MSDS Sheet 3813

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MSDS FOR; LN-601 REVISED; 07-JAN-2004 SECTION 1; -------------------------------------------------------------------------------- PRODUCT IDENTIFIER; LN-601 FOR PROJECTS & CONSTRUCTION DATE OF PREPARATION; JANUARY 7, 2004 PRODUCT USE; ADHESIVE MANUFACTURED BY: MACCO ADHESIVES 925 EUCLID AVENUE CLEVELAND, OHIO 44115,U.S.A. ICI PAINTS CANADA 8200 KEELE STREET CONCORD, ONTARIO L4K 2A5, CANADA EMERGENCY AND MSDS TELEPHONE NUMBER; 1-800-545-2643 MSDS PREPARED BY; PRODUCT SAFETY AND TOXICOLOGY DEPARTMENT ICI PAINTS NORTH AMERICA SECTION 2; COMPOSITION/INFORMATION ON INGREDIENTS -------------------------------------------------------------------------------- INGREDIENT WT% CHEMICAL NAME: 2-METHYLPENTANE 5-10 COMMON NAME; 2-METHYLPENTANE CAS NUMBER: 107-83-5 CHEMICAL NAME: LIMESTONE 20-30 COMMON NAME: LIMESTONE CAS NUMBER: 1317-65-3 CHEMICAL NAME; KAOLIN 20-30 COMMON NAME: CLAY CAS NUMBER: 1332-58-7 CHEMICAL NAME: QUARTZ .1-1.0 COMMON NAME; QUARTZ CAS NUMBER: 14808-60-7 CHEMICAL NAME; BENZENE, 1,3-DIETHENYL-, 1-5 POLYMER WITH 1,3-BUTADIENE AND ETHENYLBENZENE COMMON NAME: STYRENE-BUTADIENE POLYMER CAS NUMBER: 26471-45-4 CHEMICAL NAME: SOLVENT NAPHTHA (PETROLEUM), 10-20 LIGHT ALIPHATIC COMMON NAME: LIGHT ALIPHATIC SOLVENT NAPHTHA (PETROLEUM) CAS NUMBER: 64742-89-8 CHEMICAL NAME: DISTILLATES (PETROLEUM), STEAM- 10-20 CRACKED, POLYMERS WITH LIGHT STEAM-CRACKED PETROLEUM NAPHTHA COMMON NAME: AROMATIC HYDROCARBON RESIN CAS NUMBER: 68410-16-2 CHEMICAL NAME: 2,2-DIMETHYLBUTANE 1-5 COMMON NAME: DIMETHYLBUTANE CAS NUMBER: 75-83-2 CHEMICAL NAME: 2,3-DIMETHYLBUTANE 1-5 COMMON NAME: DIMETHYLBUTANE CAS NUMBER: 79-29-8 CHEMICAL NAME: BENZENE, ETHENYL-, POLYMER WITH 1-5 1,3-BUTADIENE COMMON NAME: STYRENE-BUTADIENE POLYMER CAS NUMBER: 9003-55-8 CHEMICAL NAME; 3-METHYLPENTANE 1-5 COMMON NAME: 3-METHYLPENTANE CAS NUMBER: 96-14-0 SECTION 3; HAZARDS IDENTIFICATION -------------------------------------------------------------------------------- PRIMARY ROUTE(S) OF EXPOSURE: INHALATION, SKIN CONTACT, EYE CONTACT, INGESTION. EFFECTS OF OVEREXPOSURE INHALATION: IRRITATION OF RESPIRATORY TRACT. PROLONGED INHALATION. MAY LEAD TO LOSS OF APPETITE, MUCOUS MEMBRANE IRRITATION, FATIGUE, DROWSINESS, DIZZINESS AND/OR LIGHTHEADEDNESS, HEADACHE, IN COORDINATION, NAUSEA, VOMITING, COUGHING, CENTRAL NERVOUS SYSTEM DEPRESSION, INTOXICATION, ANESTHETIC EFFECT OR NARCOSIS, DIFFICULTY OF BREATHING, CONVULSION, PNEUMOCONIOSIS, LOSS OF CONSCIOUSNESS, DEATH. SKIN CONTACT: IRRITATION OF SKIN. PROLONGED OR REPEATED CONTACT CAN CAUSE DERMATITIS, DEFATTING. EYE