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MSDS 4635-4 4635-4: Degreaser 1 Gallon [6]4735: Degreaser 16 Oz Trigger [12] MSDS Last updated: 05/19/2005
MATERIAL SAFETY DATA SHEET
Imperial Degreaser
Flammability: 0
Instability: 0
Health: 2
Special: -
Printed: 05/10/2005
Revision: 02/19/2005
Supercedes Revision: 08/22/2000
Date Created; 06/03/1997
1. PRODUCT AND COMPANY IDENTIFICATION
Product Code: 710-1334-C
Product Name: Imperial Degreaser
Manufacturer Information
Company Name; Imperial Supplies LLC
789 Packer Drive
P.O. Box 11008
Green Bay, WI 54307-1008
Emergency Contact; Chem Tel (800)255-3924
Information: (800)558-2808
Chemical Family; Aqueous Cleaning Compound
2. HAZARDS IDENTIFICATION
Emergency Overview
Corrosive to eyes and skin. When ingested, it can cause burns, ulcerations or
perforation(in extreme cases). Concentration vapors cause respiratory tract
irritation, cough, discomfort and difficulty in breathing.
Route(s) of Entry: Inhalation? Yes Skin: Yes Eyes? Yes Ingestion? Yes
Health Hazards (Acute and Chronic)
EYES; Irritating or corrosive to eyes.
SKIN: Frequent or prolonged contact may irritate the skin and cause a skin
rash (dermatitis).
INGESTION: Can burn mouth, throat and stomach. Can cause ulcerations or
perforation.
INHALATION: Causes respiratory tract irritation, cough, discomfort and
difficulty in breathing.
Signs and Symptoms of Exposure
EYES; Contact may result in severe eye irritation and damage.
INGESTION; May result in severe irritation of the mouth, throat and stomach.
INHALATION; Vapors ay cause respiratory tract irritation, cough, discomfort
and difficulty in breathing.
SKIN: May be irritating to skin upon prolonged or repeated contact.
Medical conditions Generally Aggravated By Exposure
Respiratory tract irritation, dermatitis, nausea and vomiting.
OSHA Hazard Classes:
HEALTH HAZARDS; Irritant, Corrosive
PHYSICAL HAZARDS; No Physical Hazards
TARGET ORGANS & EFFECTS: Eyes, Skin, Mucous Membranes, Respiratory
System.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Components CAS # Percentage RTECS #
(Chemical Name)
--------------------------------------------------------------------------------
1. Silica acid (H2S1O3), 6834-92-0 1.0 - 5.0 % W9275000
Disodium salt
2. ®-1-Methyl-4- 5989-27-5 1.0 - 5.0 % GW6360000
(1-methylethanyl)-cyclohexene
3. Sulfuric acid, mono 128-92-1 1.0 - 5.0 % MP0700000
(2-ethylhexyl) ester, sodium salt
4. alcohol ethoxylate 68439-46-3 1.0 - 5.0 % AZ8100000
4. FIRST AID MEASURES
Emergency and First Aid Procedures
SKIN: Wash with soap and water.
EYES: Flush eyes with water for at least 15 minutes. Call a physician.
INHALATION; If inhaled, remove from exposure.
INGESTION; Do not induce vomiting. Give milk or water. Get immediate
medical attention. Careful evacuation of stomach by medical personnel
imperative.
5. FIRE FIGHTING MEASURES
Flash Pt: N.A.
Explosive Limits: LEL: No data. UEL: No data.
Auto ignition Pt. No data.
Special Fire Fighting Procedures
As in any fire, wear self-contained breathing apparatus pressure-demand,
MSHA/NIOSH approved or equivalent and full protective gear.
Unusual Fire and Explosion Hazards
No data available.
Suitable Extinguishing Media
Dry Chemicals, CO2 or foam.
Unsuitable Extinguishing Media
No data available.
6. ACCIDENTAL RELEASE MEASURES
Steps To Be Taken In Case Material Is Released Or Spilled
Absorb spill with inert material (e.g. dry sand or earth), then place in a
chemical waste container. Avoid runoff into storm sewers and ditches which
lead to waterways.
7. HANDLING AND STORAGE
Hazard Label Information:
Avoid contact with skin and eyes. Corrosive to eyes and skin. CAUTION!
