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MSDS 4605 4605: Bug & Tar Remover 1 Gallon [2]MSDS Last updated: 12/21/2009
IMPERIAL SUPPLIES LLC MSDS SHEET FOR 4605
M A T E R I A L S A F E T Y D A T A S H E E T
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME : 4605-0 GALLON BUG & TAR REMOVE
IDENTIFICATION NUMBER: 0147-113 DATE PRINTED: 08/06/09
PRODUCT USE/CLASS : BUG AND TAR
SUPPLIER/DISTRIBUTOR
MANUFACTURED BY:
IMPERIAL SUPPLIES LLC
IMPERIAL SUPPLIES LLC
789 ARMED FORCES DRIVE
789 ARMED FORCES DRIVE
GREEN BAY, WI 54304
GREEN BAY, WI 54304
INFORMATION#: 800-558-2808
INFORMATION#: 800-558-2808
EMERGENCY#: 800-255-3924
EMERGENCY#: 800-255-3924
CHEM-TEL
CHEM-TEL
PREPARER: CUSTOMER SERVICE, PHONE: , PREPARE DATE: 08/06/09
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
ITEM CHEMICAL NAME CAS NUMBER WEIGHT %
01 PETROLEUM HYDROCARBON MIXTURE 64741-65-7 1-10
02 D-LIMONENE 5989-27-5 1-10
03 KEROSENE 8008-20-6 1-10
04 TOLUENE 108-88-3 1-10
05 ORGANOPHILIC CLAY PROPRIETARY 1-10
EXPOSURE LIMITS
ACGIH OSHA COMPANY
ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILIN TLV-TWA SKIN
G
01 300 PPM N.E. 300 PPM N.E. 300 PPM NO
02 N.E. N.E. N.E. N.E. N.E. NO
03 400 PPM N.E. 400 PPM N.E. N.E. NO
04 20 PPM 200 PPM 300 PPM N.E. NO
05 10 MG/M3 N.E. 10 MG/M3 N.E. N.E. NO
(See Section 16 for abbreviation legend)
SECTION 3 - HAZARDS IDENTIFICATION
*** EMERGENCY OVERVIEW ***: Vapors irritating to eyes and respiratory tract.
High vapor concentrations may cause drowsiness.
EFFECTS OF OVEREXPOSURE - Liquid, aerosols and vapors of this product are
EYE CONTACT: irritating and can cause pain, tearing, reddening
and swelling accompanied by a stinging sensation
and/or a feeling like that of fine dust in the
eyes.
EFFECTS OF OVEREXPOSURE - Prolonged or repeated contact can result in
SKIN CONTACT: defatting and drying of the skin which may result
in skin irritation and dermatitis (rash).
EFFECTS OF OVEREXPOSURE - Headaches, dizziness, nausea, decreased blood
INHALATION: pressure, changes in heart rate and cyanosis may
result from over-exposure to vapor or skin
exposure. Prolonged inhalation may be harmful.
EFFECTS OF OVEREXPOSURE - This material may be harmful or fatal if
INGESTION: swallowed.
EFFECTS OF OVEREXPOSURE - Overexposure may cause nervous system damage.
CHRONIC HAZARDS:
PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT INHALATION INGESTION EYE CONTACT
SECTION 4 - FIRST AID MEASURES
FIRST AID - EYE Immediately flush eyes with plenty of water. Get medical
CONTACT: attention, if irritation persists.
FIRST AID - SKIN Immediately flush skin with plenty of water. Remove
CONTACT: clothing. Get medical attention immediately. Wash
clothing separately before reuse.
FIRST AID - Remove to fresh air. If not breathing, give artificial
INHALATION: respiration. If breathing is difficult, give oxygen. Get
immediate medical attention.
FIRST AID - Get medical attention immediately. If swallowed, do NOT
INGESTION: induce vomiting. Give victim a glass of water or milk.
Call a physician or poison control center immediately.
Never give anything by mouth to an unconscious person.
SECTION 5 - FIRE FIGHTING MEASURES
FLASH POINT: 250 F LOWER EXPLOSIVE LIMIT: 0.6 %
UPPER EXPLOSIVE LIMIT: 8.0 %
AUTOIGNITION TEMPERATURE: N.D.