CONTACT: IRRITATION OF EYES. PROLONGED OR REPEATED CONTACT CAN CAUSE CONJUNCTIVITIS, BLURRED VISION, TEARING OF EYES, REDNESS OF EYES, SEVERE EYE IRRITATION. INGESTION: INGESTION MAY CAUSE LUNG INFLAMMATION AND DAMAGE DUE TO ASPIRATION OF MATERIAL INTO LUNGS, DROWSINESS, DIZZINESS AND/OR LIGHTHEADEDNESS, HEADACHE, IN COORDINATION, NAUSEA, VOMITING, DIARRHEA, GASTROINTESTINAL DISTURBANCES, ABDOMINAL PAIN, CENTRAL NERVOUS SYSTEM DEPRESSION, INTOXICATION, DIFFICULTY OF BREATHING, CONVULSIONS, PARALYSIS, CARDIAC FAILURE, DEATH. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE; EYE, SKIN, RESPIRATORY DISORDER, LUNG DISORDERS SECTION 4; FIRST-AID MEASURES -------------------------------------------------------------------------------- INHALATION: REMOVE TO FRESH AIR. RESTORE AND SUPPORT CONTINUED BREATHING. GET EMERGENCY MEDICAL ATTENTION. HAVE TRAINED PERSON GIVE OXYGEN IF NECESSARY. GET MEDICAL HELP FOR ANY BREATHING DIFFICULTY. SKIN CONTACT: WASH THOROUGHLY WITH SOAP AND WATER. IF ANY PRODUCT REMAINS, GENTLY RUB PETROLEUM JELLY, VEGETABLE OR MINERAL/ BABY OIL ONTO SKIN. REPEATED APPLICATIONS MAY BE NEEDED. REMOVE CONTAMINATED CLOTHING. WASH CONTAMINATED CLOTHING BEFORE RE-USE. EYE CONTACT: FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER, ESPECIALLY UNDER LIDS FOR AT LEAST 15 MINUTES. IF IRRITATION OR OTHER EFFECTS PERSIST, OBTAIN MEDICAL TREATMENT. INGESTION: IF SWALLOWED, OBTAIN MEDICAL TREATMENT IMMEDIATELY. SECTION 5; FIRE-FIGHTING MEASURES; -------------------------------------------------------------------------------- FLASH POINT (SET A): 4 F./ - 16 C. LOWER EXPLOSIVE LIMIT; 1.0 % UPPER EXPLOSIVE LIMIT; 7.0 % FIRE EXTINGUISHING MEDIA; DRY CHEMICAL FOAM, WATER FOG, CARBON DIOXIDE UNUSUAL FIRE AND EXPLOSION HAZARDS CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT OR FIRE. VAPORS MAY IGNITE EXPLOSIVELY AT AMBIENT TEMPERATURES. VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL LONG DISTANCES TO A SOURCE OF IGNITION AND FLASH BACK. VAPORS CAN FORM EXPLOSIVE MIXTURES IN AIR AT ELEVATED TEMPERATURES. CLOSED CONTAINERS MAY BURST IF EXPOSED TO EXTREME HEAT OR FIRE. MAY DECOMPOSE UNDER FIRE CONDITIONS EMITTING IRRITANT AND/OR TOXIC GASES. FIRE FIGHTING PROCEDURES WATER MAY BE USED TO COOL AND PROTECT EXPOSED CONTAINERS. FIREFIGHTERS SHOULD USE FULL PROTECTIVE CLOTHING, EYE PROTECTION, AND SELF-CONTAINED BREATHING APPARATUS. HAZARDOUS DECOMPOSITION OR COMBUSTION PRODUCTS CARBON MONOXIDE, CARBON DIOXIDE, TOXIC GASES. OXIDES OF CALCIUM. SECTION 6; ACCIDENTAL RELEASE MEASURES; -------------------------------------------------------------------------------- STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED. COMPLY