Keep out of reach of children.
Precautions To Be Taken In Handling
Avoid contact with eyes, skin, and clothing. Corrosive to eyes and skin.
Check container for leaks.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Hazardous Components CAS # OSHA PEL ACGIH TLV Other Limits
(Chemical Name)
--------------------------------------------------------------------------------
1.Silica acid (H2S1O3),6834-92-0 5mg/m3 5mg/m3 5mg/m3
Disodium salt
2.®,1-Methyl-4- 5989-27-5 NO DATA No data No data
(methylethenyl)-cyclohexene
3.Sulfuric acid, mono 126-92-1 No data. No data. No data
(2-ethylhexyl) ester, sodium salt.
4.Alcohol ethoxylate 68439-46-3 No data. No data. No data.
Protective Equipment Summary - Hazard Label Information:
Chemical safety goggles Latex gloves
Respiratory Equipment (Specify Type)
None should be needed under normal use. If exposure limits are exceeded, use a
NIOSH/MSHA approved respirator.
Eye Protection
Chemical safety goggles.
Protective Gloves
Latex gloves.
Other Protective Clothing
Boots, apron, or coveralls as necessary to prevent skin contact.
Ventilation
Good general ventilation should be sufficient to control levels.
Work/Hygienic/Maintenance Practices
Launder clothes before reuse. Do not smoke while using. Wash hands after use.
Use good personal hygiene at all times.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical States: [ ] Gas [X] Liquid [ ] Solid
Melting Point: No data.
Boiling Point; 212.00 F (100.0 C)
Auto ignition Pt: No data.
Flash Pt: N.A. Method:
Explosive Limits: LEL: No data. UEL: No data.
Specific Gravity (Water = 1); 1.01 - 1.03 at 20.0 C (68.0 F)
Vapor Pressure (vs. Air or mm Hg): No data.
Vapor Density (vs. Air = 1): No data.
Evaporation Rate (vs Butyl No data.
Acetate=1);
Solubility in Water: complete at 20.0 C (68.0 F)
Percent Volatile: No data.
VOC/ Volume: 4.0000 WT %
Viscosity: as water at 20.0 C (68.0 F)
Corrosion Rate: No data.
pH; 12.5
Appearance and Odor
Clear yellow with a citrus odor.
10. STABILITY AND REACTIVITY
Stability: Unstable [ ] Stable [X]
Conditions To Avoid: Instability
None known.
Incompatibility - Materials to Avoid
None known.
Hazardous Decomposition Or Byproducts
None known.
Possibility of Hazardous Reactions; Will occur [ ] Will not occur [X]
Conditions To Avoid - Hazardous Reactions
None known.
11. TOXICOLOGICAL INFORMATION
Toxicological Information
No data available.
Carcinogenicity/Other Information
No data available.
Carcinogenicity: NTP? No IARC Monographs? No OSHA Regulated? No
12. ECOLOGICAL INFORMATION
Ecological Information
No data available.
13. DISPOSAL CONSIDERATIONS
Waste /Disposal Method
All notification, clean up and disposal should be carried out in accordance
with federal, state and local regulations.
14. TRANSPORT INFORMATION
LAND TRANSPORT (US DOT)
DOT Proper Shipping Name
Corrosive Liquids, NOS (SODIUM METASILICATE), 8, UN1760,PGIII.
DOT Hazard Class; 8
DOT Hazard Label: Corrosive Liquids
UN/NA Number; UN1760
DOT Packing Group: III
Additional Transport Information
IATA: Corrosive Liquids, NOS (SODIUM METASILICATE), 8,UN1760,PG III.
IMDG; Corrosive Liquids, NOS (SODIUM METASILICATE),8,UN1760PG III
DOT Hazard determination may be reclassed according to 49 CFR 173.154.