EXTINGUISHING MEDIA: CO2 DRY CHEMICAL FOAM WATER FOG
UNUSUAL FIRE AND "Empty" containers retain product residue (liquid
EXPLOSION HAZARDS: and/or vapor) and can be dangerous. DO NOT
PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND,
OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS,
STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION;
THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Empty
drums should be completely drained, properly bunged
and promptly returned to a drum reconditioner, or
properly disposed of.
SPECIAL FIREFIGHTING Containers can build up pressure if exposed to heat
PROCEDURES: (fire). As in any fire, wear self-contained breathing
apparatus pressure-demand (MSHA/NIOSH approved or
equivalent) and full protective gear.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE Absorb spill with inert material (e.g. dry sand or
MATERIAL IS RELEASED OR earth), then place in a chemical waste container.
SPILLED: Avoid runoff into storm sewers and ditches which
lead to waterways.
SECTION 7 - HANDLING AND STORAGE
AEROSOL LEVEL: N/A
HANDLING: Wash thoroughly after handling.
STORAGE: Keep away from heat, sparks and flame. Keep from freezing.
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: Local exhaust ventilation may be necessary to
control any air contaminants to within their TLVs
during the use of this product.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA
1910.134 and ANSI Z88.2 requirements must be
followed whenever workplace conditions warrant a
respirator's use.
SKIN PROTECTION: No Information.
EYE PROTECTION: Wear safety glasses with side shields (or goggles)
and a face shield.
OTHER PROTECTIVE STANDARD INDUSTRIAL CLOTHING STANDARDS SHOULD BE
EQUIPMENT: FOLLOWED.
HYGIENIC PRACTICES: Wash hands before eating. Remove contaminated
clothing and wash before reuse. Use only in a well
ventilated area. Follow all MSDS/label precautions
even after container is emptied because they may
retain product residues. Avoid prolonged or
repeated contact with skin. Avoid breathing vapors
from heated material. Avoid contact with eyes,
skin, and clothing.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
BOILING RANGE : 228 - 522 VAPOR DENSITY : Is heavier than air
F
ODOR : MILD ODOR THRESHOLD : N.D.
APPEARANCE : CLEAR EVAPORATION RATE: Is faster than Butyl Acetate
SOLUBILITY IN H2O : MISCIBLE
FREEZE POINT : N.D. SPECIFIC GRAVITY: 0.9416
VAPOR PRESSURE : N.D. pH @ 0.0 % : N.A.
PHYSICAL STATE : LIQUID VISCOSITY : N.D.
COEFFICIENT OF WATER/OIL DISTRIBUTION: N.D.
VOLATILE ORGANIC COMPOUNDS (VOCS): 2.15 lbs/gal, 258 grams/ltr
VOC, % (wt): 27.34%
(See Section 16 for abbreviation legend)
SECTION 10 - STABILITY AND REACTIVITY
CONDITIONS TO AVOID: ALL SOURCES OF IGNITION, WELDING ARCS, AND OPEN
FLAMES.
INCOMPATIBILITY: STRONG ACIDS, ALKALIS, OXIDIZERS, AND AMINES.
HAZARDOUS DECOMPOSITION OXIDES OF CARBON, OXIDES OF NITROGEN, AND MAY
PRODUCTS: PRODUCE FORMS OF CHLORIDE, CHLORINE, AND
PHOSGENE.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage
conditions.
SECTION 11 - TOXICOLOGICAL PROPERTIES
PRODUCT LD50: 10097 mg/kg PRODUCT LC50: 5000 ppm
COMPONENT TOXICOLOGICAL INFORMATION:
CHEMICAL NAME LD50 LC50
PETROLEUM HYDROCARBON MIXTURE >10000 MG/KG no data
D-LIMONENE 4400 MG/KG RAT NE
KEROSENE >5000 MG/KG/RAT >5000 MG/M3/4H/RAT
TOLUENE 636 MG/KG/RAT 49000 MG/M3/4H/RAT
SORBITAN MONOOLEATE 40000 MG/KG RAT NE
ORGANOPHILIC CLAY 20000 MG/KG/RAT NE
SECTION 12 - ECOLOGICAL
ECOLOGICAL INFORMATION: No Information.
