disposal regulations vary on national,
state/provincial and local bases.
Disposal must be conducted in accordance with the applicable regulations.
These batteries contain recyclable materials and recycling is encouraged over
disposal.
SECTION XIV. TRANSPORTATION INFORMATION
Ultralife's lithium metal primary cells and batteries and lithium-ion cells
and batteries are classified and regulated as Class 9 dangerous goods (also
known as "hazardous materials" in the United States) by the
International Civil Aviation Organization (ICAO), International Air Transport
Association (IATA), International Maritime Organization (IMO) and many
government agencies such as the U.S. Department of Transportation (DOT). These
organizations and agencies publish regulations that contain detailed
packaging, marking, labeling, documentation, and training requirements that
must be followed when offering (shipping) Ultralife's cells and batteries for
transportation. However, small cells and batteries are not subject to certain
provisions of the regulations (e.g. Class 9 labeling and UN specification
packaging) if they meet specific requirements. The regulations are based on
the UN Recommendations on the Transport of Dangerous Goods Model Regulations
and the UN Manual of Tests and Criteria. These regulations also apply to
shipments of cells and batteries that are packed with or contained in
equipment. Failure to comply with these regulations can result in substantial
civil or criminal penalties.
The dangerous goods regulations require that each cell and battery design be
subject to tests contained in Section 38.3 of the UN Manual of Tests and
Criteria prior to being offered for transport.
Approved, production level cells and batteries manufactured and assembled by
Ultralife have been tested to Section 38.3 of the UN Manual of Tests and
Criteria and passed T1 through T8.
Batteries or battery packs constructed by other parties using Ultralife's
cells must be subjected to the tests contained in Section 38.3 of the UN
Manual of Tests and Criteria.
Important Note Regarding Prototype Cells and Batteries
As a member of PRBA (The Rechargeable Battery Association) Ultralife is
permitted to ship prototype cells and batteries as Class 9 hazardous
materials/dangerous goods in accordance with the requirements contained in
Approval #CA2003030003; provided by the US DOT Research and Special Programs
Administration. Recipients of these shipments are prohibited from reshipping
unless they are also PRBA members.
For more detailed information, refer to the Transportation Regulations Page on
Ultralife's website:
http://www.ultralifebatteries.com/engineers.php?ID=137
Air, Sea and Surface UN 3090, Lithium metal batteries
Classification
UN 3091, Lithium metal batteries, contained in
equipment
UN 3091, Lithium metal batteries, packed with
equipment
These cells and batteries must be identified as above on the Bill of Lading
(or other shipping documentation) and properly packaged with their terminals
protected from short circuit.
Air shipments of lithium metal cells and batteries must be packed and marked
according to IATA/ICAO
Packing Instruction 968 (batteries only); 969 (with equipment) or 970
(contained in equipment).
Sea shipments of lithium metal cells and batteries must be packed and marked
according to IMDG Packing Instruction P903.
Hazard Class 9 Packing Group II Tunnel Code E
Stowage A Marine No
Location Pollutant
SECTION XV. REGULATORY INFORMATION
US Hazard Communication Standard (29 CFR 1910.1200) Article
CERCLA SECTION 304 Hazardous Substances NA
EPCRA SECTION 302 Extremely Hazardous Substance NA
EPCRA SECTION 313 Toxic Release Inventory Yes
EPCRA SECTION 312 NA
Components Listed on US Toxic Substances Control Act Yes
(TSCA) Inventory
EU Registration, Evaluation, Authorisation and Restriction of Article
Chemicals (REACH)
European RoHS Directive 2002/95/EC Not
Applicable
European WEEE Directive 2002/96/EC See Note
Note: Applies to cells and batteries incorporated into
electrical and electronic equipment, when that equipment
becomes waste.
SECTION XVI. OTHER INFORMATION
If returning product to any division of Ultralife, consult the relevant
regulations regarding handling, packaging, labeling and transportation.
Disclaimer
The information contained herein is furnished without warranty of any kind.
Users should consider this data only as a supplement to other information
gathered by them and must make independent determinations of the suitability
and completeness of information from all sources to assure proper use and
disposal of these materials and the safety and health of employees and
customers.
The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance. For more product information by email, click here Imperial Supplies LLC does not provide services and products outside the United States |
