MSDS Sheet 4600-4

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MATERIAL SAFETY DATA SHEET PENETRATING AND LOCK LUBRICANT <50% Flammability 2 Instability 0 Health 1 Special - Printed: 02/21/2005 Revision: 02/21/2005 Supercedes Revision: 04/02/2003 Date Created: 04/02/2003 1. PRODUCT AND COMPANY IDENTIFICATION Product Code: 4600-4 & 4700 Product Name: PENETRATING AND LOCK LUBRICANT <50% Reference #: LIQUID VERSION Manufacturer Information Company Name: Imperial Supplies LLC 789 Packer Drive P.O. Box 11008 Green Bay, WI 54307-1008 Emergency Contact: Chem Tel (800) 255-3924 Information: (800) 558-2808 2. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Components CAS# Percentage OSHA ACGIH Other Limits (Chemical Name) PEL TLV -------------------------------------------------------------------------------- 1. OMS Naptha 64742-48-9 30.0-40.0% No data No data. 300 PPM 2. Hydrotreated light 64742-47-8 40.0-50.0% No data No data No data distillate (petroleum) Hazardous Components RTECS # OSHA OSHA ACGIH ACGIH (Chemical Name) STEL CEIL STEL CEIL -------------------------------------------------------------------------------- 1. OMS Naptha NA No data. No data No data No data 2. Hydrotreated light OA5504000 No data No data No data No data distillate (petroleum) 3. HAZARDS IDENTIFICATION Emergency Overview HEALTH HAZARD; A component is harmful, or fatal, if swallowed. Aspiration hazard. May cause severe skin irritation after prolonged or repeated contact. A component may cause allergic skin reaction. Causes eye irritation. Use ventilation adequate to keep exposures below recommended exposure limits. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated contact with skin. Do not taste or swallow. Wash thoroughly after handling. PHYSICAL HAZARD; Combustible liquid and vapor. Keep away from heat, sparks, flames, or other sources of ignition. Keep containers tightly closed. Route(s) of Entry: Inhalation? Yes Skin? Yes Eyes? Yes Ingestion? Yes Potential Health Effects (Acute and Chronic) EYE: Eye Irritant. Contact may cause stinging, watering, redness, and swelling. SKIN: Skin Irritant. Contact may cause redness and burning of the skin. Prolonged or repeated contact may cause drying and cracking of the skin and severe skin damage. No harmful effects from skin absorption have been reported. INHALATION; No information available. Studies by other exposure routes suggest a low degree of toxicity. INGESTION; A component of this material is toxic. May be harmful, or fatal, if swallowed. Aspiration Hazard- This material can enter lungs during swallowing or vomiting and cause lung inflammation and damage. Signs and symptoms of Exposure Effects of overexposure may include irritation of the nose and throat, irritation of the digestive tract, headaches, nausea, vomiting, diarrhea, signs of nervous system depression, abdominal pain, an allergic skin reaction through repeated contact, pneumonitis, blood disorders, and jaundice. Medical Conditions Generally Aggravated By Exposure. Skin disorders, blood disorders and liver disorders. OSHA Hazard Classes: HEALTH HAZARDS; Irritant PHYSICAL HAZARDS; Combustible Liquid TARGET ORGANS & EFFECTS: Lungs, Eyes, Skin, Central Nervous System, Respiratory System, Blood 4. FIRST AID MEASURES Emergency and First Aid Procedures EYES: Move victim away from exposure and into fresh air. If irritation or redness develops, flush eyes with clean water and seek medical attention. For direct contact, hold eyelids apart and flush the affected eye(s) with clean water for at least 15 minutes. Seek medical attention. SKIN: Remove contaminated shoes and clothing, and flush affected area(s) with large amounts of water. If skin surface is damaged, apply a clean dressing and seek medical attention. If skin surface is not damaged, cleanse affected area thoroughly by washing with mild soap and water. If irritation or redness develops, seek medical attention. INHALATION: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, seek medical attention. If victim is not breathing immediately begin artificial respiration. If breathing difficulties develop, oxygen should be administered by qualified personnel. Seek immediate medical attention. INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. If victim is drowsy or unconscious, place on the left side with the head down. If possible, do not leave victim unattended. Seek medical attention. Note to Physician IF AN ALLERGIC REACTION TO THIS MATERIAL DEVELOPS, AVOID ANY FURTHER CONTACT. 