SECTION 13 - DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: DISPOSE IN ACCORDANCE WITH ALL FEDERAL, STATE, AND LOCAL
REGULATIONS.
SECTION 14 - TRANSPORTATION INFORMATION
DOT PROPER SHIPPING NAME: NOT REGULATED
DOT TECHNICAL NAME:
DOT HAZARD CLASS: HAZARD SUBCLASS:
DOT UN/NA NUMBER: PACKING GROUP: RESP. GUIDE PAGE:
DOT EXEMPTIONS:
DOT SPECIAL INSTRUCTIONS:
IMDG SHIPPING INFORMATION:
IMDG PROPER SHIPPING NAME: NOT REGULATED
IMDG TECHNICAL NAME:
IMDG HAZARD CLASS: HAZARD SUBCLASS:
PACKING GROUP: FLASH POINT, C:
IMDG EXEMPTIONS:
IMDG SPECIAL INSTRUCTIONS:
MARINE POLLUTANT (YES/NO):
IATA SHIPPING INFORMATION:
IATA PROPER SHIPPING NAME: NOT REGULATED
IATA TECHNICAL NAME:
IATA HAZARD CLASS: HAZARD SUBCLASS:
PACKING GROUP:
IATA EXEMPTIONS:
IATA SPECIAL INSTRUCTIONS:
SECTION 15 - REGULATORY INFORMATION
U.S. FEDERAL AS FOLLOWS -
REGULATIONS:
OSHA: Hazardous by definition of Hazard Communication
Standard (29 CFR 1910.1200)
CERCLA - SARA HAZARD CATEGORY:
This product has been reviewed according to the EPA 'Hazard Categories'
promulgated under Sections 311 and 312 of the Superfund Amendment and
Reauthorization Act of 1986 (SARA Title III) and is considered, under
applicable definitions, to meet the following categories:
IMMEDIATE HEALTH HAZARD CHRONIC HEALTH HAZARD FIRE HAZARD
SARA SECTION 313:
This product contains the following substances subject to the reporting
requirements of Section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 and 40 CFR Part 372:
CHEMICAL NAME CAS NUMBER WT/WT % IS LESS THAN
TOLUENE 108-88-3 1-10
TOXIC SUBSTANCES CONTROL ACT:
This product contains the following chemical substances subject to the
reporting requirements of TSCA 12(B) if exported from the United States:
CHEMICAL NAME CAS NUMBER
No information is available.
U.S. STATE REGULATIONS: AS FOLLOWS -
NEW JERSEY RIGHT-TO-KNOW:
The following materials are non-hazardous, but are among the top five
components in this product:
CHEMICAL NAME CAS NUMBER
WATER 7732-18-5
PENNSYLVANIA RIGHT-TO-KNOW:
The following non-hazardous ingredients are present in the product at greater
than 3%:
CHEMICAL NAME CAS NUMBER
WATER 7732-18-5
CALIFORNIA PROPOSITION 65:
WARNING: The chemical(s) noted below and contained in this product, are known
to the state of California to cause cancer, birth defects or other
reproductive harm:
CHEMICAL NAME CAS NUMBER
TOLUENE 108-88-3
ETHYLBENZENE 100-41-4
BENZENE 71-43-2
INTERNATIONAL REGULATIONS: AS FOLLOWS -
CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled
Product Regulations except for use of the 16 headings.
CANADIAN WHMIS CLASS: No information available
SECTION 16 - OTHER INFORMATION
HMIS RATINGS - 2 FLAMMABILITY 4 REACTIVITY: 0
HEALTH: :
PREVIOUS MSDS REVISION DATE: 08/06/09
REASON FOR REVISION: UPDATE PHYSICAL PROPERTIES AND TRANSPORTATION
LEGEND: N.A. - Not Applicable, N.E. - Not Established,
N.D. - Not Determined
*** THIS MSDS IS NOT FOR REPRODUCTION OR DISTRIBUTION ***
The information contained on this MSDS has been checked and should be accurate.
However, it is the responsibility of the user to comply with all Federal,
State, and Local laws and regulations.
The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance. For more product information by email, click here Imperial Supplies LLC does not provide services and products outside the United States |