WITH ALL APPLICABLE HEALTH AND ENVIRONMENTAL REGULATIONS. ELIMINATE ALL SOURCES OF IGNITION. VENTILATE AREA WITH EXPLOSION-PROOF EQUIPMENT. USE NON-SPARKING TOOLS. EVACUATE ALL UNNECESSARY PERSONNEL. PLACE COLLECTED MATERIAL IN PROPER CONTAINER. COMPLETE PERSONAL PROTECTIVE EQUIPMENT MUST BE USED DURING CLEANUP. LARGE SPILLS; SHUT OFF LEAK IF SAFE TO DO SO. DIKE AND CONTAIN SPILL. PUMP TO STORAGE OR SALVAGE VESSELS. USE ABSORBENT TO PICK UP EXCESS RESIDUE. KEEP SALVAGEABLE MATERIAL AND RINSE WATER OUT OF SEWERS AND WATER COURSES. SMALL SPILLS; USE ABSORBENT TO PICK UP RESIDUE AND DISPOSE OF PROPERLY. SECTION 7; HANDLING AND STORAGE; -------------------------------------------------------------------------------- STORE BELOW 80F. KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAME. OTHER PRECAUTIONS; USE ONLY WITH ADEQUATE VENTILATION. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. AVOID CONTACT WITH SKIN AND EYES, AND BREATHING OF VAPORS. WASH HANDS THOROUGHLY AFTER HANDLING, ESPECIALLY BEFORE EATING OR SMOKING. KEEP CONTAINERS TIGHTLY CLOSED AND UPRIGHT WHEN NOT IN USE. EMPTY CONTAINERS MAY CONTAIN HAZARDOUS RESIDUES. GROUND EQUIPMENT WHEN TRANSFERRING TO PREVENT ACCUMULATION OF STATIC CHARGE. SECTION 8; EXPOSURE CONTROLS/PERSON PROTECTION; -------------------------------------------------------------------------------- COMMON NAME; 2-METHYLPENTANE CAS NUMBER: 107-83-5 ACGIH (TWA): 500 PPM ACGIH (STEL): C 1000 PPM COMMON NAME: LIMESTONE CAS NUMBER: 1317-65-3 ACGIH (TWA): 10 MG/M3 OSHA (TWA): 5 MG/M3 COMMON NAME: CLAY CAS NUMBER: 1332-58-7 ACGIH (TWA); 2 MG/M3 OSHA (TWA): 5 MG/M3 COMMON NAME: QUARTZ CAS NUMBER; 14808-60-7 ACGIH (TWA): .05 MG/M3 OSHA (TWA): 0.1 MG/M3 COMMON NAME; LIGHT ALIPHATIC SOLVENT NAPHTHA (PETROLEUM) CAS NUMBER: 64742-89-8 OSHA (TWA): 300 PPM COMMON NAME: DIMETHYLBUTANE CAS NUMBER: 75-83-2 ACGIH (TWA); 500 PPM ACGIH (STEL): 1000 PPM COMMON NAME: DIMETHYLBUTANE CAS NUMBER: 79-29-8 ACGIH (TWA): 500 PPM ACGIH (STEL): 1000 PPM COMMON NAME: 3-METHYL PENTANE CAS NUMBER: 96-14-0 ACGIH (TWA): 500 PPM ACGIH (STEL): 1000 PPM RESPIRATORY PROTECTION CONTROL ENVIRONMENTAL CONCENTRATIONS BELOW APPLICABLE EXPOSURE STANDARDS WHEN USING THIS MATERIAL. WHEN RESPIRATORY PROTECTION IS DETERMINED TO BE NECESSARY, USE A NIOSH/MSHA (CANADIAN Z94.4) APPROVED ELASTOMERIC SEALING-SURFACE FACE PIECE RESPIRATORY OUTFITTED WITH ORGANIC VAPOR CARTRIDGES AND PAINT SPRAY (DUST/MIST) PREFILTERS. DETERMINE THE PROPER LEVEL OF PROTECTION BY CONDUCTING APPROPRIATE AIR MONITORING. CONSULT 29CFR 1910.134 