5. FIRE FIGHTING MEASURES Flash Pt: 140.00 F (60.0 C) Method Used: PMCC Explosive Limits: LEL: 0.9 UEL: 8.0 Autoignition Pt: N.A. Fire Fighting Instructions Emergency responders in the danger area should wear bunker gear and self-contained breathing apparatus for fires beyond the incipient stage. In addition, wear other appropriate protective equipment as conditions warrant. Isolate damage area, keep unauthorized personnel out. Stop spill/release if it can be done with minimal risk. Move undamaged containers from danger area if it can be done with minimal risk. Water spray may be useful in minimizing or dispersing vapors. Cool equipment exposed to fire with water, if it can be done with minimal risk. Avoid spreading burning liquid with water used for cooling purposes. Flammable Properties and Hazards Combustible liquid and vapor. Combustible components will float on water creating a floating fire hazard. Hazardous Combustion Products Oxides of carbon, primarily carbon dioxide, carbon monoxide, and incompletely combusted hydrocarbons. Extinguishing Media Foam, CO2, Dry chemical or halon is recommended. Use water spray to cool fire exposed surfaces and to protect personnel. Water may be ineffective for extinguishment, unless under favorable conditions by experienced fire fighters. Halon may decompose into toxic material. Carbon dioxide can displace oxygen. Use caution when applying halon or carbon dioxide in confined spaces. Unsuitable Extinguishing Media No data available. 6. ACCIDENTAL RELEASE MEASURES Steps To Be Taken In Case Material Is Released Or Spilled Keep all sources of ignition and hot metal surfaces away from spill/release. Use explosion proof equipment. Stay upwind and away from spill/release. Isolate danger area and keep unauthorized personnel out. Stop spill/release if it can be done with minimal risk. Wear appropriate protective equipment including respiratory protection as conditions warrant. Prevent spilled material from entering sewers, storm drains, other unauthorized treatment drainage systems, and natural waterways. Dike far ahead of spill for later recovery or disposal. Use foam on spills to minimize vapors. Spilled material may be absorbed into an appropriate absorbent material. Notify fire authorities and appropriate federal, state, and local agencies. Immediate cleanup of any spill is recommended. If spill of any amount is made into or upon navigable waters, the contiguous zone, or adjoining shorelines, notify the National Response Center (800)-424-8802). 7. HANDLING AND STORAGE Hazard Label Information: Keep containers closed when not using. Store in a cool dry place. Keep away from heat, sparks, flame. Store away from incompatible material. Precautions to Be Taken in Handling Open container slowly to relieve any pressure. Bond and ground all equipment when transferring from one vessel to another. Can accumulate static charge by flow or agitation. Vapor can be ignited by static discharge. The use of explosion-proof equipment is recommended and may be required. Do not enter confined spaces such as tanks or pits without following proper entry procedures such as ASTMD-4276 and 29CFR 1910.146. The use of respiratory protection is advised when concentrations exceed any established exposure limits. Wash thoroughly after handling. Do not wear contaminated clothing or shoes. Use good personal hygiene practice. Empty containers retain residue (liquid and/or vapor) and may be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, or other sources of ignition. They may explode and cause injury or death. Empty drums should be completely drained properly bunged, and promptly shipped to the supplier or a drum reconditioner. All containers should be disposed of in an environmentally safe manner and in accordance with governmental regulations. Before working on or in tanks which contain or have contained this material, refer to Occupational Safety and Health Administration Regulations, ANSI Z49.1 and other governmental and industrial references pertaining to cleaning, repairing, welding, or other contemplated operations. Keep containers tightly closed. Use and store this material in cool, dry, well-ventilated areas away from heat, direct sunlight, hot metal surfaces, and all sources of ignition. Post are "NO Smoking or Open Flame." Store only in approved containers. Keep away from any incompatible material. Protect container against physical damage. Outdoor or detached storage is preferred. Indoor storage should meet OSHA standards and appropriate fire codes. Precautions To Be Taken in Storing Store in well ventilated area away from sources of heat, sparks and open flame. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Protective Equipment Summary - Hazard Label Information: Chemical resistant gloves. Chemical safety goggles Eye was station in work area. Clothes to prevent skin contact. ANSI approved respirator. Respiratory Equipment (Specify Type). The use of respiratory protection is advised when concentrations are expected to exceed the established exposure limits. Depending on the airborne concentration, use a respirator with appropriate cartridges or supplied-air equipment. Eye Protection Approved eye protection to safeguard against potential eye contact, irritation, or injury is recommended. Protective Gloves Impervious gloves. Other Protective Clothing Eye wash and quick drench shower facilities should be available in the work area. Thoroughly clean shoes and wash contaminated clothing before reuse. It is recommended that impervious clothing be worn. Engineering Controls (Ventilation etc.) If current ventilation practices are not adequate to maintain airborne concentrations below the established exposure limits, additional ventilation or exhaust systems may be required. Where explosive mixtures may be present,electrical systems safe for such locations must be used. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical States: { } Gas {X} Liquid { } Solid Melting Point; No data. Boiling Point: 0.00 F (-17.8 C) Autoignition Pt: N.A. Flash Pt: 140.00 F (60.0 C) Method: PMCC Explosive Limits: LEL: 0.9 UEL: 8.0 Specific Gravity (Water = 1): 0.79 - 8.5 Vapor Pressure (vs. Air or mm Hg): No data. Vapor Density (vs. Air = 1): No data. Evaporation Rate (vs Butyl Acetate = 1): No data. Solubility in Water: No data. Percent Volatile: No data. VOC / Volume: 37.0000 WT % Corrosion Rate: No data. Formula: N/AV pH; No data. Appearance and Odor: Thin, light amber colored liquid: characteristic vanilla odor. 10. STABILITY AND REACTIVITY Stability: Unstable { } Stable {X} Conditions to Avoid: - Instability Stable under normal conditions of storage and handling. Flammable liquid and vapor. Vapor can cause flash fire. Incompatibility - Materials To Avoid Avoid contact with strong oxidizing agents. Hazardous Decomposition Or Byproducts Combustion can yield major amounts of oxides of carbon and minor amounts of oxides of sulfur and nitrogen. Hazardous Polymerization: Will occur { } Will not occur {X} Conditions To Avoid - Hazardous Polymerization None known. 11. TOXICOLOGICAL INFORMATION Toxicological Information See Carcinogenity section. Target Organs: Ingestion of naphthalene has caused hemolysis in humans deficient in glucose-6-phosphate dehydrogenase. Limited evidence of cataract formation and liver damage has been reported in laboratory animals. Carcinogenicity/Other Information None Carcinogenicity: NTP? No IARC Monograhs? No OSHA Regualted? No 12. ECOLOGICAL INFORMATION Ecological Information Not available 13. DISPOSAL CONSIDERATIONS Waste Disposal Method Dispose of in accordance with federal, state and local regulations. 14. TRANSPORT INFORMATION LAND TRANSPORT (US DOT) DOT Proper Shipping Name Flammable liquids, n.o.s. (mineral spirits) DOT Hazard Class; 3 DOT Hazard Label: FLAMMABLE LIQUID UN/NA Number: UN1993 DOT Packing Group; III Additional Transport Information IMDG: Flammable liquids, n.o.s. (mineral spirits), 3, UN1993, PG III IATA: Flammable liquids, n.o.s. (mineral spirits), 3, UN1993, PG III DOT Hazard determination may be reclassed according to 49 CFR 173.150. 