15. REGULATORY INFORMATION
US EPA SARA Title III
Hazardous Components CAS # Sec. 302 Sec. 304 Sec. 313 Sec.110
(Chemical Name) (EHS) RQ (TRI)
--------------------------------------------------------------------------------
1. Silica acid (H28103).6834-92-0 No No No No
Disodium salt
2. ®- 1-Methyl-4 5989-27-5 No No No No
(1-methylethanyl)-cyclohexane
3. Sulfuric acid, mono 126-92-1 No No No No
(2-ethylhexyl) ester, sodium salt
4. Alcohol ethoxylate 68439-46-3 No No No No
US EPA CAA, CWA, TSCA
Hazardous Components CAS # EPA CAA EPA CWA EPA CA PROP
(Chemical Name) NPDES TSCA 65
--------------------------------------------------------------------------------
1. Silica acid (H291O3)6834-92-0 No No No No
Disodium salt
2. ®-1-Methyl-4- 5989-27-5 No No No No
(1-methylethanyl)-cyclohexene
3. Sulfuric acid, mono 126-92-1 No No No No
(2-ethylhexyl) ester, sodium salt
4. Alcohol ethoxylate 68439-46-3 No No No No
SARA (Superfund Amendments and Reauthorization Act of 1986) Lists:
Sec. 302: EPA SARA Title III Section 302 Extremely Hazardous Chemical with
TPQ.
* indicates 10000 LB TPQ if not volatile.
Sec. 304: EPA SARA Title Section 304: CERCLA Reportable + Sec. 302 with
Reportable Quantity.
** indicates statutory RQ.
Sec. 313: EPA SARA Title III Section 313Toxic Release Inventory. Note: -Cat
indicates a member of a chemical category.
Sec. 110: EPA SARA 110 Superfund site Priority Contaminant List
TSCA (Toxic Substances Control Act) Lists:
5A (2): Chemical Subject to Significant New Rules (SNURS)
6A: Commercial Chemical Control Rules
8A; Toxic Substances Subject To Information Rules on Production
8A CAIR: Comprehensive Assessment Information Rules - (CAIR)
8A PAIR: Preliminary Assessment Information Rules - (PAIR)
8C: Records of Allegations of Significant Adverse Reactions
8D: Health and Safety Data Reporting Rules
8D TERM: Health and Safety Rata Reporting Rule Terminations
Other Important Lists;
CWA NPDES: EPA Clean Water Act NPDES Permit Chemical.
CAA HAP: EPA Clean Air Act Hazardous Air Pollutant.
CAA ODC: EPA Clean Air Act Ozone Depleting Chemical (1=CFC,2=HCFC)
CA PROP 65: California Proposition 65
Regulatory Information
New Jersey Right-To-Know: Water, 7732-18-5: Sodium Met silicate
6834-92-0: Sodium 2-ethylhexyl Sulfate 126-92-1: Surfactant, CAS #
T.S.: Sulfur-Containing Poly alkylene Oxide, CAS # T.S.
Prop 65: Warning: This product contains a chemical(s) known to the State of
California to cause cancer and birth defects or other reproductive harm.
EPA Hazard Categories:
This material meets the EPA 'Hazard Categories' defined for SARA Title III
Sections 311/312 as indicated:
[X] Yes [ ] No Acute (immediate) Health Hazard
[ ] Yes [X] No Chronic (delayed) Health Hazard
[ ] Yes [X] No Fire Hazard
[ ] Yes [X] No Reactive Hazard
[ ] Yes [X] No Sudden Release of Pressure Hazard
Regulatory Information Statement
The information contained herein is based on data considered accurate.
However, no warranty is expressed or implied regarding the accuracy of
this data or the results to be obtained from the use thereof. Vendor assumes
no responsibility for injury to vendee or third person proximately caused
by the material if reasonable safety procedures are not adhered to as
stipulated in the data sheet. Additionally, vendor assumes no responsibility
for injury to vendee or third persons proximately caused by abnormal use of
the material even if reasonable safety procedures are followed. Furthermore,
vendee assumes all risk in use of the material.
16. OTHER INFORMATION
Company Policy or Disclaimer
THIS INFORMATION IS FURNISHED WITHOUT WARRANTY, EXPRESSED OR IMPLIED, EXCEPT
THAT IS ACCURATE TO THE BEST KNOWLEDGE OF EXCELDA MANUFACTURING. THE DATA ON
THIS SHEET RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED HEREIN.
EXCELDA MANUFACTURING ASSUMES NO LEGAL RESPONSIBILITY FOR USE OR RELIANCE UPON
THIS DATA.
Licensed to Excelda Manufacturing, Inc. ANSI Z400.1-2003
The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance. For more product information by email, click here Imperial Supplies LLC does not provide services and products outside the United States |