FOR SELECTION OF RESPIRATORS (CANADIAN Z94.4). VENTILATION; PROVIDE DILUTION VENTILATION OR LOCAL EXHAUST TO PREVENT BUILD-UP OF VAPORS. USE EXPLOSION-PROOF EQUIPMENT. USE NON-SPARKING EQUIPMENT. PERSONAL PROTECTIVE EQUIPMENT; EYE WASH, SAFETY SHOWER, SAFETY GLASSES OR GOGGLES. IMPERVIOUS GLOVES, IMPERVIOUS CLOTHING. SECTION 9; PHYSICAL AND CHEMICAL PROPERTIES; -------------------------------------------------------------------------------- VAPOR PRESSURE; NOT AVAILABLE BOILING RANGE (F/C): 122-185/50-85 % VOLATILE BY VOLUME; 57.74 APPEARANCE; TAN PH: NOT APPLICABLE SPECIFIC GRAVITY; 1.132 WEIGHT PER GALLON; 9.43/11.32IMP PHYSICAL STATE; PASTE SOLUBLE IN WATER; N SECTION 10; STABILITY AND REACTIVITY -------------------------------------------------------------------------------- UNDER NORMAL CONDITIONS; STABLE - STABLE- SEE SECTION 5 FIRE FIGHTING MEASURES MATERIAL TO AVOID; OXIDIZERS, ACIDS, STYRENE MONOMER. CONDITIONS TO AVOID; ELEVATED TEMPERATURES, CONTACT WITH OXIDIZING AGENT, SPARKS, OPEN FLAME, IGNITION SOURCES. HAZARDOUS POLYMERIZATION; WILL NOT OCCUR SECTION 11; TOXICOLOGICAL INFORMATION -------------------------------------------------------------------------------- COMMON NAME; 2-METHYLPENTANE CAS NUMBER; 107-83-5 CARCINOGENICITY LISTED BY; NTP NO IARC NO OSHA NO ACGIH NO COMMON NAME; LIMESTONE CAS NUMBER; 1317-65-3 CARCINOGENICITY LISTED BY: NTP NO IARC NO OSHA NO ACGIH NO LD 50; 6450.00 MG/KG ORL RAT COMMON NAME; CLAY CAS NUMBER; 1332-58-7 CARCINOGENICITY LISTED BY; NTP NO IARC NO OSHA NO ACGIH NO COMMON NAME; QUARTZ CAS NUMBER: 14808-60-7 CARCINOGENICITY LISTED BY; NTP YES IARC YES 1 OSHA NO ACGIH NO COMMON NAME: LIGHT ALIPHATIC SOLVENT NAPHTHA (PETROLEUM) CAS NUMBER: 64742-89-8 CARCINOGENICITY LISTED BY; NTP NO IARC NO OSHA NO ACGIH NO LD 50; > 3.16 GM/KG SKN RBT LD50; > 5.00 GM/KG ORL RAT COMMON NAME; AROMATIC HYDROCARBON RESIN CAS NUMBER: 68410-16-2 CARCINOGENICITY LISTED BY: NTP NO IARC NO OSHA NO ACGIH NO COMMON NAME: DIMETHYLBUTANE CAS NUMBER: 75-83-2 CARCINOGENICITY LISTED BY; NTP NO IARC NO OSHA NO ACGIH NO COMMON NAME: DIMETHYLBUTANE CAS NUMBER: 79-29-8 CARCINOGENICITY LISTED BY; NTP NO IARC NO OSHA NO ACGIH NO COMMON NAME: STYRENE-BUTADIENE POLYMER CAS NUMBER: 9003-55-8 CARCINOGENICITY LISTED BY; NTP NO IARC NO OSHA NO ACGIH NO COMMON NAME: 3-METHYL PENTANE CAS NUMBER: 96-14-0 CARCINOGENICITY LISTED BY; NTP NO IARC NO OSHA NO ACGIH NO SUPPLEMENTAL HEALTH INFORMATION CONTAINS A CHEMICAL THAT MAY BE ABSORBED THROUGH SKIN. NOTICE; REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS MAY BE HARMFUL OR FATAL. OTHER EFFECTS OF OVEREXPOSURE MAY INCLUDE