15. REGULATORY INFORMATION US EPA SARA Title III Hazardous Components CAS # Sec.302(EHS) Sec.304 RQ Sec.313(TRI) Sec.110 (Chemical Name) -------------------------------------------------------------------------------- 1.OMS Naptha 64742-48-9 No No No No 2.Hydrotreated light 64742-47-8 No No No No distillate (petroleum) US EPA CAA, CWA, TSCA Hazardous Components CAS EPA CAA EPA CWA EPA TSCA CA PROP65 (Chemical Name) NPDES -------------------------------------------------------------------------------- 1. OMS Naptha 64742-48-9 No No No No 2. Hydrotreated light 64742-47-8 No No No No distillate(petroleum) SARA (Superfund Amendments and Reauthorization Act of 1986) Lists: Sec. 302: EPA SARA Title III Section 302 Extremely Hazardous Chemical with TPQ. * indicates 10000 LB TPQ if not volatile. Sec. 304: EPA SARA Title III Section 304: CERCLA Reportable + sec. 302 with Reportable Quantity. ** indicates statutory RQ. Sec. 313: EPA SARA Title III Section 313 Toxic Release Inventory. Note: - Cat indicates a member of a chemical category. Sec. 110: EPA SARA 110 Superfund Site Priority Contaminant List TSCA (Toxic Substances Control Act) Lists: 5A (2): Chemical Subject to Significant New Rules (SNURS) 6A: Commercial Chemical Control Rules 8A: Toxic Substances Subject To Information Rules on Production. 8A CAIR: Comprehensive Assessment Information Rules - (CAIR) 8A PAIR: Preliminary Assessment Information Rules - (PAIR) 8C: Records of Allegations of Significant Adverse Reactions 8D: Health and Safety Data Reporting Rules 8D TERM: Health and Safety Data Reporting Rule Terminations Other Important Lists: CWA NPDES: EPA Clean Water Act NPDES Permit Chemical CAA HAP: EPA Clean air Act Hazardous Air Pollutant CAA ODC: EPA Clean air Act Ozone Depleting Chemical (1=CFC,2=HCFC) CA PROP 65: California Proposition 65 Regulatory Information This Material contains the following chemicals subject to the reporting requirements of SARA 313 and 40 CFR 372: Naphthalene (91-20-3) 0-1% Prop 65: This material is not known to contain any chemical known to the State of California to cause cancer, and birth defects or other reproductive harm. This material has not been identified as a carcinogen by NTP, IARC, or OSHA. For carcinogenity information on individual components see section 11. EPA Reportable Quantity: RQ #1 Naphthalene 100 lb equal to 10000 lb, (1482), of this material. EPA Hazard Categories This material meets the EPA 'Hazard Categories' defined for SARA Title III Sections 311/312 as indicated: {X} Yes { } No Acute (immediate) Health Hazard {X} Yes { } No Chronic (delayed) Health Hazard {X} Yes { } No Fire Hazard { } Yes {X} No Reactive Hazard { } Yes {X} No Sudden Release of Pressure Hazard Regulatory Information Statement The information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. Vendor assumes no responsibility for injury to vendee or third person proximately caused by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Additionally, vendor assumes no responsibility for injury to vendee or third persons proximately cased by abnormal use of the material even if reasonable safety procedures are followed. Furthermore, vendee assumes all risk in use of the material. 16. OTHER INFORMATION Additional Information About This Product THE INFORMATION CONTAINED HEREIN IS BELIEVED TO BE ACCURATE. IT IS PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT FOR PURPOSE OF HAZARD COMMUNICATION AS PART OF THE PRODUCT SAFETY PROGRAM. IT IS NOT INTENDED TO CONSTITUTE PERFORMANCE INFORMATION CONCERNING THE PRODUCT. NO EXPRESS WARRANTY, OR IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE IS MADE WITH RESPECT TO THE PRODUCT OR THE INFORMATION CONTAINED HEREIN. DATA SHEETS ARE AVAILABLE FOR ALL PRODUCTS. YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL PRODUCTS YOU BUY, PROCESS, USE OR DISTRIBUTE AND YOU ARE ENCOURAGED AND REQUESTED TO ADVISE THOSE WHO MAY COME IN CONTACT WITH SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN. TO DETERMINE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH RESPECT TO THE PRODUCT, USER SHOULD CONSULT HIS LEGAL ADVISOR OR THE APPROPRIATE GOVERNMENT AGENCY. WE WILL NOT UNDERTAKE TO FURNISH ADVICE ON SUCH MATTERS. Company Policy or Disclaimer THIS INFORMATION IS FURNISHED WITHOUT WARRANTY, EXPRESSED OR IMPLIED, EXCEPT THAT IS ACCURATE TO THE BEST KNOWLEDGE OF EXCELDA MANUFACTURING. THE DATA ON THIS SHEET RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED HEREIN. EXCELDA MANUFACTURING ASSUMES NO LEGAL RESPONSIBILITY FOR USE OR RELIANCE UPON THIS DATA. Licensed to Excelda Manufacturing, Inc. ANSI Z400.1 Format