TOXICITY TO CENTRAL NERVOUS SYSTEM. CARCINOGENICITY: CONTAINS CRYSTALLINE SILICA WHICH IS CONSIDERED A HAZARD BY INHALATION. IARC HAS CLASSIFIED CRYSTALLINE SILICA AS CARCINOGENIC TO HUMANS (GROUP 1). CRYSTALLINE SILICA IS ALSO A KNOWN CAUSE OF SILICOSIS, A NON CANCEROUS LUNG DISEASE. THE NATIONAL TOXICOLOGY PROGRAM (NTP) HAS CLASSIFIED CRYSTALLINE SILICA AS A KNOWN HUMAN CARCINOGEN. REPRODUCTIVE EFFECTS; NO REPRODUCTIVE EFFECTS ARE ANTICIPATED MUTAGENICITY: NO MUTAGENIC EFFECTS ARE ANTICIPATED. TERATOGENICITY: NO TERATOGENIC EFFECTS ARE ANTICIPATED. SECTION 12; ECOLOGICAL INFORMATION -------------------------------------------------------------------------------- NO ECOLOGICAL TESTING HAS BEEN DONE BY ICI PAINTS ON THIS PRODUCT AS A WHOLE. SECTION 13; DISPOSAL CONSIDERATIONS -------------------------------------------------------------------------------- WASTE DISPOSAL; DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS. SECTION 14; TRANSPORT INFORMATION -------------------------------------------------------------------------------- DOT; ADHESIVES, 3, UN1133, PGIII IMDG; ADHESIVES, CLASS 3, UN1133, PGIII, LIMITED QUANTITY. ADHESIVES, CLASS 3, UN1133, PGIII IATA; CONSUMER COMMODITY, 9, ID8000 TDG; NOT AVAILABLE SECTION 15; REGULATORY INFORMATION -------------------------------------------------------------------------------- SARA SARA CERCLA HAZ AIR MARINE 302 313 302.4 POLLUTANT POLTNT THIS PRODUCT CONTAINS NO SARA 302, CERCLA 302.4 OR HAZARDOUS AIR POLLUTANT CHEMICALS. IT ALSO CONTAINS NO CHEMICALS WHICH ARE SUBJECT TO THE REPORTING REQUIREMENTS UNDER SARA 313. AS OF THE DATE OF THIS MSDS, ALL OF THE COMPONENTS IN THIS PRODUCT ARE LISTED (OR ARE OTHER WISE EXEMPT FROM LISTING) ON THE TSCA INVENTORY. THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE CPR (CONTROLLED PRODUCTS REGULATIONS) & THE MSDS CONTAINS ALL THE INFORMATION REQUIRED BY THE CPR. SECTION 16; OTHER INFORMATION -------------------------------------------------------------------------------- THE INFORMATION CONTAINED HEREIN IS BASED ON DATA AVAILABLE AT THE TIME OF PREPARATION OF THIS DATA SHEET AND WHICH ICI PAINTS BELIEVES TO BE RELIABLE. HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THIS DATA. ICI PAINTS SHALL NOT BE RESPONSIBLE FOR THE USE OF THIS INFORMATION, OR OF ANY PRODUCT, METHOD OR APPARATUS MENTIONED AND YOU MUST MAKE YOUR OWN DETERMINATION OF ITS SUITABILITY AND COMPLETENESS FOR YOUR OWN USE, FOR THE PROTECTION OF THE ENVIRONMENT, AND THE HEALTH AND SAFETY OF YOUR EMPLOYEES AND USERS OF THIS MATERIAL. COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD 29CFR 1910.1200.